Tuning clathrate hydrates for hydrogen storage

Nature

Volumn 434, Issue 7034, 2005, Pages 743-746

  Lee, Huen ^a   Lee, Jong Won ^a   Kim, Do Youn ^a   Park, Jeasung ^a   Seo, Yu Taek ^b,c   Zeng, Huang ^b   Moudrakovskr, Igor L ^b   Ratcliffe, Christopher I ^b   Ripmeester, John A ^b  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^b NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^c Korea Institute of Energy Research (KIER)   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; HYDRATES; HYDROGEN; SOLUBILITY; TUNING;

HYBRID MATERIALS; HYDROGEN STORAGE; HYDROGEN-BASED ECONOMY; TETRAHYDROFURAN (THF);

COMPLEXATION;

CLATHRATE; HYDROGEN; TETRAHYDROFURAN; UNCLASSIFIED DRUG;

CLATHRATE; HYDROGEN;

ADSORPTION; ARTICLE; CHEMICAL BOND; ENERGY; PRIORITY JOURNAL; PROTON TRANSPORT; SYNTHESIS;

EID: 17644397538     PISSN: 00280836     EISSN: None     Source Type: Journal    
DOI: 10.1038/nature03457     Document Type: Article

References (13)

1. Berry, G. D. & Aceves, S. M. Onboard storage alternatives for hydrogen vehicles. Energy Fuels 12, 49-55 (1998).
2. Schlapbach, L. & Zuttel, A. Hydrogen-storage materials for mobile applications. Nature 414, 353-358 (2001).
3. Weitkamp, I., Fritz, M. & Ernst, S. Zeolites as media for hydrogen storage. Int. J. Hydrogen Energy 20, 967-970 (1995).
4. Schimmel, H. G. et al. Hydrogen adsorption in carbon nanostructures: Comparison of nanotubes, fibers, and coals. Chem. Eur. J. 9, 4764-4770 (2003).
5. Rosi, N. L. et al. Hydrogen storage in microporous metal-organic frameworks. Science 300, 1127-1129 (2003).
6. Mao, W. L. et al. Hydrogen clusters in clathrate hydrate. Science 297, 2247-2249 (2002).
7. Patchkovskii, S. & Tse, J. S. Thermodynamic stability of hydrogen clathrates. Proc. Natl. Acad. Sci. USA 100, 14645-14650 (2003).
8. Mao, W. L. & Mao, H. Hydrogen storage in molecular compounds. Proc. Natl. Acad. Sci. USA 101, 708-710 (2004).
9. Florusse, L. I. et al. Stable low-pressure hydrogen clusters stored in a binary clathrate hydrate. Science 306, 469-471 (2004).
10. Jeffrey, G. A. in Comprehensive Supramolecular Chemistry Vol. 6 (eds MacNicol, D. D, Toda, F. & Bishop, R.) 757-788 (Pergamon, Oxford, 1996).
11. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds 4th edn (Wiley, New York, 1986).
12. Nakahara, J. et al. C. C. Raman spectra of natural clathrates in deep ice cores. Phil. Mag. B 3, 421-430 (1988).
13. Lokshin, K. A. et al. Structure and dynamics of hydrogen molecules in the novel clathrate hydrate by high pressure neutron diffraction. Phys. Rev. Lett. 93, 125503 (2004).