Rate constants for the solution and electrode electron-transfer to substituted bromobenzenes in DMF

Tetrahedron Letters

Volumn 37, Issue 20, 1996, Pages 3553-3556

  Jaworski, Jan S ^a   Leszczyński, Piotr ^a  

^a UNIVERSITY OF WARSAW   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

BROMOBENZENE;

ARTICLE; ELECTROCHEMISTRY; ELECTRON TRANSPORT;

EID: 17544403136     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)00610-7     Document Type: Article

References (12)

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3. Andrieux, C.P.; Dumas-Bouchiat, J.-M.; Savéant, J.M. J. Electroanal. Chem. 1978, 87, 39-53 and 55-65.
4. Andrieux, C.P.; Blocman, C.; Dumas-Bouchiat, M'Halla, F.; J.-M.; Savéant, J.M. J. Electroanal. Chem. 1980, 113, 19-40.
5. Andrieux, C.P.; Blocman, C.; Dumas-Bouchiat, J.-M.; Savéant, J.M. J. Am. Chem. Soc. 1979, 101, 3431-3441.
6. Savéant, J.M. Adv. Phys. Org. Chem. 1990, 26, 1-130.
7. Andrieux, C.P.; Hapiot, P.; Savéant, J.M. Chem. Rev. 1990, 90, 723-738.
8. The quadratic dependence, predicted by the Marcus model, is not expected here because of the small range of the variation in rate constants.
9. Hansch, C.; Leo, A., Taft, R.W. Chem. Rev. 1991, 91, 165-195.
10. 1 but this effect is small giving a change in logk, not more than 0.2 for the reactants under investigation, as calculated for the radii estimated from the molar mass and the density.
11. Savéant, J.M. J. Am. Chem. Soc. 1992, 114, 10595-10602.
12. 5 in the presence of tetrabutylammonium iodide.