Macropolyhedral boron-containing cluster chemistry. Synchrotron X-ray structural analysis of [(PMe2Ph)2Pd2B 16H20(PMe2Ph)2] and [(PMe 2Ph)3Pt2B16H18(PMe 2Ph)]: Models of intermediates to more condensed metallaboranes from the [(PMe2Ph)

Chemical Communications

Volumn , Issue 12, 2005, Pages 1584-1586

  Londesborough, Michael G S ^a   MacLean, Elizabeth J ^b   Teat, Simon J ^b   Thornton Pett, Mark ^a   Kennedy, John D ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

^b DARESBURY LABORATORY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

BORANE DERIVATIVE; BORON DERIVATIVE; HYDROGEN; PALLADIUM COMPLEX; PHOSPHORUS DERIVATIVE; PLATINUM DERIVATIVE;

ARTICLE; CHEMISTRY; CRYSTAL STRUCTURE; GEOMETRY; POLYMERIZATION; STOICHIOMETRY; STRUCTURE ANALYSIS; SYNCHROTRON; THERMODYNAMICS; THERMOLYSIS; X RAY CRYSTALLOGRAPHY;

EID: 17544383960     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b419242g     Document Type: Article

References (28)

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18. T 12 min; 2 mg, 3.5 μmol, ca. 1%).
19. 2 = 0.0768 for all 29614 unique reflections, CCDC reference number 198685.
20. 31P) ca. 50 Hz], and -1.6 (broader) and -5.2 ppm (broader).
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28. SHELXTL software, Bruker AXS Inc., Madison, WI, USA, 1997.