Sensitivity of methane hydrate phase equilibria to sediment pore size

Fluid Phase Equilibria

Volumn 228-229, Issue , 2005, Pages 505-510

  Turner, Douglas J ^a   Cherry, Robert S ^b   Sloan, E Dendy ^a  

^a Department of Geology and Geological Engineering   (United States)

^b IDAHO NATIONAL LABORATORY   (United States)

Author keywords

Adriatic sandstone; Equilibria shift; Methane hydrate; Porous media; Sediment; Surface energy

Indexed keywords

INTERFACIAL ENERGY; METHANE; NUCLEATION; PHASE EQUILIBRIA; PORE SIZE; SANDSTONE; SEDIMENTS; THERMOCOUPLES;

HYDRATE EQUILIBRIA; KELVIN-CLAPEYRON EQUATION; METHANE HYDRATE;

HYDRATES;

METHANE;

EID: 17544383503     PISSN: 03783812     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fluid.2004.09.025     Document Type: Conference Paper

References (23)

1. M. Kastner Gas hydrates in convergent margins: formation, occurrence, geochemistry, and global significance C.K. Paull W.P. Dillon Natural Gas Hydrates: Occurrence, Distribution, and Detection 2001 American Geophysical Union Washington, DC 67 86
2. H. Lu, and R. Matsumoto What Caused the Discrepancy between BSR and BGHS? 1998 Japan National Oil Corporation p. 71
3. P.Y. Handa, and D. Stupin Thermodynamic properties and dissociation characteristics of methane and propane hydrate in 70-Å radius silica gel pores J. Phys. Chem. 96 1992 8599 8603
4. T. Uchida, T. Ebinuma, and T. Ishizaki Dissociation condition measurements of methane hydrate in confined small pores of porous glass J. Phys. Chem. B 103 1999 3659 3662
5. K. Seshadri, J.W. Wilder, and D.H. Smith Measurements of equilibrium pressures and temperatures for propane hydrate in silica gels with different pore-size distributions J. Phys. Chem. B 105 2001 2627 2631
6. R. Anderson, R.W. Burgass, B. Tohidi, and K.K. Østergaard Experimental measurement of gas hydrate stability in porous media Proceedings of the EAGE 63rd Conference and Technical Exhibition Amsterdam, The Netherlands 2000 567
7. M.A. Clarke, M. Pooladi-Darvish, and P.R. Bishnoi A method to predict equilibrium conditions of gas hydrate formation in porous media Ind. Eng. Chem. Res. 38 1999 2485 2490
8. T. Uchida, T. Ebinuma, S. Takaya, J. Nagao, and H. Narita Effects of pore sizes on dissociation temperatures and pressures of methane, carbon dioxide, and propane hydrates in porous media J. Phys. Chem. B 106 2002 820 826
9. B.M. Clennell, M. Hovland, J.S. Booth, P. Henry, and W.J. Winters Formation of natural gas hydrates in marine sediments. 1. Conceptual model of gas hydrate growth conditioned by host sediment properties J. Geophys. Res. 104 B10 1999 22985 23003
10. D.H. Smith, J.W. Wilder, K. Seshadri, and W. Zhang Equilibrium pressures and temperatures for equilibria involving sI and sII hydrate, liquid water, and free gas in porous media Proceedings of the 4th ICGH Yokohama 2002 295 300
11. D.H. Smith, J.W. Wilder, and K. Seshadri Methane hydrate equilibria in silica gels with broad pore-size distributions AIChE J. 48 2 2002 393 400
12. W. Zhang, J.W. Wilder, and D.H. Smith Interpretation of ethane hydrate equilibrium data for porous media involving hydrate-ice equilibria AIChE J. 48 10 2002 2324 2331
13. D. Turner, Sensitivity of methane and tetrahydrofuran hydrate equilibria to porous media, Master Thesis, Colorado School of Mines, 2003.
14. S. Adisasmito, R.J. Frank, and E.D. Sloan J. Chem. Eng. Data 36 1991 68
15. J.L. de Roo, C.J. Peters, R.N. Lichtenthaler, and G.A.M. Diepen Occurrence of methane hydrate in saturated and unsaturated solutions of sodium chloride and water in dependence of temperature and pressure AIChE J. 29 1983 651
16. J.L. Thakore, and G.D. Holder Solid-vapor azeotropes in hydrate-forming systems Ind. Eng. Chem. Res. 26 1987 462 469
17. A. Ballard, A non-ideal hydrate solid solution model for a multi-phase equilibria program, Ph.D. Thesis, Colorado School of Mines, 2002.
18. P.S. Epstein Textbook of Thermodynamics 1954 Wiley New York (Chapter 12)
19. E.D. Sloan Clathrate Hydrates of Natural Gases 2nd ed. 1998 Marcel Decker p. 241
20. R.M. Rueff, The heat capacity and heat of dissociation of methane hydrates: a new approach, Ph.D. Thesis, Colorado School of Mines, 1985, p. 116.
21. A.W. Adamson, and A.P. Gast Physical Chemistry of Surfaces 1997 Wiley
22. R.C. Weast Handbook of Chemistry and Physics 70th ed. 1990 CRC Press p. 34
23. Uchida, Decomposition of methane hydrates in sand, sandstone, clays, and glass beads, J. Geophys. Res. 109 No. B5, B05206 (2004), pp. 1-12.