(Cyclopentadienyl)chromiumtricarbonyl dimers as a source of metal-centered free-radicals to form stable η2-bonded spin-adducts with fullerenes

Journal of Organometallic Chemistry

Volumn 690, Issue 9, 2005, Pages 2333-2338

  Sokolov, Viatcheslav I ^a   Gasanov, Rashid G ^a   Goh, Lai Yoong ^b   Weng, Zhiqiang ^b   Chistyakov, Anatoliy L ^a   Stankevich, Ivan V ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

Chromium chromium bond; Cyclopentadienylchromiumcarbonyl dimers; DFT PBE calculations; ESR spectroscopy; Fullerenes C60, C70; Metal centered free radicals; Spin adducts; 2 bonding

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; COORDINATION REACTIONS; DIMERS; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICALS; ISOMERS; ISOTOPES; ORGANOMETALLICS; PROBABILITY DENSITY FUNCTION; REACTION KINETICS; TOLUENE;

CHROMIUM-CHROMIUM BOND; CYCLOPENTADIENYLCHROMIUMCARBONYL DIMERS; DFT-PBE CALCULATIONS; ESR SPECTROSCOPY; FULLERENES C60, C70; METAL-CENTERED FREE RADICALS; SPIN-ADDUCTS; Η2 BONDING;

FULLERENES;

EID: 17444430815     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2005.03.002     Document Type: Article

References (25)

1. P.J. Krusic, E. Wasserman, B.A. Parkinson, P.N. Keizer, J.R. Morton, and K.F. Preston Science 254 1991 1183
2. B.L. Tumanskii, V.V. Bashilov, S.P. Solodovnikov, and V.I. Sokolov Russ. Chem. Bull. [Engl.] 41 1992 1140
3. B.L. Tumanskii, and O.G. Kalina Radical reactions of fullerenes and their derivatives 2001 Kluwer Academic Publ. Dordrecht
4. B.L. Tumanskii, V.V. Bashilov, S.P. Solodovnikov, and V.I. Sokolov Russ. Chem. Bull. [Engl.] 41 1992 1521
5. B.L. Tumanskii, V.V. Bashilov, S.P. Solodovnikov, and V.I. Sokolov Russ. Chem. Bull. Engl. 44 1995 1771
6. B.L. Tumanskii, V.V. Bashilov, M.N. Nefedova, N.N. Bubnov, S.P. Solodovnikov, and V.I. Sokolov Mol. Mater. 11 1998 91
7. O.G. Kalina, B.L. Tumanskii, V.V. Bashilov, A.L. Chistyakov, I.V. Stankevich, V.I. Sokolov, T.J.S. Dennis, and R. Taylor J. Chem. Soc., Perkin Trans. 2 1999 2655
8. V.V. Bashilov, B.L. Tumanskii, P.V. Petrovskii, and V.I. Sokolov Russ. Chem. Bull. [Engl.] 43 1994 1069
9. S. Zhang, T.L. Brown, Y. Du, and J.R. Shapley J. Am. Chem. Soc. 115 1993 6705
10. H.J. Keller Z. Naturforsch. B 23 1968 133
11. R.D. Adams, D.E. Collins, and F.A. Cotton J. Am. Chem. Soc. 96 1974 749
12. J.R. Morton, K.F. Preston, N.A. Cooley, M.C. Baird, P.J. Krusic, and S.J. McLain J. Chem. Soc. Faraday Trans. 1 83 1987 3535
13. S.J. McLain J. Am. Chem. Soc. 110 1988 643
14. J.R. Morton, K.F. Preston, P.J. Krusic, S.A. Hill, and E. Wasserman J. Chem. Soc., Perkin Trans. 2 1992 1425
15. L.Y. Goh, S.K. Khoo, and Y.Y. Lim J. Organomet. Chem. 399 1990 115
16. L.Y. Goh, and Y.Y. Lim J. Organomet. Chem. 402 1991 209
17. M.C. Baird Chem. Rev. 88 1988 1217
18. Z. Weng, and L.Y. Goh Acc. Chem. Res. 37 2004 187
19. I. Kovacs, and M. Baird Organometallics 15 1996 3588
20. J.P. Perdew, K. Burke, and M. Ernzerhof Phys. Rev. Lett. 77 1996 3865
21. D.N. Laikov Chem. Phys. Lett. 281 1997 151
22. A.L. Chistyakov, and I.V. Stankevich Russ. Chem. Bull. [Engl]. 51 2002 709
23. A.L. Chistyakov, and I.V. Stankevich Russ. Chem. Bull. Engl. 52 2003 1027
24. V.V. Bashilov, P.V. Petrovskii, S.V. Lindeman, I.A. Guzei, Yu.T. Struchkov, and V.I. Sokolov Organometallics 12 1993 991
25. A.L. Balch, and M.M. Olmstead Chem. Rev. 98 1998 2123