A new synthesis of allyl sulfoxides via nucleophilic addition of sulfinyl carbanions to group 6 fischer carbene complexes

Organic Letters

Volumn 7, Issue 7, 2005, Pages 1235-1237

  Barluenga, José ^a   Fañanás Mastral, Martín ^a   Aznar, Fernando ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENOID; SULFOXIDE;

ADDITION REACTION; ARTICLE; COMPLEX FORMATION; REACTION ANALYSIS; SYNTHESIS;

EID: 17444362678     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0473795     Document Type: Article

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22. This olefination reaction is achieved only with aryl or heteroaryl carbene complexes. When alkenyl and alkynyl carbene complexes are used, a complex mixture of products coming from 1,2- and 1,4-addition is obtained.