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Volumn , Issue 6, 2005, Pages 1012-1014

Condition-driven selective syntheses of dialkyl diselenides involving elemental selenium and sodium borohydride

Author keywords

Alkyl halides; Alkylation; Benzyl halides; Dimetal diselenide; Elemental selenium; Sodium borohydride

Indexed keywords

HALIDE; SELENIDE; SELENIUM; SODIUM BOROHYDRIDE;

EID: 17144403790     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-864814     Document Type: Article
Times cited : (14)

References (44)
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  • 2
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    • Patai, S.; Rappoport, Z., Eds.; John Wiley and Sons: Chichester
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    • (1987) The Chemistry of Organic Selenium and Tellurium Compounds , vol.2
  • 5
    • 0000025907 scopus 로고
    • Abel, E. W.; Stone, F. G. A.; Wilkinson, G.; McKillop, A., Eds.; Pergamon: Oxford
    • (e) Krief, A. In Comprehensive Organometallic Chemistry II, Vol. 11; Abel, E. W.; Stone, F. G. A.; Wilkinson, G.; McKillop, A., Eds.; Pergamon: Oxford, 1995, 516.
    • (1995) Comprehensive Organometallic Chemistry II , vol.11 , pp. 516
    • Krief, A.1
  • 34
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    • note
    • 13a
  • 35
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    • note
    • 4 and EtOH (1:1:3 molar equiv each) leads to the evolvement of dihydrogen (2.58 molar equiv, 86% of the expected amount), sequential addition of DMF and decyl bromide produces an additional formation of hydrogen (0.42 molar equiv, 14% of the expected amount).
  • 36
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    • 77Se NMR. For a related work see: Cusik, J.; Dance, I. Polyhedron 1991, 10, 2629.
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    • note
    • 4 and EtOH (1:2:6 mol equiv).
  • 38
    • 17144399639 scopus 로고    scopus 로고
    • note
    • (b) Another 0.81 molar equiv of dihydrogen is evolved if aq EtOH (4 molar equiv each), is added before that of the second crop of elemental selenium.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.