Electronic structure of Ag2Cu2O4. Evidence of oxidized silver and copper and internal charge delocalization

Journal of Physical Chemistry B

Volumn 109, Issue 13, 2005, Pages 6193-6203

  Munoz Rojas D ^a   Subias G ^b   Fraxedas, J ^a   Gomez Romero P ^a   Casan Pastor N ^a  

^a INSTITUT DE CIÈNCIA DE MATERIALS DE BARCELONA ICMAB CSIC   (Spain)

^b UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC CHARGE; ELECTROCHEMISTRY; ELECTRONIC STRUCTURE; INTERCALATION COMPOUNDS; OXIDATION; SOLID SOLUTIONS; X RAY ANALYSIS;

CHARGE DELOCALIZATION; OXYGEN INTERCALATION; REDOX INTERCALATION REACTIONS; TERNARY COMPOUNDS;

SILVER COMPOUNDS;

COPPER; OXIDE; SILVER DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; OXIDATION REDUCTION REACTION;

COPPER; MODELS, MOLECULAR; OXIDATION-REDUCTION; OXIDES; SILVER COMPOUNDS;

EID: 17144403511     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp044493w     Document Type: Article

References (53)

1. (a) Baker, C. L.; Lincoln, F. J.; Johnson, A. W. S. Acta Crystallogr. B 1991, 104, 891.
2. (b) Baker, C. L.; Lincoln, F. J.; Johnson, A. W. S. Aust. J. Chem. 1992, 45, 1441.
3. (c) Frueh, A. J.; Czamanske, G. K.; Knight, C. Z. Kristallogr., Kristallgeom. 1957, 108, 389.
4. (d) Avilov, A. S.; Baranova, R. V. Kristallografiya 1972, 17, 219.
5. Tejada-Rosales, E. M.; Palacín M. R.; Gómez-Romero, P. Bol. Soc, Esp. Cerám. Vidrio 2000, 39 (3), 209.
6. Gómez-Romero, P.; Tejada-Rosales, E. M.; Palacín, M. R. Angew. Chem. Int. Ed. 1999, 38 (4), 524.
7. Tejada-Rosales, E. M.; Rodríguez-Carvajal, J.; Casañ-Pastor, N.; Alemany, P.; Ruiz, E.; Alvarez, S.; Gómez-Romero, P. Inorg. Chem. 2002, 41, 6604.
8. Tejada-Rosales, E. M.; Oró-Solé, J.; Gómez-Romero, P. 2002, 163 (1), 151.
9. McMillan, J. A. Chem. Rev. 1962, 62, 65.
10. Ebert, M. S.; Rodowskas, E. L.; Frazer, J. C. W. J. Am. Chem. Soc. 1933, 55, 3056.
11. (a) Grochala, W.; Huffman, R. Angew. Chem., Int. Ed. 2001, 40, 2742.
12. (b) Grochala, W.; Egdell, R. G.; Edwards, P. P.; Mazej, Z.; Zemva, B. Chem. Phys. Chem. 2003, 4, 997
13. Vanderah, T. A. Chemistry of Superconductor Materials. Preparation, Chemistry, Characterization and Theory; Noyes Publications: Mill Road, 1992.
14. Casañ-Pastor, N.; Gómez-Romero, P.; Fuertes, A.; Navarro, J. M.; Sanchis, J. M.; Ordoño-Castillo, S Physica C 1993, 216, 478.
15. Muñoz-Rojas, D.; Tejada-Rosales, E. M.; Gómez-Romero, P.; Casañ Pastor, N. Poster and oral presentations at Vth Electroceramics and FIGIPS Meeting in Barcelona, May-June 2001.
16. Muñoz-Rojas, D.; Oró, J.; Gómez-Romero, P.; Fraxedas, J.; Casañ-Pastor, N. Electrochem. Commun. 2002, 4, 684.
17. Muñoz-Rojas, D.; Fraxedas, J.; Oró, J.; Gómez-Romero, P.; Casañ-Pastor, N. Cryst. Eng. 2002, 5, 459.
18. Muñoz-Rojas, D.; Fraxedas, J.; Gómez-Romero, P.; Casañ-Pastor, N. J. Solid State Chem. 2005, 178, 295.
19. Curda, J.; Klein, W.; Liu, H.; Jansen, M. J. Alloys Compd. 2002, 338, 99.
20. Muñoz-Rojas, D. New Ag-Cu Oxides by Electrochemical Intercalation and other soft methods. Ph.D. Thesis, Autonomous University of Barcelona (UAB), May 2004.
21. Wattiaux, A.; Park, J. C.; Grenier, J. C.; Pouchard, M. C. R. Acad. Sci. Paris Serie II 1990, 310, 1047.
22. Ordoño-Castillo, S.; Michel, C. R.; Seffar, A.; Fontcuberta, F.; Casañ-Pastor, N. Physica C 1994, 235-240, 563.
23. Michel, C. M.; Casañ-Pastor, N. Physica C 1997, 278, 149.
24. Casañ-Pastor, N.; Michel, C. R.; Zinck, C.; Tejada-Rosales, E. M. Chem. Mater. 2001, 13, 2118.
25. Grenier, J. C.; Wattiaux, A.; Lagueyte, N.; Park, J. C.; Marquestaut, E.; Etorneau, J.; Pouchard, M. Physica C 1991, 173, 139.
26. Gómez-Romero, P.; Palacín, M. R.; Michel, C. R.; Casañ-Pastor, N. Solid State Ion. 1997, 101-103, 411.
27. Michel, C. R.; Amigó, R.; Casañ-Pastor, N. Chem. Mater. 1999, 11, 195.
28. Tejada-Rosales, E. M. Complex Oxides of Silver and Copper. Ph.D. Thesis, Autonomous University of Barcelona (UAB), Jan. 2001.
29. Adelsberger, K.; Curda, J.; Vensky, S.; Jansen, M. J. Solid State Chem. 2001, 158(1), 82.
30. Jansen, M.; Fischer, P. J. Less-Common Met. 1988, 137 (1-2), 123.
31. Choy, J. H.; Kim, Y. I.; Hwang, S. J. J. Phys. Chem. 1998, 102, 9191.
32. Behrens, P.; Assmann, S.; Bilow, U.; Linke, C.; Jansen, M. Z Anorg. Allg. Chem. 1999, 625, 111.
33. Allen, P. G.; Gash, A. E.; Dorhout, P. K.; Strauss, S. H. Chem. Mater. 2001, 13, 2257.
34. Curda, J.; klein, W.; Jansen, M. J. Solid State Chem. 2001, 162, 220.
35. Friedman, T. L.; Stacy, A. M. J. Solid State Chem. 1994, 109, 203.
36. Filiponi, A.; Borowski, M.; Bowron, D. T.; Ansell, S.; A. Di Cicco, A.; de Panfilis, S.; Itiè, J. P. Rev. Sci. Instrum. 2002, 71, 2422.
37. Koningsberger, D. C.; Prins, R. X-Ray absorption: Principles, Application, Techniques of EXAFS, SEXAFS and XANES; Wiley: New York, 1988.
38. (a) Rehr, J. J.; Albers, R. C. Rev. Mod. Phys. 2002, 72, 621. See http://FEFF.phys.washington.edu.
39. (b) Stern, E. A.; Newville, H.; Ravel, B.; Yaroby, Y.; Haskel, D. Physica B 1995, 208&209, 117.
40. Schön, G. Acta Chem. Scand. 1973, 27, 24623.
41. Bao, X.; Muhler, M.; Schedel-Niedrig, T.; Schlögl, R. Phys. Rev. B 1996, 54, 2249.
42. Tjeng, L. H.; Meinders, M. B. J.; van Elp, J.; Ghijsen, J.; Sawatzky, G. A.; Johnson, R. L. Phys. Rev. B 1990, 41, 3190.
43. Waterhouse, G. I. N.; Bowmaker, G. A.; Metson, J. B. Appl. Surf. Sci. 2001, 183, 191.
44. Boronin, A. I.; Koscheev, S. V.; Zhidomirov, O. V. K. G. M. React. Kinet. Catal. Lett. 1998, 63, 291.
45. Ghijsen, J.; Tjeng, L. H.; van Elp, J.; Eskes, H.; Westerink, J.; Sawaztzky, G. A.; Czyzyk, M. T. Phys. Rev. B. 1998, 38, 11332.
46. Cox, P. A. The Electronic Structure and Chemistry of Solids; Oxford Science Publications: Walton Street, Oxford OX26DP, U.K., 1989.
47. Norby, P.; Dinnebier, R. E.; Fitch, A. N. Inorg. Chem. 2002, 41, 3628.
48. Brese, N. E.; O'Keefe, M. O.; Ramakrisna, B. L.; Dreele, R. B. V. J. Solid State Chem. 1990, 89, 184.
49. Brese, N. E.; O'Keefe, M. O.; VonDreele, R. B.; Young, V. G., Jr. J. Solid State Chem. 1989, 83, 1.
50. Orgel, L. E. J. Chem. Soc 1958, 4186.
51. Müller-Buschbaum, H. Z. Anorg. Allg. Chem. 2004, 630, 2125.
52. Lucier, G.; Münzeberg, J.; Casteel, W. J.; Bartlett, N. Inorg. Chem. 1995, 34, 2692.
53. West, A. R. Solid-State Electrochemistry, Bruce, P. G., Ed.; Cambridge University Press: Cambridge, U.K., 1995; Chapter 2.