The discovery of metallocene- and metallocene-like addition polymers

Journal of Inorganic and Organometallic Polymers

Volumn 15, Issue 1, 2005, Pages 33-55

  Pittman Jr , Charles U ^a,b  

^a MISSISSIPPI STATE UNIVERSITY   (United States)

^b Mississippi State University University Industry Chemical Research Center   (United States)

Author keywords

Metallocene; Polymers; Vinylferrocene polymerization

Indexed keywords

POLYMER; TRANSITION ELEMENT;

ADDITION REACTION; CATALYSIS; LABORATORY TEST; MACROMOLECULE; MOLECULAR WEIGHT; REVIEW; RING OPENING METATHESIS POLYMERIZATION; SYNTHESIS;

EID: 17144374137     PISSN: 10530495     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10904-004-2374-6     Document Type: Review

References (131)

1. T. J. Kealy and P. L. Pauson, Nature 168, 1039 (1951).
2. G. Wilkinson, M. Rosenblum, H. C. Whiting, and R. B. Woodward, J. Am. Chem. Soc. 74, 2125 (1952).
3. R. B. Woodward, M. Rosenblum, and H. C. Whiting, J. Am. Chem. Soc. 74. 3458 (1952).
4. R. Dagani, "Fifty Years of Ferrocene Chemistry," in Chem. And Eng. News 79(49), 37-38, Dec. 3 (2001); also see "50th Anniversary of the Discovery of Ferrocene," Ed. R. D. Adams, special edition of J. Organometal. Chem. Vol. 637-639, 1-875 (2001).
5. R. Dagani, "Fifty Years of Ferrocene Chemistry," in Chem. And Eng. News 79(49), 37-38, Dec. 3 (2001); also see "50th Anniversary of the Discovery of Ferrocene," Ed. R. D. Adams, special edition of J. Organometal. Chem. Vol. 637-639, 1-875 (2001).
6. F. S. Arimoto and A. C. Haven, Jr., J. Am. Chem. Soc. 77, 6295 (1955); also see A. C. Haven, Jr., US Patent 2,821,512 (January 28, 1958).
7. F. S. Arimoto and A. C. Haven, Jr., J. Am. Chem. Soc. 77, 6295 (1955); also see A. C. Haven, Jr., US Patent 2,821,512 (January 28, 1958).
8. M. G. Baldwin and K. E. Johnson, J. Polym. Sci. 5, 2901 (1967).
9. J. C. Lai, T. Rounsefell, and C. U. Pittman, Jr., J. Polym. Sci. Part A-1 9, 651 (1971).
10. C. U. Pittman, Jr., J. C. Lai, and D. P. Vanderpool, Macromolecules 3(1), 105 (1970).
11. C. U. Pittman, Jr., J. C. Lai, D. P. Vanderpool, M. Good, and R. Prados, Macromolecules 3(6), 746 (1970).
12. J. C. Lai, T. D. Rounsefell, and C. U. Pittman, Jr., Macromolecules 4(2), 155 (1971).
13. C. U. Pittman, Jr., R. L. Voges, and J. Elder, Polymer Lett. 9, 191 (1971).
14. C. U. Pittman, Jr., R. L. Voges, and W. R. Jones, Macromolecules 4(3), 291 (1971).
15. C. U. Pittman, Jr., R. L. Voges, and W. R. Jones, Macromolecules 4(3), 298 (1971).
16. Y. Sasaki, L. L. Walker, E. L. Hurst, and C. U. Pittman, Jr., J. Polym. Sci. Polym. Chem. Ed. 11, 1213 (1973).
17. M. George and G. Hayes, J. Polym. Sci. Chem. Ed. 13, 1049 (1975).
18. M. George and G. Hayes, J. Polym. Sci. Chem. Ed. 14, 475 (1976).
19. M. George and G. Hayes, Polymer 15, 397 (1974).
20. C. U. Pittman, Jr., J. Paint Technol. 39(513), 585 (1967). Now this journal is J. Coatings Technol.
21. L. H. Caveny and C. U. Pittman, Jr., AIAA J. 6(8), 1461 (1968).
22. C. U. Pittman, Jr., AIAA J. 7(2), 328 (1969).
23. (a) C. U. Pittman, Jr. and J. A. Eikenberry, J. Ala, Acad. Sci. 38 (1967).
24. (b) C. U. Pittman, Jr., Polymer Lett. 6, 18 (1968).
25. (a) C. U. Pittman, Jr., J. Polym. Sci. Part A-1 5, 2927 (1967).
26. (b) C.U. Pittman, Jr., J. Polym. Sci., Part A-1 6, 1687 (1968)..
27. (a) C. U. Pittman, Jr. and P. L. Grube, J. Polym. Sci. A-1 9, 3175 (1971). C. U. Pittman, Jr. and P. L. Grube, J. Appl. Polym. Sci. 18, 2269 (1974).
28. (a) C. U. Pittman, Jr. and P. L. Grube, J. Polym. Sci. A-1 9, 3175 (1971). C. U. Pittman, Jr. and P. L. Grube, J. Appl. Polym. Sci. 18, 2269 (1974).
29. C. C. Price, J. Polym. Sci. 3, 772 (1948).
30. T. Alfrey, Jr., J. J. Bohrer, and H. Mark, Copolymerization, Vol. VIII: High Polymers (Interscience Publishers, New York, 1952).
31. F. R. Mayo and F. M. Lewis, JACS 66, 1954 (1944).
32. D. R. Montgomery and C. E. Fry, J. Polym. Sci. Part C 25, 59 (1968).
33. (a) C. U. Pittman, Jr. and M. D. Rausch, Pure Appl. Chem. 58(4), 617 (1986) and references therein.
34. (b) C. U. Pittman, Jr. and T. D. Rounsefell, Macromolecules 9(6), 936 (1976).
35. C. U. Pittman, Jr. and Y. Sasaki, Chem. Lett. (Japan) 383 (1975).
36. C. U. Pittman, Jr., J. C. Lai, D. P. Vanderpool, M. Good, and R. Prados in Polymer Characterization: Interdisciplinary Approaches, C. D. Carver, ed. (Plenum Press, NY, 1971), pp. 97-124.
37. C. U. Pittman, Jr., Chem. Technol. 1, 416 (1971).
38. O. E. Ayers, S. P. McManus, and C. U. Pittman, Jr., J. Polym. Sci. Polym. Chem. Ed. 11, 1201 (1973).
39. C. U. Pittman, Jr., G. V. Marlin, and T. D. Rounsefell, Macromolecules 6(1), 1 (1973).
40. C. U. Pittman, Jr., C.-C. Lin, and T. D. Rounsefell, Macromolecules 11(5), 1022 (1978).
41. C. U. Pittman, Jr., T. V. Jayaraman, R. D. Priester, Jr., M. D. Rausch, D. W. Macomber, and W. P. Hart, Polymer Preprints 23(2), 73 (1982).
42. C. U. Pittman, Jr., T. D. Rounsefell, E. A. Lewis, J. E. Sheats, B. H. Edwards, M. D. Rausch, and E. A. Mintz, Macromolecules 11, 560 (1978).
43. D. W. Macomber, W. P. Hart, and M. D. Rausch, JACS 104, 884 (1982).
44. M. D. Rausch, D. W. Macomber, K. Gonsalves, F. G. Fang, Z.-R. Lin, and C. U. Pittman, Jr., in Metal-Containing Polymeric Systems, J. E. Sheats, C. E. Carraher and C. U. Pittman, Jr., ed. (Plenum Publishing, NY, 1985), pp. 43-57.
45. D. W. Macomber, W. P. Hart, M. D. Rausch, R. D. Priester, and C. U. Pittman, Jr., J. Organometal. Chem. 205, 353 (1981).
46. M. D. Rausch, D. W. Macomber, C. U. Pittman, Jr., R. D. Priester, Jr., and T. V. Jayaraman, J. Organometal. Chem. 205, 353 (1981).
47. C. U. Pittman, Jr., T. V. Jayaraman, R. D. Priester, Jr., S. Spenser, M. D. Rausch, and D. W. Macomber, Macromolecules 14, 237 (1981).
48. C. U. Pittman, Jr., R. D. Priester, Jr., and T. V. Jayaraman, J. Polym. Sci. Polym. Chem. Ed. 19, 3351 (1981).
49. C. U. Pittman, Jr., T. D. Rounsefell, J. E. Sheats, B. H. Edwards, M. D. Rausch, and E. A. Mintz, Organometallic Polymers (Academic Press, NY, 1978) 67-78.
50. E. A. Mintz, M. D. Rausch, B. H. Edwards, J. E. Sheats, T. D. Rounsefell, and C. U. Pittman, Jr., J. Organometal. Chem. 137, 199 (1977).
51. C. U. Pittman, Jr., R. L. Voges, and J. Elder, Macromolecules 4(3), 302 (1971).
52. C. U. Pittman, Jr., J. Paint Technol. 43(561), 29 (1971).
53. C. U. Pittman, Jr., P. L. Grube, O. E. Ayers, S. P. McManus, M. D. Rausch, and G. A. Moser, J. Polymer Sci. Part A-1 10, 379 (1972).
54. C. U. Pittman, Jr. and R. L. Voges, in Macromolecular Syntheses, W. J. Bailey, ed. (John Wiley and Sons, 1972), Vol. 4, p. 175.
55. C. U. Pittman, Jr. and G. V. Martin, J. Polym. Sci. Polym. Chem. Ed. 11, 2753 (1973).
56. C. U. Pittman, Jr., O. E. Ayers, and S. P. McManus, J. Macromol. Sci. Chem. A7(8), 1563 (1973).
57. C. U. Pittman, Jr., Macromolecules 7(3), 396 (1974).
58. C. U. Pittman, Jr., P. L. Grube, and R. M. Hanes, J. Paint Technol. 46(597), 35 (1974).
59. C. U. Pittman, Jr., O. E. Ayers, and S. P. McManus, Macromolecules 7(6), 737 (1974).
60. C. U. Pittman, Jr., J. Saad, J. Chapman, J. C. Lai, and T. D. Rounsefell, Joint Southeast-Southwest Regional Meeting of the American Chem. Soc. New Orleans, LA, December 2-4, 1970, papers 627, 664 and 666; see Abstracts, pp. 187, 199-200.
61. J. Kozikowski and M. Cais, US. Patent 3,290,337 (1966).
62. C. U. Pittman, Jr., B. T. Kim, and W. M. Douglas, J. Org. Chem. 40, 590 (1975).
63. M. D. Rausch and C. U. Pittman, Jr. in New Monomers and Polymers, B. M. Culbertson and C. U. Pittman, Jr. eds. (Plenum Publishing Corp., New York, 1984), pp. 243-267.
64. D. W. Macomber and M. D. Rausch, J. Organometal. Chem. 205, 311 (1983).
65. M. D. Rausch, D. W. Macomber, K. Gonsalves, F. G. Fang, Z.-R. Lin, and C. U. Pittman, Jr. in Metal-Containing Polymeric Systems, J. E. Sheats, C. E. Carraher, Jr., and C. U. Pittman, Jr. ed. (Plenum Publishins Corp., 1985), pp. 43-57.
66. M. D. Rausch, D. W. Macomber, K. Gonsalves, F. C. Fan, Z. R. Lin, and C. U. Pittman, Jr., Polymeric Mater.: Sci. Eng. Preprints (ACS) 49, 358 (1983).
67. K. Hafner, G. Schultz, and K. Wagner, Justus Liebigs Ann. Chem. 678, 39 (1964).
68. W. P. Hart, D. W. Macomber, and M. D. Rausch, J. Amer. Chem. Soc. 102, 1196 (1980).
69. D. O. Cowan and F. Kaufman, JACS 92, 219 (1970).
70. D. O. Cowan and F. Kaufman, JACS 92, 6198 (1970).
71. D. O. Cowan, J. Park, C. U. Pittman, Jr., Y. Sasaki, T. K. Mukherjee, and N. A. Diamond, JACS 94, 5110 (1972).
72. A. F. Garito and A. J. Heeger, Accounts Chem. Res. 7, 232 (1974).
73. C. U. Pittman, Jr., Y. Sasaki, and P. L. Grube, J. Macromol. Sci.-Chem. A-8(5), 923 (1974).
74. U. T. Mueller-Westerhoff and P. Eilbracht, JACS 94, 9272 (1972).
75. D. O. Cowan and C. LeVanda, JACS 94, 9271 (1972).
76. C. U. Pittman, Jr. and B. Surynarayanan, JACS 96, 7916 (1974).
77. C. U. Pittman, Jr., B. Surynarayanan, and Y. Sasaki in Advances in Chemistry Series, Number 150: Inorganic Compounds With Unusual Properties, R. B. King ed. (ACS Publishers, Washington, DC, 1976) pp. 46-55.
78. C. U. Pittman, Jr., O. E. Ayers, B. Suryanarayanan, S. P. McManus, and J. E. Sheats, Die Makromolekulare Chemie 175, 1427 (1974).
79. J. E. Sheats and T. C. Willis, Org. Coatings Plastics Preprints 41(2), 33 (1979).
80. J. E. Sheats and T. C. Willis, J. Polym. Sci. Polym. Chem. Ed. 22, 1077 (1984).
81. J. E. Sheats, F. Hessel, L. Tsarouhas, K. G. Podejko, T. Porter, L. B. Kool, and R. L. Nolen, Jr., Polymeric. Mater. Sci. Eng. 49(2), 363 (1983).
82. S. P. McManus, W. J. Patterson, and C. U. Pittman, Jr., J. Polym. Sci. Chem. Ed. 13, 1721 (1975).
83. (a) S. P. McManus, W. J. Patterson, and C. U. Pittman, Jr., J. Polym. Sci.: Polym. Chem. Ed., 12, 825 (1974).
84. (b) C. U. Pittman, Jr., W. J. Patterson, and S. P. McManus, J. Polym. Sci. Polym. Chem. Ed., 14, 1715 (1976)..
85. C. U. Pittman, Jr., W. J. Patterson, and S. P. McManus, J. Polym. Sci. Part A-1 9, 3187 (1971).
86. W. J. Patterson, S. P. McManus, and C. U. Pittman, Jr., J. Polym. Sci. Polym. Chem. Ed. 12, 837 (1974).
87. R. B. King, Accounts Chem. Res. 3, 417 (1970).
88. C. U. Pittman, Jr. and R. F. Felis, J. Organometal. Chem. 72, 389 (1974).
89. C. U. Pittman, Jr. and R. F. Felis, J. Organometal. Chem. 72, 399 (1974).
90. C. U. Pittman, Jr. and A. Hirao, J. Polym. Sci.: Polym. Chem. Ed. 15, 1677 (1977).
91. A. Hirao and C. U. Pittman, Jr., Polymer Preprints. Japan 26(4), 634 (1977).
92. C. U. Pittman, Jr. and G. O. Evans, Chemtech, 560, September 1973.
93. G. O. Evans, C. U. Pittman, Jr., R. McMillan, R. T. Beach, and R. Jones, J. Organometal. Chem. 67, 295 (1974).
94. C. U. Pittman, Jr. and R. M. Hanes, Ann. New York Acad. Sci. 239, 76 (1974).
95. C. U. Pittman, Jr. and L. R. Smith, JACS 97, 341 (1975).
96. C. U. Pittman, Jr., L. R. Smith, and R. M. Hanes, JACS 97, 1742 (1975).
97. C. U. Pittman, Jr. and L. R. Smith, JACS 97, 1749 (1975).
98. C. U. Pittman, Jr. and L. R. Smith in Organotransition-Metal Chemistry, Y. Ishii and M. Tsutsui, eds. (Plenum Publ. Co., New York, 1975), pp. 143-156.
99. C. U. Pittman, Jr., L. R. Smith, and S. E. Jacobson, in Catalysis: Heterogeneous and Homogeneous, Proceedings of the Inter'nl. Symposium on the Relations between Heterogeneous and Homogeneous Catalytic Phenomena, Brussels, Belgium, October 23-25, 1974, (Elsevier Scientific Publi. Co., Amsterdam, 1975).
100. J. Haggin, Chem. Eng. News November 15, 11-17 (1982).
101. Science, 194, 1261-1263, December 17 (1976).
102. S. E. Jacobson, C. U. Pittman, Jr., J. Chem. Soc. Chem. Commun., 187 (1975).
103. C. U. Pittman, Jr., S. E. Jacobson, and H. Hiramoto, JACS 97, 4774 (1975).
104. C. U. Pittman, Jr., S. E. Jacobson, L. R. Smith, W. Clements, and H. Hiramoto hagehn, in Catalysis in Organic Syntheses, P. N. Rylander and H. Greenfield, eds. (Academic Press, Inc., New York, 1976) pp. 161-180.
105. S. Jacobson, W. Clements, H. Hiramoto, and C. U. Pittman, Jr., J. Mol. Catal. 1, 73 (1975/76).
106. C. U. Pittman, Jr. and R. M. Hanes, JACS 98, 5402 (1976).
107. C. U. Pittman, S. K. Wuu, Jr., and S. E. Jacobson, J. Catal. 44, 87 (1976).
108. C. U. Pittman, Jr. and R. M. Hanes, J. Org. Chem. 42, 1194 (1977).
109. C. U. Pittman, Jr., A. Hirao, C. Jones, R. M. Hanes, and Q. Ng, Ann. New York Acad. Sci. 295, 15-35, November 25 (1977).
110. C. U. Pittman, Jr., Polymer News 4(1), 5-15, (1977).
111. C. U. Pittman, Jr., J. Mol. Catal. 3, 293 (1977/78).
112. C. U. Pittman, Jr. and A. Hirao, J. Org. Chem. 43, 640 (1978).
113. C. U. Pittman, Jr. and Q. Ng, J. Organometal. Chem. 153, 85 (1978).
114. C. U. Pittman, Jr. and C.-C. Lin, J. Org. Chem. 43, 4928 (1978).
115. C. U. Pittman, Jr., Q. Ng, A. Hirao, W. Honnick, and R. Hanes, Colloques Internat. du Centre National de la Recherche Scientifique: No 281, Relations Entre Catalyse Homogène Et Catalyse Hétérogene, Lyon FR., November 3-6, 1977, pp, 4-100.
116. R. D. Sanner, R. G. Austin, M. S. Wrighton, W. D. Honnick, and C. U. Pittman, Jr., Inorg. Chem. 18, 928 (1979).
117. C. U. Pittman, Jr., W. D. Honnick, M. S. Wrighton, R. D. Sanner, and R. G. Austin, in Fundamental Research in Homogeneous Catalysis, M. Tsutsui, ed. (Plenum Publ. Corp., 1979), Vol. 3, pp. 603-619.
118. C. U. Pittman, Jr. and Q. Ng, US Patent 4,258,206, March 24 (1981).
119. C. U. Pittman, Jr. and Y. F. Liang, J. Org. Chem. 45, 5048 (1980).
120. C. U. Pittman, Jr., W. D. Honnick, and J. J. Yang, J. Org. Chem. 45, 684 (1980).
121. C. U. Pittman, Jr. and G. Wilemon, Ann. New York Acad. Sci. 333, 67 (1980).
122. C. U. Pittman, Jr., in Polymer-supported Reactions in Organic Synthesis, P. Hodge and D. C. Sherrington, eds. (John Wiley and Sons Ltd., 1980). Chap. 5, pp. 249-291.
123. R. D. Sanner, R. G. Austin, M. S. Wrighton, W. D. Honnick, and C.U. Pittman, Jr., in Interfacial Photoprocesses: Energy Conversion and Synthesis, Advances in Chemistry Series 184 (ACS Publishers, 1980), Chap. 2, pp. 13-26.
124. C. U. Pittman, Jr. and W. D. Honnick, J. Org. Chem. 45, 2132 (1980).
125. C. U. Pittman, Jr., G. M. Wilemon, Q. Y. Ng, and L. I. Flowers, Polymer Preprints 22(1), 153 (1981).
126. Y. Kawabata, C. U. Pittman, Jr., and R. Kobayashi, J. Mol. Catal. 12, 113 (1981).
127. C. U. Pittman, Jr. and G. Wilemon, J. Org. Chem. 46, 1901 (1981).
128. C. U. Pittman, Jr. and W. D. Honnick in Catalysis of Organic Reactions, W. R. Moser, ed. (Marcel Dekker, Inc., New York, 1981) pp. 353-380.
129. C. U. Pittman, Jr., Y. Kawabata, L. I. Flowers, J. Chem. Soc. Chem. Commun. 473 (1982).
130. G. Consiglio, P. Pino, L. I. Flowers, C. U. Pittman, Jr., J. Chem. Soc. Chem. Commun. 612 (1983).
131. C. U. Pittman, Jr., in Comprehensive Organometallic Chemistry, G. Wilkinson, F. G. A. Stone, and E. W. Abel, eds. (Pergamon Press, Oxford), Vol. 8, Chap. 55, pp. 553-611.