Trivalent lanthanide lacunary phosphomolybdate complexes: A structural and spectroscopic study across the series [Ln(PMo11O39) 2]11-

Dalton Transactions

Volumn , Issue 7, 2005, Pages 1256-1262

  Copping, Roy ^a   Gaunt, Andrew J ^a   May, Iain ^a   Sarsfield, Mark J ^a,b   Collison, David ^a   Helliwell, Madeleine ^a   Denniss, Iain S ^b   Apperley, David C ^c  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b SELLAFIELD LTD   (United Kingdom)

^c DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

LANTHANIDE LACUNARY PHOSPHOMOLYBDATE COMPLEXES; POLYOXOMETALATE ANIONS; SOLID-STATE MEASUREMENTS; SPACE GROUP;

CATALYSIS; COMPLEXATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; INFRARED SPECTROSCOPY; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RAMAN SPECTROSCOPY; SOLUTIONS; SYNTHESIS (CHEMICAL);

LANTHANUM COMPOUNDS;

LANTHANIDE; MOLYBDENUM; PHOSPHOMOLYBDIC ACID; PHOSPHORIC ACID;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; INFRARED SPECTROPHOTOMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RAMAN SPECTROMETRY; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; LANTHANOID SERIES ELEMENTS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLYBDENUM; PHOSPHORIC ACIDS; SPECTROPHOTOMETRY, INFRARED; SPECTRUM ANALYSIS, RAMAN;

EID: 17144370553     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b500408j     Document Type: Article

References (39)

1. (a) M. T. Pope, Heteropoly and Isopoly Oxometalates, Springer-Verlag, Berlin, 1983;
2. (b) L. C. Baker and D. C. Click, Chem. Rev., 1998, 98, 1.
3. See for example: (a) R. C. Howell, F. G. Perez, S. Jian, W. DeW. Horrocks, Jr., A. L. Rheingold and L. C. Francesconi, Angew. Chem., Int. Ed., 2001, 40, 4031; (b) M. Sadakane, A. Ostuni and M. T. Pope, J. Chem. Soc., Dalton Trans., 2002, 63; (c) M. Sadakane, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed., 2000, 39, 2914; (d) P. Mialane, L. Lisnard, A. Mallard, J. Marrot, E. Antic-Fidancev, P. Aschehoug, D. Vivien and F. Sécheresse, Inorg. Chem., 2003, 42, 2102; (e) K. Wasserman, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed. Engl., 1997, 36, 1445.
4. See for example: (a) R. C. Howell, F. G. Perez, S. Jian, W. DeW. Horrocks, Jr., A. L. Rheingold and L. C. Francesconi, Angew. Chem., Int. Ed., 2001, 40, 4031; (b) M. Sadakane, A. Ostuni and M. T. Pope, J. Chem. Soc., Dalton Trans., 2002, 63; (c) M. Sadakane, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed., 2000, 39, 2914; (d) P. Mialane, L. Lisnard, A. Mallard, J. Marrot, E. Antic-Fidancev, P. Aschehoug, D. Vivien and F. Sécheresse, Inorg. Chem., 2003, 42, 2102; (e) K. Wasserman, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed. Engl., 1997, 36, 1445.
5. See for example: (a) R. C. Howell, F. G. Perez, S. Jian, W. DeW. Horrocks, Jr., A. L. Rheingold and L. C. Francesconi, Angew. Chem., Int. Ed., 2001, 40, 4031; (b) M. Sadakane, A. Ostuni and M. T. Pope, J. Chem. Soc., Dalton Trans., 2002, 63; (c) M. Sadakane, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed., 2000, 39, 2914; (d) P. Mialane, L. Lisnard, A. Mallard, J. Marrot, E. Antic-Fidancev, P. Aschehoug, D. Vivien and F. Sécheresse, Inorg. Chem., 2003, 42, 2102; (e) K. Wasserman, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed. Engl., 1997, 36, 1445.
6. See for example: (a) R. C. Howell, F. G. Perez, S. Jian, W. DeW. Horrocks, Jr., A. L. Rheingold and L. C. Francesconi, Angew. Chem., Int. Ed., 2001, 40, 4031; (b) M. Sadakane, A. Ostuni and M. T. Pope, J. Chem. Soc., Dalton Trans., 2002, 63; (c) M. Sadakane, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed., 2000, 39, 2914; (d) P. Mialane, L. Lisnard, A. Mallard, J. Marrot, E. Antic-Fidancev, P. Aschehoug, D. Vivien and F. Sécheresse, Inorg. Chem., 2003, 42, 2102; (e) K. Wasserman, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed. Engl., 1997, 36, 1445.
7. See for example: (a) R. C. Howell, F. G. Perez, S. Jian, W. DeW. Horrocks, Jr., A. L. Rheingold and L. C. Francesconi, Angew. Chem., Int. Ed., 2001, 40, 4031; (b) M. Sadakane, A. Ostuni and M. T. Pope, J. Chem. Soc., Dalton Trans., 2002, 63; (c) M. Sadakane, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed., 2000, 39, 2914; (d) P. Mialane, L. Lisnard, A. Mallard, J. Marrot, E. Antic-Fidancev, P. Aschehoug, D. Vivien and F. Sécheresse, Inorg. Chem., 2003, 42, 2102; (e) K. Wasserman, M. H. Dickman and M. T. Pope, Angew. Chem., Int. Ed. Engl., 1997, 36, 1445.
8. R. D. Peacock and T. J. R. Weakley, J. Chem. Soc. A., 1971, 1836.
9. Y. K. Shan, Z. X. Liu, Z. S. Jin and G. C. Wei, Acta Chim. Sin., 1992, 50, 357.
10. Y. K. Shan, Z. X. Liu, B. E. Wang, Z. S. Jin, G. C. Wei and Y. S. Liu, Jiegou Huaxue, 1990, 9, 159.
11. E. B. Wang, Y. K. Shan, Z. X. Xu, J. F. Liu and B. J. Zhang, Acta Chim. Sin., 1991, 49, 774.
12. Z. X. Liu, Y. K. Shan, E. B. Wang, Z. S. Jin, G. C. Wei and Y. S. Liu, Chem. J. Chin. Univ., 1991, 12, 1.
13. F. L. Sousa, F. A. Almeida Paz, A. M. V. Cavaleiro, J. Klinowski and H. I. S. Nogueira, Chem. Commun., 2004, 2656.
14. A. J. Gaunt, I. May, D. Collison and O. D. Fox, Inorg. Chem, 2003, 42, 5049.
15. A. J. Gaunt, I. May, M. J. Sarsfield, D. Collison, M. Helliwell and I. S. Denniss, Dalton Trans., 2003, 2767.
16. (a) D. Parker, H. Puschman, A. S. Batsanov and K. Senanayake, Inorg. Chem., 2003, 42, 8646;
17. (b) U. Abram, D. B. Dell'Amico, F. Caderazzo, C. Della Porta, U. Englert, F. Marchetti and A. Merigo, Chem. Commun., 1999, 2053;
18. (c) E. A. Quadrelli, Inorg. Chem., 2002, 41, 167;
19. (d) U. Baisch, D. Dell'Amico, F. Calderazzo, L. Labella, F. Marchetti and A. Merigo, Eur. J. Inorg. Chem., 2004, 1219.
20. A. Chatterjee, E. N. Maslen and K. T. Watson, Acta Crystallogr., Sect. B: Struct. Sci., 1988, 44, 381.
21. L. Petterson, I. L. Anderson and L.-O. Ohman, Inorg. Chem., 1986, 25, 4726.
22. L. A. Combs-Walker and C. L. Hill, Inorg. Chem, 1991, 30, 4016.
23. G. M. Sheldrick, SHELX97, University of Göttingen, Germany, 1997.
24. Determined from the criteria set out in C. W. Haigh, Polyhedron, 1995, 14, 2871.
25. D. A. Johnson, Some Thermodymmic Aspects of Inorganic Chemistry, Cambridge University Press, Cambridge, 2nd edn., 1982.
26. (a) Z. G. Xiao, Q. L. Chen and C. Chen, J. Fujian Teach. Univ. Nat. Sci. Ed., 1986, 2, 77;
27. (b) R. Massart, R. Contant, J.-P. Ciabrini and M. Fournier, Inorg. Chem., 1977, 16, 2916;
28. (c) C. R. Rocchiccioli-Deltcheffand R. Thouvenot, J. Chem. Res., Synop., 1977, 46.
29. C. Rocchiccioli-Deltcheff, M. Fournier, R. Frank and R. Thouvenot, Inorg. Chem., 1983, 22, 207.
30. C. Den Auwer, M. C. Charbonnel, M. G. B. Drew, M. Grigoriev, M. J. Hudson, B. P. Iveson, C. Madic, M. Nierlich, M. T. Presson, R. Revel, M. L. Russell and P. Thuery, Inorg. Chem., 2000, 39, 1487.
31. M. A. Fedotov, B. Z. Pertsikov and D. K. Danovich, Polyhedron, 1990, 9, 1249.
32. A. Ostuni, R. E. Bachman and M. T. Pope, J. Cluster Sci. 2003, 14, 431.
33. R. M. Golding and M. P. Halton, Aust. J. Chem., 1972, 25, 2577.
34. B. Bleaney, J. Magn. Reson., 1972, 8, 91.
35. A. D. Sherry, P. P. Yang and L. O. Morgan, J. Am. Chem. Soc., 1980, 102, 5755.
36. See, for example: (a) S. Rigault and C. Piguet, J. Am. Chem. Soc., 2000, 122, 9304; (b) D. P. Arnold and J. Jiang, J. Phys. Chem. A, 2001, 105, 7525; (c) C. Platas, F. Avecilla, A. de Blas, C. F. G. C. Geraldes and T. Rodriguez-Blas, Inorg. Chem., 1999, 38, 3190;
37. See, for example: (a) S. Rigault and C. Piguet, J. Am. Chem. Soc., 2000, 122, 9304; (b) D. P. Arnold and J. Jiang, J. Phys. Chem. A, 2001, 105, 7525; (c) C. Platas, F. Avecilla, A. de Blas, C. F. G. C. Geraldes and T. Rodriguez-Blas, Inorg. Chem., 1999, 38, 3190;
38. See, for example: (a) S. Rigault and C. Piguet, J. Am. Chem. Soc., 2000, 122, 9304; (b) D. P. Arnold and J. Jiang, J. Phys. Chem. A, 2001, 105, 7525; (c) C. Platas, F. Avecilla, A. de Blas, C. F. G. C. Geraldes and T. Rodriguez-Blas, Inorg. Chem., 1999, 38, 3190;
39. (d) N. Ouali, J.-P. Rivera, P.-Y. Morgantini, J. Weber and C. Piguet, Dalton Trans., 2003, 1251.