Use of lipophilic ion adsorption isotherms to determine the surface area and the monolayer capacity of a chromatographic packing, as well as the thermodynamic equilibrium constant for its adsorption

Journal of Chromatography A

Volumn 1072, Issue 2, 2005, Pages 201-206

  Cecchi, T ^a  

^a ITIS Montani   (Italy)

Author keywords

Adsorption isotherms; Chromatographically accessible area; LC; Monolayer capacity; Surface potential; Thermodynamic equilibrium constant

Indexed keywords

ADSORPTION ISOTHERMS; ELECTROSTATICS; FREE ENERGY; THERMODYNAMICS;

LIPOPHILIC ION ADSORPTION; LIPOPHILIC ION ADSORPTION ISOTHERMS; MONOLAYER CAPACITY; RETENTION EQUATIONS;

CHROMATOGRAPHIC ANALYSIS;

AMPHOPHILE; ION;

ADSORPTION; ANALYTIC METHOD; ARTICLE; CHROMATOGRAPHY; ENERGY; EQUILIBRIUM CONSTANT; ISOTHERM; LIPOPHILICITY; MATHEMATICAL ANALYSIS; MOLECULAR INTERACTION; PRIORITY JOURNAL; RELIABILITY; STANDARD; THEORETICAL STUDY; THERMODYNAMICS; VALIDATION PROCESS;

EID: 17044431776     PISSN: 00219673     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chroma.2005.03.022     Document Type: Article

References (22)

1. D. Farin, A. Volgert, and D. Avnir J. Am. Chem. Soc. 107 1985 3368
2. T. Cecchi, F. Pucciarelli, and P. Passamonti Anal. Chem. 73 2001 2632
3. T. Cecchi J. Chromatogr. A 958 2002 51
4. T. Cecchi, F. Pucciarelli, and P. Passamonti Cromatographia 58 2003 411
5. T. Cecchi, in: J. Cazes (Ed.), Dekker Encyclopedia of Chromatography, Marcel Dekker Inc, New York, DOI:10.1081/E-ECHR-120040673 copyright 2004.
6. T. Cecchi, F. Pucciarelli, and P. Passamonti Analyst 129 2004 1037 (Article B404721D available http://www.rsc.org/is/journals/current/analyst/ anlpub.htm)
7. J. Stahlberg, and A. Bartha J. Chromatogr. 456 1988 253
8. A. Bartha, Gy. Vigh, H.A.H. Billiet, and L. De Galan J. Chromatogr. 303 1984 29
9. R.S. Deelder, and J.H.M. Van Der Berg J. Chromatogr. 218 1981 327
10. A. Bartha, and J. Stahlberg J. Chromatogr. A 668 1994 255
11. J.H. Knox, and R.A. Hartwick J. Chromatogr. 204 1981 3
12. I. Hagglund, and J. Stahlberg J. Chromatogr. A 761 1997 13
13. J. Stahlberg J. Chromatogr. A 855 1999 3
14. T.L. Niederhauser, R.A. Lochhead, D.H. Scoville, and J.D. Lamb J. Chromatogr. A 982 2002 49
15. J.T. Davies, and E.K. Rideal Interfacial Phenomena 1961 Academic Press New York and London (Chapter 4)
16. S.G. Weber Talanta 36 1989 99
17. D.J. Snaw Introduction to Colloid and Surface Chemistry second ed. 1970 Butterworth London, UK (Chapters 5 and 7)
18. M.J. Rosen Surfactant and Interfacial Phenomena 1978 Wiley New York (Chapter 2)
19. F.F. Cantwell, and S. Puon Anal. Chem. 51 1979 623
20. W. Hertl, and M.G. Neuman J. Chromatogr. 60 1971 319
21. O.L. Hollis J. Chromatogr. Sci. 11 1973 335
22. J. Rouquerol, D. Avnir, C.W. Fairbridge, H.E. Everett, J.H. Haynes, N. Pernicone, J.D.F. Ramsey, K.S.W. Sing, and K.K. Unger Pure Appl. Chem. 66 1994 1739