Fluorous distannoxane-catalyzed acetylation of alcohols in heterogeneous single fluorous solvent system

Tetrahedron Letters

Volumn 46, Issue 18, 2005, Pages 3187-3189

  Peng, Zhihong ^a,b   Orita, Akihiro ^b   An, Delie ^a   Otera, Junzo ^b  

^a HUNAN UNIVERSITY   (China)

^b OKAYAMA UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Acetylation; Fluorous distannoxane; Heterogeneous catalysis

Indexed keywords

ACETIC ANHYDRIDE; ALCOHOL DERIVATIVE; ALKANE DERIVATIVE; FLUORINE DERIVATIVE;

ACETYLATION; ARTICLE; CATALYSIS; CATALYST; REACTION ANALYSIS;

EID: 17044398513     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.03.055     Document Type: Article

References (16)

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15. Usually, the catalyst was recovered more than 95% by weight. It is reasonable to assume that the recovery is virtually perfect because a slight loss might be attributed to the small-scale reaction
16. 4, filtered, and evaporated. The combined organic layer was subjected to column chromatography on silica gel to afford 2-phenylethyl acetate (3.15 g, 96%). The recovered FC solution of catalyst 1 was reused for the next acetylation