Kinetics and mechanism of esterification of monoepoxies

Materials and Manufacturing Processes

Volumn 20, Issue 2, 2005, Pages 317-327

  Pal, Neelam ^a   Srivastava, Akanksha ^a   Agrawal, Sudha ^a   Rai, J S P ^a  

^a HARCOURT BUTLER TECHNOLOGICAL INSTITUTE   (India)

Author keywords

Acrylic acid; Activated complex; Energy of activation; Enthalpy; Entropy; Free energy; Frequency factor; Inductive effect; Kinetics; Monoepoxy; Rate constant; Reaction mechanism; Triphenylphosphine esterification; Vinyl ester resins

Indexed keywords

ACRYLICS; ACTIVATION ENERGY; ENTHALPY; ENTROPY; ESTERIFICATION; FREE ENERGY; RATE CONSTANTS; REACTION KINETICS; VINYL RESINS;

ACRYLIC ACID; ACTIVATED COMPLEX; ENERGY OF ACTIVATION; FREQUENCY FACTOR; INDUCTIVE EFFECT; KINETICS; MONOEPOXY; REACTION MECHANISM; TRIPHENYLPHOSPHINE ESTERIFICATION; VINYL ESTER RESINS;

EPOXY RESINS;

EID: 16644402572     PISSN: 10426914     EISSN: None     Source Type: Journal    
DOI: 10.1081/AMP-200042132     Document Type: Review

References (26)

1. Launikitis, M.B. Vinyl ester resins. In Hand Book of Composities; Lubin, G., Ed.; Van Nostran Reinhold Company: New York, 1982; 38-49.
2. Poland, D.E.; Martineau, R.R. FRP in the bottle against acid rain, part-3. Epoxy based vinyl ester resins as materials of constraction. Mater. Process. Tech. Environ. Prot. Min. Metall. Proc. Ibnt. Symp. 1993; Godbehev, P.W., Eds.; Chem. Abstr. 1993, 121, 181350z, 15-163.
3. Poland, D.E.; Martineau, R.R. FRP in the bottle against acid rain, part-3. Epoxy based vinyl ester resins as materials of constraction. Mater. Process. Tech. Environ. Prot. Min. Metall. Proc. Ibnt. Symp. 1993; Godbehev, P.W., Eds.; Chem. Abstr. 1993, 121, 181350z, 15-163.
4. Peng, L.; Xiaoping, Y.; Yunhua, Y.; Dingshing, Y. Cure kinetics, microheterogeneity, and mechanical properties of the high temperature cure of vinyl ester resins. J. Appl. Polym. Sci. 2004, 92 (2), 1124-1133.
5. Amendola, E.; Giamberini, M.; Carfagna, C.; Ambrogi, V. Self-toughening liquid crystalline vinyl ester adhesives. Macromole. Symp. 2002, 780 (1), 153-168.
6. Yamada, K.; Yamane, H.; Kumada, K.; Tanabe, S.; Kajiyama, T. Plasma-graft polymerization of a monomer with double bonds onto the surface of carbon fiber and its adhesion to a vinyl ester resin. J. Appl. Polym. Sci. 2003, 90 (9), 2415-2419.
7. Howell, B.F.; De Realf, Pigmented coatings cured with visible light. Polym. Mater Sci. & Engg. 1996, 74, 387-388.
8. Masujiro, S.; Kazuyoshi, I. Thermosetting Printing Inks. JP 74, 67, 709, July 01, 1974.
9. Macinally, A.; Miller, A. The Use of Epoxy VER System in the Marine, Offshore, Chemical and Construction Industries. Proc. Int. Conf. Fiber Reinf. Compos. 7th 1998; Gibson A.G., Woodhead: Eds.; Combridge, UK, Chem. Abstr. 1998, Vol. 129, 149501d, 3-11.
10. Macinally, A.; Miller, A. The Use of Epoxy VER System in the Marine, Offshore, Chemical and Construction Industries. Proc. Int. Conf. Fiber Reinf. Compos. 7th 1998; Gibson A.G., Woodhead: Eds.; Combridge, UK, Chem. Abstr. 1998, Vol. 129, 149501d, 3-11.
11. Henne, M.; Breyer, G; Niedermeier, M.; Ermanni, P.A. New kinetic and viscosity model for liquid composite molding simulations in an industrial environment. Polym. Comp. 2004, 25 (3), 255-269.
12. da-Silva, A.L.; Teixcira, S.C.S.; Widal, A.C.C.; Coutinho, F.M.B. Mechanical properties of polymer composites based on commercial epoxy vinyl ester resin and glass fiber. Polym. Test. 2001, 20 (8), 895-899.
13. Agrawal, S.; Mishra, A.; Rai, J.S.P. Effect of diluent on the curing behaviour of vinyl ester resin. J. Appl. Polym. Sci. 2003, 87 (12), 1948-1951.
14. Gaur, B.; Rai, J.S.P. Rheological and thermal behaviour of vinyl ester resin. Polym. 1993, 29 (8), 1149-1153.
15. Siva, P.; Verma, I.K.; Patel, D.M.; Sinha, T.J.M. Effect of structure on property of vinyl ester resin. Bull. Mater. Sci. 1994, 17 (6), 1095-1101.
16. Kant, K.; Mishra, A.; Rai, J.S.P. Curing studies on vinyl ester resin using acrylates as reactive diluents. Polym. Inter. 1992, 28, 189-192.
17. Takao, I.; Masao, T.; Akio, S.; Hiroshi, K. Toughining of epoxy resins by modification with reactive elastomers composed by butyl acrylate and glycidyl methacrylate. Eur. Poly. J. 1991, 27(9), 851-858.
18. Abadie, M.J.M.; Mekhissi, K.; Burchill, P.J. Effects of processing conditions on the curing of a vinyl ester resin. J. Appl. Polym. Sci. 2002, 84 (6), 1146-1154.
19. Yukato, G.; Hirofumi, I. Vinyl Ester Polymer Compositions with Good Hot Water Resistance and Discoloration Prevention and Manufacture of Artificial Marble JP 09, 104, 728, April 22, 1997.
20. Agrawal, S.; Singhal, R.; Rai, J.S.P. Curing and rheological behaviour of vinyl ester resins prepared in the presence of tertiary amines. J. Macromol. Sci. Pure & Appl. Chem. 1999, 36 (5-6), 741-757.
21. Matejka, L.; Dusek, K. Specific features of the kinetics of addition esterification of epoxide with the carboxyl group. Polym. Bull. 1986, 75 (3), 215-221.
22. Rao, B.S.; Madec, P.J.; Marechael, E. Synthesis of vinyl ester resins evidence of secondary reactions by C-13NMR. Polm. Bull. 1986, 16 (2-3), 153-157.
23. Peter, M.; Barbara, S.; Ramona, S.; Heike, B. Catalysts for preparation of addition products of epoxide oligomer and methacrylic acid. Ger. Offen. DE 1991, 4, 004, 091. Chem. Abstr. 1991, 115, 233095d
24. Peter, M.; Barbara, S.; Ramona, S.; Heike, B. Catalysts for preparation of addition products of epoxide oligomer and methacrylic acid. Ger. Offen. DE 1991, 4, 004, 091. Chem. Abstr. 1991, 115, 233095d
25. Ogg, C.L.; Porter, W.L.; Willitis, C.O. Ind. Eng. Chem. Anal. Edn. 1945, 17, 394.
26. Odian, G. Step polymerization. In Principals of Polymerization, 2nd Ed.; Wiley Interscience: New York, 1981, 40-178.