High-spin chloro mononuclear MnIII complexes: A multifrequency high-field EPR study

ChemPhysChem

Volumn 6, Issue 3, 2005, Pages 541-546

  Mantel, Claire ^a,b   Chen, Hongyu ^c   Crabtree, Robert H ^c   Brudvig, Gary W ^c   Pécaut, Jacques ^d   Collomb, Marie Noëlle ^b   Duboc, Carole ^a  

^a GRENOBLE HIGH MAGNETIC FIELD LABORATORY   (France)

^b UNIVERSITÉ JOSEPH FOURIER   (France)

^c YALE UNIVERSITY   (United States)

^d DRFMC   (France)

Author keywords

Electronic properties; EPR spectroscopy; Manganese; Multifrequency EPR spectroscopy; N ligands

Indexed keywords

ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC PROPERTIES; FLUORINE COMPOUNDS; LIGANDS; MANGANESE; PARAMAGNETIC RESONANCE; SYNTHESIS (CHEMICAL);

CRYSTALLOGRAPHIC DATA; EPR SPECTROSCOPY; EQUATORIAL LIGANDS; MULTIFREQUENCY EPR; N LIGANDS; N-TRIDENTATE LIGAND; STRUCTURAL CHARACTERIZATION; TETRAGONAL DISTORTION;

MANGANESE COMPOUNDS;

AZIDE; CHLOROMANGANESE; ETHYLAMINE; FLUORIDE; LIGAND; MANGANESE; PYRIDINE; UNCLASSIFIED DRUG; ANION; CHLORINE; ION; MANGANESE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTRON SPIN RESONANCE; X RAY CRYSTALLOGRAPHY; BIOPHYSICS; CHEMICAL MODEL; CHEMISTRY; CONFORMATION; ELECTRON; HYDROGEN BOND; METHODOLOGY; PHYSICAL CHEMISTRY; TEMPERATURE;

ANIONS; BIOPHYSICS; CHEMISTRY, PHYSICAL; CHLORINE; CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; FLUORIDES; HYDROGEN BONDING; IONS; LIGANDS; MANGANESE; MANGANESE COMPOUNDS; MODELS, CHEMICAL; MODELS, MOLECULAR; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; TEMPERATURE;

EID: 16644392752     PISSN: 14394235     EISSN: None     Source Type: Journal    
DOI: 10.1002/cphc.200400484     Document Type: Article

References (31)

1. a) F. J. Yost, I. Fridovich, J. Biol. Chem. 1976, 251, 4905;
2. b) P. Chelikani, I. Fita, P. C. Loewen, Cell. Mol. Life Sci. 2004, 61, 192.
3. a) A. Sorokin, J.-L. Seris, B. Meunier, Science 1995, 268, 1163;
4. b) L. Jun, T. Chao, L. Hao, J. Pengju, D. Jun, G. Zijian, Inorg. Chem. Commun. 2003, 6, 262, and references therein.
5. a) R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature 1993, 365, 141;
6. b) J. Yoo, A. Yamaguchi, M. Nakano, J. Krzystek, W. E. Streib, L.-C. Brunel, H. Ishimoto, G. Christou, D. N. Hendrikson, Inorg. Chem. 2001, 40, 4604.
7. W. R. Hagen, Coord Chem. Rev. 1999, 190-192, 209.
8. J. Krystek, L. A. Pardi, L.-C. Brunel, D. P. Goldberg, B. M. Hoffman, S. Licoccia, J. Telser, Spectrochim. Acta, Part A 2002, 58, 1113.
9. a) A.-L. Barra, D. Gatteschi, R. Sessoli, G.-L. Abatti, A. Cornia, A.-C. Fabretti, M.-G. Uytterhoeven, Angew. Chem. 1997, 109, 2423; Angew. Chem. Int. Ed. 1997, 36, 2329;
10. a) A.-L. Barra, D. Gatteschi, R. Sessoli, G.-L. Abatti, A. Cornia, A.-C. Fabretti, M.-G. Uytterhoeven, Angew. Chem. 1997, 109, 2423; Angew. Chem. Int. Ed. 1997, 36, 2329;
11. b) J. Krzystek, G. J. Yeagle, J.-H. Park, R. D. Britt, M. W. Meisel, L.-C. Brunel, J. Telser, Inorg. Chem. 2003, 42, 4610;
12. c) P. L. W. Tregenna-Piggott, H. Weihe, A.-L. Barra, Inorg. Chem. 2003, 42, 8504.
13. a) J. Limburg, J. S. Vrettos, R. H. Crabtree, G. W. Brudvig, J. C. de Paula, A. Hassan, A.-L. Barra, C. Duboc-Toia, M.-N. Collomb, Inorg. Chem. 2001, 40, 1698;
14. b) C. Mantel, A. K. Hassan, J. Pécaut, A. Deronzier, M.-N. Collomb, C. Duboc, J. Am. Chem. Soc. 2003, 125, 12 337.
15. H. A. Goodwin, R. N. Sylva, Aust. J. Chem. 1967, 20, 629.
16. S. Ganguly, S. Karmakar, A. Chakravorty, Inorg. Chem. 1997, 36, 116.
17. C. Philouze, M. Henry, N. Auger, D. Vignier, M. Lance, M. Nierlich, J.-J. Girerd, Inorg. Chem. 1999, 38, 4.
18. K. R. Reddy, M. V. Rajasekharan, Polyhedron 1994, 13, 765.
19. M. U. Triller, W.-Y. Hsieh, V. L. Pecoraro, A. Rompel, B. Krebs, Inorg. Chem. 2002, 41, 5544.
20. a) R. Guilard, K. Perié, J.-M. Barbe, D. J. Nurco, K. M. Smith, E. van Caemelbecke, K. M. Kadish, Inorg. Chem. 1998, 37, 973;
21. b) A. Panja, N. Shaikh, M. Alhi, P. Vojtisek, P. Banerjee, Polyhedron 2003, 22, 1191, and references therein.
22. C. J. H. Jacobsen, E. Pedersen, J. Villardsen, H. Weihe, Inorg. Chem. 1993, 32, 1216.
23. 2)]l, which has unusual electronic properties (S. Mossin, H. Weihe, A.-L. Barra, J. Am. Chem. Soc. 2002, 124, 8764).
24. C. Mantel, J. Cano, M.-N. Collomb, C. Duboc, unpublished results.
25. G. C. Brackett, P. L. Richard, W. S. Caughey, J. Chem. Phys. 1971, 54, 4383.
26. E. C. Constable, J. Lewis, M. C. Liptrot, P. R. Raithby, Inorg. Chim. Acta 1990, 178, 47.
27. C. Baffert, M.-N. Collomb, A. Deronzier, J. Limburg, G. W. Brudvig, R. H. Crabtree, J. Pécaut, Inorg. Chem. 2002, 41, 1404.
28. a) A.-L. Barra, L.-C. Brunel, J.-B. Robert, Chem. Phys. Lett. 1990, 165, 107;
29. b) F. Muller, M.-A. Hopkins, N. Coron, M. Grynderg, L.-C. Brunel, G. Martinez, Rev. Sci. Instrum. 1989, 60, 3681.
30. SHELXTL-Plus Structure Determination Software Programs (Vers. 5.1), G. M. Sheldric, Bruker-AXS Inc. Madison, WI, 1998.
31. Z. Otwinowski, W. Minor in Methods in Enzymology, Vol. 276, (Eds.: C. W. Carter, Jr., R. M. Sweet), Academic Press, New York, 1997, pp. 307-326.