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Volumn 37, Issue 5, 2004, Pages 1671-1673

Cationic Photopolymerization of an Epoxide by Substituted Phenols as a Novel Nonsalt-Type Photolatent Initiator

Author keywords

[No Author keywords available]

Indexed keywords

ADHESIVES; DISSOCIATION; HEATING; INITIATORS (CHEMICAL); MOLECULAR WEIGHT; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLIGOMERS; PHOTOLYSIS; PHOTOPOLYMERIZATION; POSITIVE IONS; PROTONS; SUBSTITUTION REACTIONS;

EID: 1642619523     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma030398u     Document Type: Article
Times cited : (19)

References (37)
  • 2
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    • Interscience Publishers: New York, 1966; Vol. 4, p 528
    • (a) Mark, H. F., Gaylord, N. G., Bikajes, N. M., Eds. Encycl. Polym. Sci. Technol. 1968, 8, 303; Interscience Publishers: New York, 1966; Vol. 4, p 528.
  • 27
    • 0033749506 scopus 로고    scopus 로고
    • and references cited therein
    • (d) Kim, M.; Sanda, F.; Endo, T. Macromolecules 2000, 33, 3499 and references cited therein.
    • (2000) Macromolecules , vol.33 , pp. 3499
    • Kim, M.1    Sanda, F.2    Endo, T.3
  • 32
    • 1642633238 scopus 로고    scopus 로고
    • note
    • n-1Y and a proton, which should actually exist as a protonic acid in the reaction system. The protonic acid ultimately behaves as the predominant active species initiating cationic polymerizations (Scheme 3).
  • 33
    • 1642617769 scopus 로고    scopus 로고
    • note
    • The terminal end group of the resulting polymer is expected to be the corresponding substituted phenoxy group and/or hydroxyl one derived from (residual) moisture, but it was not clearly observed at this stage in the NMR measurement due to overlap of phenoxy unit based on poly(GPE).
  • 34
    • 0034743081 scopus 로고    scopus 로고
    • Excited-state intramolecular proton transfer is one of an important photochemical process, and many investigations have been widely carried out experimentally and theoretically: (a) Vargas, V.; Amigo, L. J. Chem. Soc., Perkin Trans. 2 2001, 1124.
    • (2001) J. Chem. Soc., Perkin Trans. , vol.2 , pp. 1124
    • Vargas, V.1    Amigo, L.2
  • 36
    • 0037077666 scopus 로고    scopus 로고
    • and references cited therein
    • (c) Lukeman, M.; Wan, P. J. Am. Chem. Soc. 2002, 124, 9458 and references cited therein.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 9458
    • Lukeman, M.1    Wan, P.2
  • 37
    • 1642617768 scopus 로고    scopus 로고
    • a is 2.8 in aqueous solution; see ref 10
    • a is 2.8 in aqueous solution; see ref 10.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.