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1642633238
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note
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n-1Y and a proton, which should actually exist as a protonic acid in the reaction system. The protonic acid ultimately behaves as the predominant active species initiating cationic polymerizations (Scheme 3).
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33
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1642617769
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note
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The terminal end group of the resulting polymer is expected to be the corresponding substituted phenoxy group and/or hydroxyl one derived from (residual) moisture, but it was not clearly observed at this stage in the NMR measurement due to overlap of phenoxy unit based on poly(GPE).
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34
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0034743081
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Excited-state intramolecular proton transfer is one of an important photochemical process, and many investigations have been widely carried out experimentally and theoretically: (a) Vargas, V.; Amigo, L. J. Chem. Soc., Perkin Trans. 2 2001, 1124.
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Lukeman, M.1
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37
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1642617768
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a is 2.8 in aqueous solution; see ref 10
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a is 2.8 in aqueous solution; see ref 10.
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