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It is also possible to devise mechanisms for the conversion of 7 to 1 that involve migration of tungsten instead of the intermediacy of 8. However, isolation of the isomeric metallacycle 5 from this system lends credence to the transient existence of 8
-
It is also possible to devise mechanisms for the conversion of 7 to 1 that involve migration of tungsten instead of the intermediacy of 8. However, isolation of the isomeric metallacycle 5 from this system lends credence to the transient existence of 8.
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85087250228
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note
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5 provides support for cleavage from the excited state.
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48
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Sheldrick, G.M.1
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