Cobalt-catalyzed synthesis of ε-caprolactam and nylon-6 from aminopentene and carbon monoxide

Journal of Molecular Catalysis A: Chemical

Volumn 210, Issue 1-2, 2004, Pages 69-77

  Liu, Shengsheng ^a   Sen, Ayusman ^a   Parton, Rudy ^b  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

^b DSM RESEARCH   (Netherlands)

Author keywords

Aminopentene; Caprolactam; Carbon monoxide; Carbonylation; Catalysis; Cobalt; Nylon 6

Indexed keywords

AMINES; CARBON MONOXIDE; COBALT; ISOMERIZATION; NYLON POLYMERS; OLIGOMERS; SYNTHESIS (CHEMICAL);

VOLATILE FRACTION;

CATALYSIS;

3 ETHYL 2 PYRROLIDINONE; 3 METHYL 2 PIPERIDINONE; 3 PENTEN 1 AMINE; 4 PENTEN 1 AMINE; ALKENE DERIVATIVE; AMINOPENTENE; CAPROLACTAM; CARBON MONOXIDE; COBALT; LIGAND; NYLON; OLIGOMER; PIPERIDONE DERIVATIVE; PYRROLIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; ISOMERIZATION; SOLID; STEREOCHEMISTRY; SYNTHESIS; VOLATILIZATION;

EID: 1642574280     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2003.09.011     Document Type: Article

References (11)

1. M.I. Kohan (Ed.), Nylon Plastics Handbook, Hanser/Gardner, Cincinnati, OH, 1995.
2. R. Puffr, V. Kubánek (Eds.), Lactam-based polyamides, CRC Press, Boca Raton, FL, 1991.
3. Zimmermann B., Herwig J., Beller M. Angew. Chem. Int. Ed. 38:1999;2372.
4. Falbe J., Korte F. Chem. Ber. 98:1965;1928.
5. Falbe J., Korte F. Angew. Chem. Int. Ed. Eng. 1:1962;266.
6. A. Göbel, W. Imhof, Chem. Commun. (2001) 593.
7. D. Berger, W. Imhof, Chem. Commun. (1999) 1457.
8. Chatani N., Kamitani A., Murai S. J. Org. Chem. 67:2002;7014.
9. Gagné M.R., Stern C.L., Marks T.J. J. Am. Chem. Soc. 114:1992;275.
10. Reddy P.A., Hsiang B.C.H., Latifi T.N., Hill M.W., Woodward K.E., Rothman S.M., Ferrendelli J.A., Covey D.F. J. Med. Chem. 39:1996;1898.
11. Menezes R., Smith M.B. Synth. Commun. 18:1988;1625.