Ethene/1,3-butadiene copolymerization in the presence of rac-(CH2-(3-tert-butyl-1-indenyl)2)ZrCl2/MAO catalytic system: Study of the polymerization mechanism by using 13C-labeled 1,3-butadiene

Macromolecules

Volumn 37, Issue 1, 2004, Pages 238-240

  Pragliola, Stefania ^a   Costabile, Chiara ^a   Magrino, Mariateresa ^a   Napoli, Mariagrazia ^a   Longo, Pasquale ^a  

^a UNIVERSITY OF SALERNO   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; CARBON; CATALYSTS; CHEMICAL BONDS; MICROSTRUCTURE; NUCLEAR MAGNETIC RESONANCE; POLYBUTADIENES; POLYETHYLENES; REACTION KINETICS; ZIRCONIUM COMPOUNDS;

CYCLOPENTANE; CYCLOPROPANE; ZIEGLER NATTA CATALYTIC SYSTEMS;

COPOLYMERIZATION;

EID: 1642496760     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0351064     Document Type: Article

References (12)

1. Brintzinger, H. H.; Fischer, D.; Mulhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143.
2. Resconi, L.; Cavallo, L.; Fait, A.; Piemontesi, F. Chem. Rev. 2000, 100, 1253.
3. Zambelli, A.; Ammendola, P.; Grassi, A.; Longo, P.; Proto, A. Macromolecules 1986, 19, 2703-2706.
4. Longo, P.; Grassi, A.; Pellecchia, C.; Zambelli, A. Macromolecules 1987, 20, 1015-1018.
5. Guerra, G.; Longo, P.; Cavallo, L.; Corradini, P.; Resconi, L. J. Am. Chem. Soc. 1997, 119, 4394-4403.
6. Resconi, L.; Balboni, D.; Baruzzi, G.; Fiori, C.; Guidotti, S.; Mercandelli, P.; Sironi, A. Organometallics 2000, 19, 420-429.
7. Pragliola, S.; Milano, G.; Guerra, G.; Longo, P. J. Am. Chem. Soc. 2002, 124, 3502-3503.
8. Longo, P.; Pragliola, S.; Milano, G.; Guerra, G. J. Am. Chem. Soc. 2003, 125, 4799-4803.
9. 13C NMR spectra of copolymers with those of 1,4-trans and 1,2-poly-(E)-1,3-pentadiene units which present the same stereostructures.
10. Longo, P.; Napoli, M.; Pragliola, S.; Costabile, C.; Milano, G.; Guerra, G. Macromolecules 2003, 36, 9067-9074.
11. Ropp, G. A.; Raaen, V. F. J. Am. Chem. Soc. 1954, 76, 4484.
12. Furniss, B.; Hannaford, A. J.; Smith, P. W. G.; Tatchell, A. R. In Vogel's: Textbook of Practical Organic Chemistry, 5th ed.; Longman Scientific & Technical: Essex, UK, 1989; p 491.