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2, 70:30 (v/v). Note that piranha solution is a very strong oxidant and is dangerous to handle without gloves, goggles, and a face shield. The SAMs were formed by soaking the substrates in 0.1 M ethanolic solutions of 11-mercaptodecanoic acid for 4 h. These were dried under nitrogen. The monolayer of Mn-12 was formed by soaking the SAMs substrate in a 1 mM solution of Mn-12 in ethanol for 15 min.
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2 for 10-MHz quartz.
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1642481466
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note
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3 and knowing the molecular weight of the polymer, we found the thickness of the first layer to be 8 Å.
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28
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See, for example, (a) Ruis, D.; Sun, Z.; Albela, Folting, K.; Ribas, R.; Christou, G.; Hendrickson, D. Angew. Chem., Int. Ed. 1998, 37, 300. (b) An, J.; Chen, Z.-D.; Bian, J.; Chen, J.-T.; Wang, S. X.; Gao, S.; Xu, G. X. Inorg. Chim. Acta 2000, 299, 28. (c) Sessoli, R.; Tsai, H. L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804.
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