Synthesis of trifunctional ligands containing thiophosphoryl, pyridine and pyridine N-oxide donor groups

Dalton Transactions

Volumn , Issue 24, 2003, Pages 4704-4708

  Gan, Xin Min ^a   Duesler, Eileen N ^a   Parveen, Sahrah ^a   Paine, Robert T ^a  

^a UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

INFRARED SPECTROSCOPY; MIXING; MOLECULAR STRUCTURE; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

PYRIDINE; PYRIDINE OXIDE; THIOPHOSPHORYL; TRIFUNCTIONAL LIGANDS;

ORGANIC COMPOUNDS;

EID: 1642460183     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b309336k     Document Type: Article

References (35)

1. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Pergamon, Oxford, 1984.
2. K. L. Nash, Handbook on the Physics and Chemistry of Rare Earths-Lanthanide and Actinide Chemistry; ed. K. A. Gschneidner, L. Eyring, G. R. Choppin and G. H. Lander, Elsevier, New York, 1994, vol. 18
3. R. D. Hancock and A. E. Martell, Chem. Rev., 1989, 89, 1875.
4. X. Gan, E. N. Duesler and R. T. Paine, Inorg. Chem., 2001, 40, 4420.
5. B. M. Rapko, E. N. Duesler, B. H. Smith, R. T. Paine and R. R. Ryan, Inorg. Chem., 1993, 32, 2164
6. R. T. Paine in Separations of f Elements, ed. K. L. Nash and G. R. Choppin, Plenum, New York, 1995, p. 63.
7. E. M. Bond, unpublished results.
8. K. L. Nash, C. Lavallette, M. Borkowski, R. T. Paine and X. Gan, Inorg. Chem., 2002, 41, 5849.
9. J. Yao, R. M. Wharf and G. R. Choppin, in Separations of f Elements, ed. K. L. Nash and G. R. Choppin, Plenum, New York, 1995, p. 31.
10. C. Musikas, G. LeMarois, R. Fittoussi and C. Cuillerdier, Actinide Sep., ACS Symp. Ser., 1980, 117, 130.
11. D. D. Ensor, G. D. Jarvinen and B. F. Smith, Solv. Extr. Ion Exch., 1988, 6, 439
12. B. F. Smith, G. D. Jarvinen, M. M. Jones and P. J. Hay, Solv. Extr. Ion Exch., 1989, 7, 749.
13. Z. Kolarik and U. Mllich, Solv. Extr. Ion Exch., 1997, 15, 361.
14. Y. Zhu, Radiochim. Acta, 1995, 68, 95.
15. Y. Zhu and J. Chen, Solv. Extr. Ion Exch., 1996, 14, 61.
16. G. Tian, Y. Zhu and J. Xu, Solv. Extr. Ion Exch., 2001, 19, 993.
17. A. Albini and S. Pietra, Heterocyclic N-Oxides, CRC Press, Boca Raton, FL, 1991, p. 120, and references therein.
18. N. G. Zabirov, R. A. Cherkasov, I. S. Khalikov and A. N. Pudovik, Zh. Obshch. Khim, 1989, 59, 1493.
19. S. Rashad, A. A. El-Kateb and F. H. Osman, Chem. Ind. (London), 1984, 553.
20. The synthesis and purification schemes for 1b and 2b were not optimized since the tolyl substituents did not significantly enhance the organic solvent solubilities compared to 1a and 2a.
21. Compounds 1b and 1c consistently gave carbon analytical results that suggested the presence of minor impurities or incomplete combustion. Carbon analyses for some other pyridylphosphine oxides prepared in our group have provided similar low carbon contents and it is generally thought that this results from incomplete combustion.
22. D. E. C. Corbridge, Top. Phosphorus Chem, 1969, 6, 235.
23. S. M. Nelson, M. Perks and B. J. Walker, J. Chem. Soc. A, 1976, 1205.
24. M. M. Crutchfield, C. H. Dungan, J. M. Letcher, V. Mark and J. R. VanWazer, Top. Phosphorus Chem., 1967, 5, 365.
25. L. Sacconi, F. Mani and A. Bencini, Comprehensive Coordination Chemistry, ed. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Perganon Press, New York, 1987, vol. 5, p. 86.
26. J. T. Mague and J. L. Krinsky, Inorg. Chem., 2001, 40, 1962.
27. I. Garcia, E. Bermejo, A. K. El Sawaf, A. Castiñeiras and D. X. West, Polyhedron, 2002, 21, 729.
28. Y.-C. Tan, X.-M. Gan, J. L. Stanchfield, E. N. Duesler and R. T. Paine, Inorg. Chem., 2001, 40, 2910.
29. J. H. Matonic, M. P. Neu, A. E. Enriquez, R. T. Paine and B. L. Scott, J. Chem. Soc., Dalton Trans., 2002, 2328.
30. B. Rezzonico and M. Grignon-Dubois, J. Chem. Res. (S), 1994, 142.
31. 2 solution was evaporated leaving 2,6-dichloromehylpyridine N-oxide as a white solid. Yield: 6.0 g (92%).
32. M. J. Chetcuti, M. H. Chisholm, K. Folting, D. A. Haitko, J. C. Huffman and J. Janos, J. Am. Chem. Soc., 1983, 105, 1163.
33. Data collection, cell refinement and data reduction used XSCANS, Version 2.10, Siemens, 1994.
34. Absorption correction XPREP, Version 5.03, Siemens, 1994.
35. G. M. Sheldrick, SHELXL-97 Programs for the Refinement of Crystal Structures, University of Gottingen, Germany, 1997.