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Comparing the luminescence of tcp and ccp with that of cp, the most noticeable change is the large red shift. This behaviour is typical of eximer formation (see, for example: A. Gilbert and J. Baggot, Essential of Molecular Photochemistry, Blackwell Scientific Publications, Oxford, 1981;). The difference in intensity can be attributed to the change of the nature and energy of the lowest excited state.
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27
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28
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