Synthesis of 1,9-bis[glycidyloxypropyl]penta(1′H,1′H,2′H, 2′H-perfluoroalkylmethylsiloxane)s and copolymerization with piperazine

Polymer

Volumn 45, Issue 8, 2004, Pages 2517-2523

  Grunlan, Melissa A ^a   Lee, Nam S ^a   Weber, William P ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

Copoly(carbosiloxane); Fluoro; Piperazine

Indexed keywords

CATALYSIS; CHROMATOGRAPHY; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE; PLATINUM; SYNTHESIS (CHEMICAL);

HYDROSILYLATION; THERMAL PROPERTIES;

ORGANIC POLYMERS;

1,9 BIS(GLYCIDYLOXYPROPYL) 3,5,7 TRIS(1'H,1'H,2'H,2'H PERFLUOROOCTYL)HEPTAMETHYLPENTASILOXANE; 1,9 BIS(GLYCIDYLOXYPROPYL) 3,5,7 TRIS(3',3',3' TRIFLUOROPROPYL)HEPTAMETHYLPENTASILOXANE; 1,9 BIS(GLYCIDYLOXYPROPYL)DECAMETHYLPENTASILOXANE; 1,9 DIHYDRIDODECAMETHYLPENTASILOXANE; 1,9 DIHYDRO 3,5,7 TRIS(1'H,1'H,2'H,2'H PERFLUOROOCTYL)HEPTAMETHYLPENTASILOXANE; 1,9 DIHYDRO 3,5,7 TRIS(3',3',3' TRIFLUOROPROPYL)HEPTAMETHYLPENTASILOXANE; ALLYL ALCOHOL; CARBON 13; ETHER DERIVATIVE; FLUORINE; PIPERAZINE; PROTON; SILICON DERIVATIVE; SILOXANE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; DIFFERENTIAL SCANNING CALORIMETRY; GEL PERMEATION CHROMATOGRAPHY; HYDROSILYLATION; INFRARED SPECTROSCOPY; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS; THERMAL ANALYSIS; THERMOGRAVIMETRY;

POLYMER;

EID: 1642413481     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2004.02.029     Document Type: Article

References (34)

1. Interrante L.V., Shen Q. Polycarbosilanes. Jones R.G., Ando W., Chojnowski J. Silicon-containing polymers. 2000;309 Kluwer, Netherlands.
2. Speier J.L. Adv Organomet Chem. 17:1979;407.
3. Andrianov K.A., Gavrikova L.A., Rodionova Y.F. Polym Chem USSR. A13:1971;1057.
4. Grunlan M.A., Mabry J.M., Weber W.P. Polymer. 44:2003;981.
5. Paulasaari J.K., Weber W.P. Macromolecules. 32:1999;5217.
6. Paulasaari J.K., Weber W.P. Macromolecules. 31:1998;7105.
7. Dvornic P.R., Gerov V.V., Govedarica M.N. Marcromolecules. 27:1994;7575.
8. Mathias L.J., Lewis C.M. Macromolecules. 26:1993;4070.
9. Hu J., Son D.Y. Polym Prepr. 39-I:1998;567.
10. Karstedt BD. US Patent 3 775 452; 1973.
11. Weber W.P. Silicon reagents for organic synthesis. 1983;Springer, Berlin. p. 86-7.
12. Smith D.W., Wagener K.B. Macromolecules. 26:1993;1633.
13. Riffle J.S., Yilgor I., Tran C., Wilkes G.L., McGrath J.E., Banthia A.K. Elastomeric polysiloxane modifiers for epoxy networks. Bauer R.S. Epoxy resin chemistry II. ACS symposium series 221. 1983;21-54 American Chemical Society, Washington, DC.
14. Kajiyama M., Kakimoto M., Imai Y. J Appl Polym Sci. 39:1990;1699.
15. Dvornic P.R. Thermal properties of siloxanes. Jones R.G., Ando W., Chojnowski J. Silicon-containing polymers. 2000;195 Kluwer, Netherlands.
16. Dvornic P.R. Thermal properties of siloxanes. Jones R.G., Ando W., Chojnowski J. Silicon-containing polymers. 2000;185 Kluwer, Netherlands.
17. Odian G. Principles of polymerization. 3rd ed. 1991;Wiley, New York. p. 138.
18. Odian G. Principles of polymerization. 3rd ed. 1991;Wiley, New York. p. 313.
19. Maxson M.T., Norris A.W., Owen M.J. Fluorosilicones. Scheirs J. Wiley series in polymer science. 1997;360 Wiley, Chichester.
20. Wicks Z.W., Jones F.N., Pappas S.P. Organic coatings: science and technology. vol. II:1994;163 Wiley, New York.
21. Salame M., Temple E.J. Adv Chem. 135:1974;61.
22. Odian G. Principles of polymerization. 3rd ed. 1991;Wiley, New York. p. 32.
23. Jiangnan G., Shangxian Y., Shunji J., Yalin W. J Photopolym Sci Technol. 1:1988;212.
24. Pierce O.R. Appl Polym Symp. 14:1970;7.
25. Mabry J.M., Paulasaari J.K., Weber W.P. Polymer. 41:2000;4423.
26. Grunlan M.A., Lee N.S., Cai G., Gädda T., Mabry J.M., Mansfeld F., Kus E., Wendt D.E., Kowalke G.L., Finlay J.A., Callow J.A., Callow M.E., Weber W.P. Chem Mater. 2003;. Submitted for publication.
27. Aston J.G., Szabz G.J., Fink J.L. J Am Chem Soc. 65:1943;1135.
28. Paulasaari JK. PhD Thesis, U of Southern California, Los Angeles, CA, 1999; p.194.
29. Paulasaari JK. PhD Thesis, U of Southern California, Los Angeles, CA, 1999; p.195.
30. Odian G. Principles of polymerization. 3rd ed. 1991;Wiley, New York. p. 78.
31. Wicks Z.W., Jones F.N., Pappas S.P. Organic coatings: science and technology. vol. II:1994;24 Wiley, New York.
32. Andrews R.J., Grulke E.A. Brandrup J., Immergut E.H., Grulke E.A. 4th ed. Polymer handbook. 1999;VI-231.
33. Stern S.A., Shah V.M., Hardy B.J. J Polym Sci, Polym Phys Ed. 25:1987;1263.
34. Knight G.J., Wright W.W. Br Polym J. 21:1989;199.