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(a) Arikawa, Y.; Nishimura, Y.; Kawano, H.; Onishi, M. Organometallics 2003, 22, 3354-3356.
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Arikawa, Y.1
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14
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1642397153
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note
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3N and catalytic amounts of CuI.
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-
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15
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1642363051
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note
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4 at 60 °C for 1 h, while the ratio of diastereoisomers 2 (1:1) was changed to 3.4:1, that of 2* varied from 1:1 to 2.1:1. The marked difference in steric effect between the two sets of diastereomers (i.e., with and without 4-Me substituent) was not observed.
-
-
-
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16
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1642367986
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-
note
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W) = 0.038 (0.059) for 343 variables and 6060 unique reflections (all data).
-
-
-
-
17
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-
1642343529
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-
note
-
W) = 0.176 (0.206) for 325 variables and 6122 unique reflections (all data).
-
-
-
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18
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-
1642348406
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-
note
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2Ph)(NO), was not detected in any reactions.
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19
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5244284889
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(a) Bruce, M. I. Chem. Rev. 1991, 91, 197-257.
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(1991)
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Bruce, M.I.1
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20
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0035948515
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(b) Menéndez, C.; Morales, D.; Pérez, J.; Riera, V.; Miguel, D. Organometallics 2001, 20, 2775-2781.
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Menéndez, C.1
Morales, D.2
Pérez, J.3
Riera, V.4
Miguel, D.5
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21
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1642302931
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note
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2O to the α carbon proceeded, the organic product, 2,4-diphenyl-3-butynal, could be released.
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-
-
-
22
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1642307739
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note
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Formation of a ruthenacyclopentatriene intermediate also cannot be ruled out at the present stage, as another possible route for 2. See ref 1g.
-
-
-
-
23
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1642278493
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-
note
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Treatment of the mono(alkynyl) complex TpRuCl(C≡CPh)(NO) with HC≡CC(O)OMe gave rise to the similar ene-yne complex, TpRuCl[C{C(O)OMe}=CH(C≡CPh)](NO). This complex, where the alkynyl part has no interaction with the metal center, was not hydrated.
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24
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0037148214
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Ogata, K.; Kuge, K.; Tatsumi, K.; Yamamoto, Y. Chem. Commun. 2002, 128-129.
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Ogata, K.1
Kuge, K.2
Tatsumi, K.3
Yamamoto, Y.4
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