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Volumn 126, Issue 12, 2004, Pages 3706-3707

Hydration of Nitrosylruthenium Bis(alkyayl) Complexes with Hydrotris(pyrazolyl)borate: Insertion/Hydration and Double Hydration Products

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNYL GROUP; BORIC ACID; CYCLOPENTENONE DERIVATIVE; HYDROTRIS(PYRAZOLYL)BORATE; KETONE; METAL DERIVATIVE; NITROSO DERIVATIVE; NITROSYLRUTHENIUM COMPLEX; RUTHENIUM COMPLEX; SOLVENT; UNCLASSIFIED DRUG; WATER;

EID: 1642386707     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039365k     Document Type: Article
Times cited : (28)

References (24)
  • 6
    • 0346754826 scopus 로고    scopus 로고
    • (f) Bruce, M. I. Chem. Rev. 1998, 98, 2797-2858.
    • (1998) Chem. Rev. , vol.98 , pp. 2797-2858
    • Bruce, M.I.1
  • 14
    • 1642397153 scopus 로고    scopus 로고
    • note
    • 3N and catalytic amounts of CuI.
  • 15
    • 1642363051 scopus 로고    scopus 로고
    • note
    • 4 at 60 °C for 1 h, while the ratio of diastereoisomers 2 (1:1) was changed to 3.4:1, that of 2* varied from 1:1 to 2.1:1. The marked difference in steric effect between the two sets of diastereomers (i.e., with and without 4-Me substituent) was not observed.
  • 16
    • 1642367986 scopus 로고    scopus 로고
    • note
    • W) = 0.038 (0.059) for 343 variables and 6060 unique reflections (all data).
  • 17
    • 1642343529 scopus 로고    scopus 로고
    • note
    • W) = 0.176 (0.206) for 325 variables and 6122 unique reflections (all data).
  • 18
    • 1642348406 scopus 로고    scopus 로고
    • note
    • 2Ph)(NO), was not detected in any reactions.
  • 19
  • 21
    • 1642302931 scopus 로고    scopus 로고
    • note
    • 2O to the α carbon proceeded, the organic product, 2,4-diphenyl-3-butynal, could be released.
  • 22
    • 1642307739 scopus 로고    scopus 로고
    • note
    • Formation of a ruthenacyclopentatriene intermediate also cannot be ruled out at the present stage, as another possible route for 2. See ref 1g.
  • 23
    • 1642278493 scopus 로고    scopus 로고
    • note
    • Treatment of the mono(alkynyl) complex TpRuCl(C≡CPh)(NO) with HC≡CC(O)OMe gave rise to the similar ene-yne complex, TpRuCl[C{C(O)OMe}=CH(C≡CPh)](NO). This complex, where the alkynyl part has no interaction with the metal center, was not hydrated.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.