Synthesis and structure of the incomplete cuboidal clusters [W3Se4H3(dmpe)3]+, [W3Se4H3−x(OH)x(dmpe)3]+ and [W3Se4(OH)3(dmpe)3]+, and the mechanism of the acid-assisted substitution of the coordinated hydrides

Journal of the Chemical Society. Dalton Transactions

Volumn 4, Issue 4, 2004, Pages 530-536

  Basallote, Manuel G ^a   Estevan, Francisco ^b   Feliz, Marta ^c   Jesus Fernandez Trujillo M ^a   Hoyos, Dora A ^d   Llusar, Rosa ^c   Uriel, Santiago ^e   Vicent, Cristian ^c  

^a UNIVERSITY OF CÁDIZ   (Spain)

^b UNIVERSITY OF VALENCIA   (Spain)

^c UNIVERSITAT JAUME I   (Spain)

^d UNIVERSIDAD DE ANTIOQUIA   (Colombia)

^e UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

Clusters; Hydrides; Kinetics; Mechanisms in solution; P, N, S, Se, O, Te, Si containing ligands

Indexed keywords

ACID; ORGANOMETALLIC COMPOUND; SELENIUM; TUNGSTEN;

ARTICLE; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; KINETICS; SYNTHESIS; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

ACIDS; CRYSTALLOGRAPHY, X-RAY; KINETICS; MODELS, CHEMICAL; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; SELENIUM; TEMPERATURE; TUNGSTEN;

CARRIER CONCENTRATION; CATALYSIS; CRYSTALLIZATION; MOLECULAR STRUCTURE; NEGATIVE IONS; OXIDATION; RATE CONSTANTS; REDUCTION; SOLUTIONS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

ACID-ASSISTED SUBSTITUTION; CUBOIDAL CLUSTERS;

TUNGSTEN COMPOUNDS;

EID: 1642347643     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b315841a     Document Type: Article

References (33)

1. P. Braunstein and J. Rosé, Metal Clusters in Chemistry, ed. P. Braunstein and L. Oro, Wiley–VCH, Weinheim, (1999), ch. 2:, p. 616.
2. M. Brörson, J.D. King, K. Kiriakidou, F. Prestopino and E. Nordlander, Metal Clusters in Chemistry, ed. P. Braunstein and L. Oro, Wiley–VCH, Weinheim, (1999), ch. 2:, p. 741.
3. E.I. Stiefel and K. Matsumoto, Transition Metal Sulfur Chemistry, Honolulu, Hawai, (1995)
4. D.C. Rees, M.K. Chan, J. Kim: Adv. Inorg. Chem (1994), 40: 89.
5. T. Shibahara: Coord. Chem. Rev. (1993), 123: 73.
6. R. Llusar, S. Uriel: Eur. J. Inorg. Chem. (2003), 1271.
7. D.T. Richens, P.A. Pittet, A.E. Merbach, M. Humanes, G.J. Lamprecht, B.L. Ooi, A.G. Sykes: J. Chem. Soc., Dalton Trans. (1993), 2305.
8. B.L. Ooi, M. Martinez, A.G. Sykes: J. Chem. Soc., Chem Commun. (1988), 1324.
9. Y.L. Li, C.A. Routledge, A.G. Sykes: Inorg. Chem. (1991), 30: 5043.
10. R. Hernández-Molina, A.G. Sykes: J. Chem. Soc., Dalton Trans. (1999), 3137.
11. M.G. Basallote, M. Feliz, M.J. Fernandez-Trujillo, R. Llusar, V.S. Safont, S. Uriel: Chem. Eur. J. (2003), in press.
12. R. Llusar, S. Uriel, C. Vicent: J. Chem. Soc., Dalton Trans. (2001), 2813.
13. Bruker Analytical X-Ray Systems, SAINT, 6.2, Madison, WI, (2001)
14. G.M. Sheldrick, SADABS Empirical Absorption Program, University of Göttingen, (2001)
15. G.M. Sheldrick, SHELXTL, 5.1, Madison, WI, (1997)
16. GLINT Software, Applied Photophysics Ltd., Leatherhead, (1995)
17. V.P. Fedin, M.N. Sokolov, O.A. Gerasko, B.A. Kolesov, V.Y. Fedorov, A.V. Mironov, D.S. Yufit, Y.L. Slovohotov, Y.T. Struchkov: Inorg. Chim. Acta (1990), 175: 217.
18. V.P. Fedin, M.N. Sokolov, A.O. Gerasko, A.V. Virovets, N.V. Podberezskaya, V.Y. Fedorov: Inorg. Chim. Acta (1991), 187: 81.
19. F. Estevan, M. Feliz, R. Llusar, J.A. Mata, S. Uriel: Polyhedron (2001), 20: 527.
20. M. Feliz, R. Llusar, S. Uriel, C. Vicent, M.G. Humphrey, N.T. Lucas, M. Samoc, B. Luther-Davies: Inorg. Chim. Acta (2003), 349: 69.
21. F.A. Cotton, R. Llusar, C.T. Eagle: J. Am. Chem. Soc. (1989), 111: 4332.
22. M. Sasaki, G. Sakane, T. Ouchi, T. Shibahara: J. Cluster Sci. (1998), 9: 25.
23. E.S. Shubina, N.V. Belvoka, A.N. Krylov, E.V. Vorontsov, L.M. Epstein, D.G. Gusev, M. Niederman, H. Berke: J. Am. Chem. Soc. (1996), 118: 1105.
24. R.H. Crabtree, P.E. Siegbahn, O. Eisenstein, A.L. Rheingold, T.F. Koetzle: Acc Chem. Res. (1996), 29: 348.
25. A. Messmer, H. Jacobsen, H. Berke: Chem. Eur. J. (1999), 5: 3341.
26. V.I. Bakhmutov, E.V. Vorontsov: Rev. Inorg. Chem. (1998), 18: 183.
27. G.R. Dukes, R.H. Holm: J. Am. Chem. Soc. (1975), 97: 528.
28. J.L.C. Duff, J.L.J. Breton, J.N. Butt, F.A. Armstrong, A.J. Thomson: J. Am. Chem. Soc. (1996), 118: 8593.
29. R.A. Henderson, K.E. Oglieve: J. Chem. Soc., Dalton Trans. (1998), 1731.
30. R.P. Bell, The Proton in Chemistry, Ithaca, New York, (1973), p. 200.
31. M.G. Basallote, J. Durán, M.J. Fernández-Trujillo, M.A. Máñez: J. Chem. Soc., Dalton Trans. (1998), 2205.
32. M.G. Basallote, J. Durán, M.J. Fernández-Trujillo, M.A. Máñez: Inorg. Chem. (1999), 38: 5067.
33. M.G. Basallote, J. Durán, M.J. Fernández-Trujillo, M.A. Máñez: Organometallics (2000), 19: 695.