Why Are Olefins Oxidized by RuO4 under Cleavage of the Carbon-Carbon Bond whereas Oxidation by OsO4 Yields cis-Diols?

Journal of the American Chemical Society

Volumn 126, Issue 11, 2004, Pages 3642-3652

  Frunzke, Jan ^a   Loschen, Christoph ^a   Frenking, Gernot ^a  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CHEMICAL BONDS; OXIDATION; POTENTIAL ENERGY; PROBABILITY DENSITY FUNCTION; RUTHENIUM COMPOUNDS;

BOND CLEAVAGE; OXIDATION STATES;

OLEFINS;

1,3 DIOXOLANE DERIVATIVE; ALKENE DERIVATIVE; CARBON; OSMIUM; OXYGEN; RUTHENIUM DERIVATIVE; RUTHENIUM DIOXO 2,5 DIOXOLANE; RUTHENIUM OXOBIS(2,5 DIOXOLANE); RUTHENIUM TETROXIDE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CATALYSIS; CHEMICAL BINDING; CHEMICAL BOND; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; ENERGY; OXIDATION; QUANTUM MECHANICS;

EID: 1642343884     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039921a     Document Type: Article

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