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note
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We fabricated VOPc films at substrate temperatures of 50, 100, 150, and 200°C on the ITO/YSZ substrate. Although the surface morphology of the VOPc films varied with temperature, the orientation of all films was independent of temperature, i.e., (010) VOPc ∥ (111) ITO. Typical three-dimensional growth occurred at low temperatures (<150°C). In addition, a rather large domain (∼5 μm) with crack and hole structures was observed when VOPc film was deposited at 200°C, most likely due to the fact that re-evaporation of VOPc occurred during film growth. Therefore, we fixed the substrate temperature at 150°C.
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