Phase transfer catalysed asymmetric epoxidation of chalcones using chiral crown ethers derived from D-glucose and D-mannose

Synlett

Volumn , Issue 4, 2004, Pages 643-646

  Bakó, Péter ^a   Bakó, Tibor ^a   Mészáros, Attila ^a   Keglevich, György ^a   Szöllosy, Áron ^a   Bodor, Sándor ^a   Makó, Attila ^a   Toke, László ^a  

^a BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

Author keywords

Asymmetric epoxidation; Asymmetric phase transfer catalysis; Chiral crown ethers; Lariate ether

Indexed keywords

CHALCONE DERIVATIVE; CROWN ETHER DERIVATIVE; GLUCOSE; MANNOSE; TERT BUTYL HYDROPEROXIDE;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYST; CHIRALITY; COMPLEX FORMATION; ENANTIOMER; ENANTIOSELECTIVITY; EPOXIDATION; PHASE TRANSITION; REACTION ANALYSIS; ROOM TEMPERATURE; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 1642320895     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-817751     Document Type: Article

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22. + + Na].
23. 1H NMR: δ = 7.96 (d, 2 H, o-COPh-H), 7.46 (d, 2 H, m-COPh-H), 7.40 (t, 3 H, m,p-CHPh-H), 7.36 (d, 2H, o-CHPh-H), 4.23 (d, J = 1.6 Hz, 1 H, COCH), 4.07 (d, J = 1.3 Hz, 1 H, PhCH).