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Equilibration between hydrogen-bonded and non-hydrogen-bonded states for a given N-H proton is almost always fast on the NMR time scale, and observed proton chemical shifts are weighted averages of the chemical shifts of contributing states. Variable-temperature NH proton experiments were performed for I in the range of 253-298 K.
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1642358690
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note
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The broad diffraction peaks observed in the diffractograms of 3 are related to the presence of two cis-trans isomers of the former commercial precursor.
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35
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1642285507
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note
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1/n. Had the (100) reflection been present because of another space group symmetry, then the corresponding distance would still not correspond to the length of the macrocyclic receptor 1, since the a-axis is about 4 Å longer.
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36
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1642366919
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note
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1/m) an extra volume of 504 Å3 with respect to that of 1, thus V = 2712 Å3, close to the proposed cell volume of 2 (V = 2682 Å3)
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37
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0242525157
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Since this paper was submitted, two other articles have been published reporting the synthesis of self-assembled silylated organogels: (a) Dautel, O. J.; Lère-Porte, J. P.; Moreau, J. J.; Wong, C.-M. M. Chem. Commun. 2003, 2662-2663.
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0347753821
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(b) Moreau, J. J.; Pichon, B. P.; Wong, C.-M. M.; Bied, C.; Pritzkow, H. ; Bantignes, J. L.; Dieudonné, P.; Sauvajol, J. L. Angew. Chem., Int. Ed. 2004, 43, 203-206.
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39
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1642339198
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unpublished results
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This is related to a similar proton-driven ion pump. Palmeri, J., unpublished results.
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Palmeri, J.1
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