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2 = 0.9975, where ΔE is total distortion energy (kcal/mol), d is twist angle (degrees), and n is the number of benzene rings in the acene.
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It is especially noteworthy that 1,6-methano[10]- and syn-1,6:8,13-bismethano[14]annulene are aromatic and have twists up to 34°, while anti-bismethano[14]annulene is twisted by 70° and is nonaromatic. (a) Vogel, E.; Roth, H. D. Angew. Chem., Int. Ed. Engl. 1964, 3, 228-229.
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