Calorimetric evidence about the application of the concept of CMC to asphaltene self-association

Journal of Dispersion Science and Technology

Volumn 26, Issue 2, 2005, Pages 217-225

  Merino Garcia, Daniel ^a   Andersen, Simon I ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Asphaltenes; Isothermal titration calorimetry; Self association

Indexed keywords

ASPHALT; CALORIMETRY; EMULSIONS; FLUORESCENCE; INFRARED SPECTROSCOPY; MICELLES; MONOMERS; SURFACE ACTIVE AGENTS; TITRATION; TOLUENE;

ASPHALTENES; ISOTHERMAL TITRATION CALORIMETRY; MICELLATION; SURFACE ACTIVITY;

CRITICAL MICELLE CONCENTRATION;

ASPHALTENE;

EID: 16244362343     PISSN: 01932691     EISSN: None     Source Type: Journal    
DOI: 10.1081/DIS-200045600     Document Type: Article

References (51)

1. Acevedo, S., Ranaudo, M.A., Pereira, J.C., Castillo, J., Fernandez, A., Perez, P., and Caetano, M. (1999) Thermo-optical Studies of Asphaltene Solutions: Evidence for Solvent-solute Aggregate Formation. Fuel, 78: 997-1003.
2. Andersen, S.I. (1994a) Concentration Effects in HPLC-SEC Analysis of Petroleum Asphaltenes. J. Liq. Chromatog., 17 (19):4065-4079.
3. Andersen, S.I. (1994b) Dissolution of Solid Boscan Asphaltenes in Mixed Solvents. Fuel Sci. Technol. Int., 12: 1551-1578.
4. Andersen, S.I. (2003) The State of Asphaltenes in the Region we Called CMC!? In Proceedings of the 4th Petroleum Phase Behaviour and Fouling Conference, Trondheim, Norway, Jun 21-26; Sjöblom, J., Ed.
5. Andersen, S.I. and Birdi, K.S. (1991) Aggregation of Asphaltenes as Determined by Calorimetry. J. Colloid Interface Sci., 142 (2): 497-502.
6. Andersen, S.I. and Christensen, S.D. (2000) The Critical Micelle Concentration of Asphaltenes as Measured by Calorimetry. Energy Fuels 14: 38-42.
7. Andersen, S.I., del Rio-Garcia, J.M., Khvostitchenko, D., Shakir, S., and Lira-Galeana, C. (2001) Interaction and Solubilization of Water by Petroleum Asphaltenes in Organic Solution. Langmuir, 17: 307-313.
8. Artok, L., Su, Y., Hirose, Y., Hosokawa, M., Murata, S., and Nomura, M. (1999) Structure and Reactivity of Petroleum Derived Asphaltene. Energy Fuels, 13: 287-296.
9. Ascanius, B.E. and Andersen, S.I. (2002) Fractionation of asphaltenes for optical analysis, In Proceedings of the 2002 Heavy Oil Deposition Conference, Puerto Vallarta, Mexico, Nov 17-21; Lira-Galeana, C., Ed.
10. Birdi, K.S. (1985) Enthalpy of Micelle Formation (by Calorimetry) of Mixed Sodium Dodecylsulphate and Sodium Deoxycholate Systems in Aqueous Media. In Macro and Microemulsions; Shah, D.O., Ed.; American Chemical Society: Washington, D.C., 70.
11. Boduszynski, M.M. (1987) Composition of Heavy Petroleums. 1. Molecular Weight, Hydrogen Deficiency and Heteroatom Concentration as a Function of Atmospheric Equivalent Boiling Point up to 1400 F. Energy Fuels 1: 2-11.
12. Briant, J. and Hotier, G. (1983) Etude de l'etat des asphaltenes dans les mélanges d'hydrocarbures: taille des amas moleculaires. Rev. Inst. Fran. Pet., 38 (1): 83-100.
13. Buenrostro-Gonzalez, E., Andersen, S.I., Garcia-Martinez, J.A., and Lira-Galeana, C. (2002) Solubility/molecular Structure Relationships of Asphaltenes in Polar and Nonpolar Media. Energy Fuels, 16 (3): 732-741.
14. Carbognani, L. (2002) Solid Petroleum Asphaltenes Seem Surrounded by Alkyl Crowns, In Proceedings of the 3rd International Conference on Petroleum Phase Behavior and Fouling, New Orleans, Mar 10-14; Wiehe, I.A., Ed.; AIChE: New York.
15. Deo, M.D. (2002) Examination of Asphaltene Precipitation and Self-Aggregation, In Proceedings of the 2002 Heavy Oil Deposition Conference, Puerto Vallarta, Mexico, Nov 17-21; Lira-Galeana, C., Ed.
16. Dietz, A.G., Blaha, C., and Li, N.C. (1977) Enthalpies of Hydrogen Bonding of Quinoline with o-Phenylphenol and of Hydrogen-Bonding Reactions Involving the Acid and Base Components of a Coal-derived Asphaltene. J. Chem. Thermody., 9: 783-787.
17. Escobedo, J. and Mansoori, G.A. (1994) In Proceedings of the SPE International Petroleum Conference and Exhibition of Mexico. Paper SPE 28729, 585-596.
18. Evans, D.F. and Wennestrom, H. (1999) The Colloidal Domain, 2nd Ed.; Wiley-VCH: New York, 167.
19. Freire, E., Mayorga, O.L., and Straume, M. (1990) Isothermal Titration Calorimetry. Anal. Chem., 62 (18): 950A-958A.
20. Garidel, A., Hildebrand, A., Neubert, R., and Blume, A. (2000) Thermodynamic Characterization of Bile Salt Aggregation as a Function of Temperature and Ionic Strength Using Isothermal Titration Calorimetry. Langmuir, 16: 5267-5275.
21. Groenzin, H. and Mullins, O.C. (1999) Asphaltene Molecular Size and Structure. J. Phys. Chem., 103: 11237-11245.
22. IP 143/90. In Standards for Petroleum and its Products; Institute of Petroleum: London, 1985, 143.1.
23. Majhi, P.R. and Moulik, S.P. (1998) Energetics of Micellization: Reassessment by a High-Sensitivity Titration Microcalorimeter. Langmuir, 14: 3986-3990.
24. Majhi, P.R. and Moulik, S.P. (1999) Microcalorimetric Investigation of AOT Self-Association in Oil and the State of Pool Water in Water/oil Microemulsions. J. Phys. Chem. B, 103: 5977-5983.
25. Majhi, P.R. and Blume, A. (2001) Thermodynamic Characterization of Temperature Induced Micellization and Demicellization of Detergents Studied by Differential Scanning Calorimetry. Langmuir, 17: 3844-3851.
26. Martin, R.B. (1996) Comparisons of Indefinite Self-Association Models. Chem. Rev., 96 (8): 3043-3064.
27. Merino-Garcia, D. and Andersen, S.I. (2003) Isothermal Titration Calorimetry and Fluorescence Spectroscopy Study of Asphaltene Self-Association in Toluene and Interaction with a Model Resin. Pet. Sci. Technol., 21 (3&4): 507-525.
28. Mohamed, R.S., Ramos, A.C.-S., and Loh, W. (1999) Aggregation Behaviour of Two Asphaltenic Fractions in Aromatic Solvents. Energy Fuels, 13: 323-327.
29. Moschopedis, S.E. and Speight, J.G. (1976) Investigation of Hydrogen Bonding by Oxygen Functions in Athabasca Butimen. Fuel, 55: 187-192.
30. Murgich, J. (2002) Intermolecular Forces in Aggregates of Asphaltenes and Resins. Pet. Sci. Technol., 20 (9&10): 983-997.
31. Murgich, J., Lira-Galeana, C., Merino-Garcia, D., Andersen, S.I., and del Rio-Garcia, J.M. (2002) Molecular Mechanics and Microcalorimetric Investigations of the Effects of Molecular Water on the Aggregation of Asphaltenes in Solutions. Langmuir, 18: 9080-9088.
32. Pan, H. and Firoozabadi, A. (1998) Thermodynamics Micellization Model for Asphaltene Aggregation and Precipitation in Petroleum Fluids. SPE Prod. Facil., 13: 118-127.
33. Paula, S., Süs, W., Tuchtenhagen, J., and Blume, A. (1995) Thermodynamics of Micelle Formation as a Function of Temperature: a High Sensitivity Titration Calorimetry Study. J. Phys. Chem., 99: 11742.
34. Pesce, A.J. (1971) Fluorescence Spectroscopy; Marcel Dekker: New York, 54.
35. Ralston, C.Y., Mitra-Kirtley, S., and Mullins, O. (1996) Small Population of One to Three Fused-aromatic Ring Moieties in Asphaltenes. Energy Fuels, 10: 623-630.
36. Rogacheva, O.V., Rimaev, R.N., Gubaidullin, V.Z., and Khakimov, D.K. (1980) Investigation of the Surface Activity of the Asphaltenes of Petroleum Residues. Colloid J. USSR (Translated version) 42 (3): 586-589.
37. Rogel, E., Leon, O., Torres, G., and Espidel, J. (2000) Aggregation of Asphaltenes in Organic Solvents Using Surface Tension Measurements. Fuel, 79: 1389-1394.
38. Roux, J.N., Broseta, D., and Demé, B. (2001) SANS Study of Asphaltene Aggregation: Concentration and Solvent Quality Effects. Langmuir, 17: 5085-5092.
39. Savvidis, T.G., Fenistein, D., Barre, L., and Behar, E. (2001) Aggregated Structure of Flocculated Asphaltenes. AIChE J., 47 (1): 206-211.
40. Sharma, V.K., Bhat, R., and Ahluwalia, J.C. (1987) Temperature Dependence of Enthalpies and Heat-capacities of Sodium Dodecyl Sulphate (SDS) in water. J. Colloid Interface Sci., 115 (2): 396.
41. Sheu, E.Y. (1995) Asphaltenes. Fundamentals and Applications; Sheu, E.Y. and Mullins, O.C., Eds.; Plenum Press: New York.
42. Sheu, E.Y. (2002) Petroleum Asphaltene-Properties, Characterization and Issues. Energy Fuels, 16: 74-82.
43. Speight, J.G. (1999) The Chemistry and Technology of Petroleum, 3rd Ed.; Marcel Dekker Inc.: New York.
44. Storm, D.A. and Sheu, E.Y. (1995) Characterization of Colloidal Particles in Heavy Oil. Fuel, 74 (8): 1140-1145.
45. Strausz, O.P., Mojelski, T.W., and Lown, E.M. (1999) Structural Features of Boscan and Duri Asphaltenes. Energy Fuels, 13: 228-247.
46. Strausz, O.P., Peng, P., and Murgich, J. (2002) About the Colloidal Nature of Asphaltenes and the Mw of Covalent Monomeric Units. Energy Fuels, 16: 809-822.
47. Victorov, A.I. and Smirnova, N.A. (1999) Description of Asphaltene Polydispersity and Precipitation by Means of Thermodynamic Model of Self-assembly. Fluid Phase Equilibria, 158-160: 471-480.
48. Yarranton, H.W., Alboudwarej, H., and Jakher, R. (2000) Investigation of Asphaltene Association with Vapor Pressure Osmometry and Interfacial Tension Measurements. Ind. Eng. Chem. Res., 39: 2916-2924.
49. Yarranton, H.W., Beck, J., Akbarzadeh, K., Alboudwarej, H., and Svreck, W.Y. (2003) Regular Solution Approach to Modeling Asphaltene Precipitation, In Proceedings of the 4th Petroleum Phase Behaviour and Fouling Conference, Trondheim, Norway, Jun 21-26; Sjöblom, J., Ed..
50. Yokota, T., Scriven, F., Montgomery, D.S., and Strausz, O.P. (1986) Absorption and Emission Spectra of Athabasca Asphaltene in the Visible and Near Ultraviolet Regions. Fuel, 65: 1142-1149.
51. Yudin, I.K., Nikolaenko, G.L., Gorodetskii, E.E., Kosov, V.I., Melikyan, V.R., Markhashov, E.L., Frot, D., and Briolant, Y. (1998) Mechanisms of Asphaltene Aggregation in Toluene-Heptane Mixtures. J. Pet. Sci. Eng. 20: 297-301.