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1H NMR reveals that ethyl acetoacetate, dimedone, cyclohexanedione and 2,4-pentanedione exist as 10%, 40%, 63% and 84% enolic tautomers. The low enolic content of ethyl acetoacetate and strong intramolecular hydrogen bonding in 2,4-pentanedione may be responsible for lack of their reactivity
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1H NMR reveals that ethyl acetoacetate, dimedone, cyclohexanedione and 2,4-pentanedione exist as 10%, 40%, 63% and 84% enolic tautomers. The low enolic content of ethyl acetoacetate and strong intramolecular hydrogen bonding in 2,4-pentanedione may be responsible for lack of their reactivity
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