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Volumn 24, Issue 6, 2005, Pages 1059-1061

Dehydrogenative formation of a (η4-Enone)ruthenium(0) complex as a key intermediate in the catalytic isomerization of allylic alcohol to ketone

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; BENZENE; CATALYSIS; COMPLEXATION; HYDROGEN; ISOMERIZATION; KETONES; NUCLEAR MAGNETIC RESONANCE; PHASE TRANSITIONS; REACTION KINETICS; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

EID: 15944418216     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0489711     Document Type: Article
Times cited : (20)

References (31)
  • 19
    • 15944383870 scopus 로고    scopus 로고
    • note
    • 10.
  • 21
    • 15944419954 scopus 로고    scopus 로고
    • note
    • 3Ru: C, 49.30; H, 9.65. Found: C, 49.97; H, 10.24.
  • 22
    • 15944367825 scopus 로고    scopus 로고
    • note
    • 6) δ 13.9 (dd, J = 32, 5 Hz, 1P), 25.3 (dd, J = 15, 4 Hz, 1P), 45.2 (dd, J = 32, 15 Hz, IP).
  • 23
    • 15944426467 scopus 로고    scopus 로고
    • note
    • W = 0.052, 4094 unique reflections with I > 3σ(I).
  • 26
    • 15944383493 scopus 로고    scopus 로고
    • note
    • 6 (%/4): 3 (31%), 2-butenone (28%).
  • 27
    • 15944393613 scopus 로고    scopus 로고
    • note
    • 6 (22%); for prenyl alcohol, 3-methylbutan-1-ol (840%), 3-methyl-2-buten-1-one (320%), isobutane (14%), isobutene (26%); for cinnamyl alcohol, 3-phenylpropanol (700%), cinnamaldehyde (280%), styrene (189%), ethylbenzene (nd).
  • 30
    • 15944386760 scopus 로고    scopus 로고
    • note
    • -1): 2925 (vs), 1922 (vs), 1457 (s), 1376 (m), 1035 (m), 764 (m).
  • 31
    • 15944422615 scopus 로고    scopus 로고
    • note
    • -1): 2980-2880 (m), 1919 (vs), 1458 (m), 1420 (m), 1375 (m), 1253 (w), 1030 (s), 764 (s), 709 (m), 620 (m).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.