Multitechnique characterization of coke produced during commercial resid FCC operation

Industrial and Engineering Chemistry Research

Volumn 44, Issue 7, 2005, Pages 2069-2077

  Cerqueira, Henrique S ^a   Sievers, Carsten ^b   Joly, Guy ^c   Magnoux, Patrick ^c   Lercher, Johannes A ^b  

^a PETROBRAS   (Brazil)

^b TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^c UNIVERSITÉ DE POITIERS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC POLYMERS; CATALYSIS; CHARACTERIZATION; DEPOSITION; HYDROCARBONS; INFRARED SPECTROSCOPY;

COKE DEPOSITION; PHYSIOCHEMICAL TECHNIQUES; PYRIDINE; RESID FLUID CATALYTIC CRACKING (RFCC);

COKE;

COKE; HYDROCARBON;

COKE; MANUFACTURE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYST; DEGRADATION; INFRARED SPECTROSCOPY; MATRIX ASSISTED LASER DESORPTION IONIZATION TIME OF FLIGHT MASS SPECTROMETRY; OXIDATION; PHYSICAL CHEMISTRY;

EID: 15944405776     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie048963k     Document Type: Article

References (56)

1. Cerqueira, H. S.; Ayrault, P.; Datka, J.; Guisnet, M. Influence of coke on the acid properties of a USHY zeolite. Micropor. Mesopor. Mater. 2000, 38, 197.
2. Magnoux, P.; Cerqueira, H. S.; Guisnet, M. Evolution of coke composition during aging under nitrogen. Appl. Catal., A 2002, 235, 93.
3. Froment, G. A quantitative approach of catalyst deactivation by coke formation. Stud. Surf. Sci. Catal. 1980, 6, 1.
4. Nam, I.-S.; Froment, G. F. Catalyst deactivation by coke formation. J. Catal. 1987, 108, 271.
5. Bourdillon, G.; Gueguen, C.; Guisnet, M. Characterization of acid catalysts by means of model reactions. I. Acid strength necessary for the catalysis of various hydrocarbon reactions. Appl. Catal. 1990, 61, 123.
6. Beirnaert, H.; Vermeulen, R. Froment, G. F. A recycle electrobalance reactor for the study of catalyst deactivation by coke formation. Stud. Surf. Sci. Catal. 1994, 88, 97.
7. Reyniers, M.-F.; Beirnaert, H.; Marin, G. B. Influence of coke formation on the conversion of hydrocarbons I. Alkanes on a USY-zeolite. Appl. Catal., A 2000, 202, 49.
8. Reyniers, M.-F.; Tang, Y.; Marin, G. B. Influence of coke formation on the conversion of hydrocarbons II. I-Butene on HY-zeolites. Appl. Catal., A 2000, 202, 65.
9. Beeckman, J. W.; Froment, G. F. Catalyst deactivation by active site coverage and pore blockage. Ind. Eng. Chem. Fundam. 1979, 18, 245.
10. Froment, G. F. The modeling of catalyst deactivation by coke formation. Stud. Surf. Sci. Catal. 1891, 68, 53.
11. Guisnet, M.; Magnoux, P.; Martin, D. Roles of acidity and pore structure in the deactivation of zeolites by carbonaceous deposits. Stud. Surf. Sci. Catal. 1997, 111, 1.
12. Cerqueira, H. S.; Ayrault, P.; Datka, J.; Magnoux, P.; Guisnet, M. m-Xylene transformation over a USHY zeolite at 523 and 723 K. Influence of coke deposits on activity, acidity and porosity. J. Catal. 2000, 196, 149.
13. Mihindou-Koumba, P. C.; Cerqueira, H. S.; Magnoux, P.; Guisnet, M. Methylcyclohexane transformation over HFAU, HBEA and HMFI zeolites: II. Deactivation and coke formation. Ind. Eng. Chem. Res. 2001, 40, 1042.
14. Hopkins, P. D.; Miller, J. T.; Meyers, B. L.; Ray, G. J.; Roginski, R. T.; Kuehne, M. A.; Kung, H. H. Acidity and cracking activity changes during coke deactivation of ultrastable Y zeolite. Appl. Catal., A 1996, 136, 29.
15. Williams, B. A.; Babitz, S. M.; Miller, J. T.; Snurr, R. Q.; Kung, H. H. The roles of acid strength and pore diffusion in the enhanced cracking selectivity of steamed Y zeolites. Appl. Catal., A 1999, 177, 161.
16. Forzatti, P.; Lietti, L. Catalyst deactivation. Catal. Today 1999, 52, 165.
17. Wilson, J. W. Fluid Catalytic Cracking Technology and Operation; PennWell Publishing Co.: Tulsa, Oklahoma, U.S.A., 1997.
18. Weissman, J. G.; Edwards, J. C. Characterization and aging of hydrotreating catalysts exposed to industrial processing conditions. Appl. Catal., A 1988, 142, 289.
19. Furimsky, E. Characterization of cokes from fluid/flexicoking of heavy feeds. Fuel Process. Technol. 2000, 67, 20.
20. 13C-NMR spectroscopy and temperature-programmed oxidation. Appl. Catal., A 2001, 218, 181.
21. Sahoo, S. K.; Rao, P. V. C.; Rajeshwer, D.; Krishnamurthy, K. R.; Singh, I. D. Structural characterization of coke deposits on industrial spent paraffin dehydrogenation catalysts. Appl. Catal., A 2003, 244, 311.
22. 13C NMR. Appl. Catal., A 1895, 129, 125.
23. Bayraktar, O.; Kugler, E. L. Characterization of coke on equilibrium fluid catalytic cracking catalysts by temperature-programmed oxidation. Appl. Catal., A 2002, 233, 197.
24. Karge, H. G..; Lange, J. P.; Gutsze, A.; Laniecki, M. Coke formation through the reaction of olefins over hydrogen mordenite. II. In-situ EPR measurements under on-stream conditions. J. Catal. 1888, 114, 144.
25. 13C-NMR studies. Appl. Catal., A 1988, 45, 345.
26. 13C NMR. Stud. Surf. Sci. Catal. 1891, 68, 699.
27. 13C-NMR spectroscopy. Catal. Today 1997, 37, 285.
28. Karge, H. G. Coke formation on zeolites. Stud. Surf. Sci. Catal. 1891, 58, 531.
29. Li, C.; Stair P. C. Ultraviolet Raman spectroscopy characterization of coke formation in zeolites. Catal. Today 1997, 33, 353.
30. Espinat, D.; Freund, E.; Dexpert, H.; Martino, G. Localization and structure of carbonaceous deposits on reforming catalysts. J. Catal. 1990, 126, 496.
31. Espinat, D.; Dexpert, H.; Freund, E.; Martino, G.; Couzi, M.; Lespade, P.; Cruege, F. Characterization of the coke formed on reforming catalysts by laser Raman spectroscopy. Appl. Catal. 1985, 13, 343.
32. Joly, J. F.; Zanier-Szydlowski, N.; Colin, N. S.; Raatz, F.; Saussey, J.; Lavalley, J. C. Infrared in situ characterization of HY zeolite acid sites during cyclohexane transformation. Catal. Today 1991, 9, 31.
33. Li, C. Chen, Y.-W. Yang, S.-J. Yen, R.-B. In-situ FTIR investigation of coke formation on USY zeolite. Appl. Surf. Sci. 1994, 81, 465.
34. Karge, H. G.; Nießen, W.; Bludau, H. In-situ FTIR measurements of diffusion in coking zeolite catalysts. Appl. Catal., A 1996, 146, 339.
35. Du, Y.; Wang, H.; Chen, S. Study on alkylation of benzene with ethylene over β-zeolite catalyst to ethylbenzene by in situ IR. J. Mol. Catal. A 2002, 179, 253.
36. Meunier, F. C.; Domokos, L.; Seshan, K.; Lercher, J. A. In situ IR study of the nature and mobility of sorbed species on H-FER during but-1-ene isomerization. J. Catal. 2002, 211, 366.
37. 129Xe-NMR study. Appl. Catal. 1988, 43, L5.
38. 13C CP-MAS NMR study. Appl. Catal., A 1997, 159, 187.
39. Fleisch, T. H.; Zajac, G. W.; Meyers, B. L.; Ray, G. J.; Millein, J. T. In Catalysis Theory to Practice; Proceedings of the 9th International Congress on Catalysis; Philips, M. J., Ternan, M., Eds.; The Chemical Institute of Canada: Ottawa, Ontario, 1988; p 483.
40. Qian, K.; Tomczak, D. C.; Rakiewicz, E. F.; Harding, R. H.; Yaluris, G.; Cheng, W.; Zhao, X.; Peters, A. Coke formation in the fluid catalytic cracking process by combined analytical techniques. Energy Fuels 1997, 11, 596.
41. Guisnet, M.; Magnoux, P. Influence of the pore structure. Appl. Catal. 1989, 54, 1.
42. Koon, C. L.; Akbar, F.; Hughes, R.; Tyagi, Y. R.; Castro Diaz, M.; Martin, S. C.; Hall, P. J.; Snape, C. E. Development of an experimental protocol to evaluate FCC stripper performance in terms of coke yield and composition. Trans. Inst. Chem. Eng. 2000, 78, 738.
43. Hanton, S. D. Mass spectrometry of polymers and polymer surfaces. Chem. Rev. 2001, 101, 527-570.
44. Fitzgerald, M. C.; Siuzdak, G. Biochemical mass spectrometry: worth the weight? Chem. Biol. 1996, 3, 707.
45. Yang, M.; Reilly, J. P. Kinetic energy distributions of aniline molecules and cations following their UV-laser-induced desorption from a metal surface. J. Phys. Chem. 1990, 94, 6299.
46. Zenobi, R.; Knochenmuss, R. Ion formation in MALDI mass spectrometry. Mass Spectrom. Rev. 1998, 337.
47. Barth, J. O.; Jentys, A.; Lercher, J. A. On the nature of nitrogen-containing carbonaceous deposits on coked fluid catalytic cracking catalysts. Ind. Eng. Chem. Res. 2004, 43, 2368.
48. Feller, A.; Earth, J.-O.; Guzman, A.; Zuazo, I.; Lercher, J. A. Deactivation pathways in zeolite-catalyzed isobutane/butene alkylation. J. Catal. 2003, 220, 192.
49. Morgado, E., Jr.; Leite, L. F.; Pravia, O. R.; Torem, M. A. New and improved: Resid FCC catalysts. Hydrocarbon Eng. 2002, 7, 1.
50. Cerqueira, H. S.; Morgado, E., Jr.; Pimenta, R. D. M. Fresh vs. flush catalysts. Hydrocarbon Eng. 2003, 8, 23.
51. Hayatsu, R.; Scott, R. G.; Moore, L. P. Studia, M. H. Aromatic units in coal. Nature (London) 1975, 257, 378.
52. Moljord, K.; Magnoux, P.; Guisnet, M. Coking, aging, and regeneration of zeolites XV. Influence of the composition of HY zeolites on the mode of formation of coke from propene at 450°C. Appl. Catal., A 1995, 122, 21.
53. Earth, J.-O.; Jentys, A.; Lercher, J. A. Elementary reactions and intermediate species formed during the oxidative regeneration of spent fluid catalytic cracking catalysts. Ind. Eng. Chem. Res. 2004, 43, 3097.
54. Deno, N. C. In Carbonium Ions; Olah, G. A., Schleyer, P. R., Eds.; Interscience: New York, 1970; Vol. 1, p 223.
55. Olah, G. A.; Pittman, C. U.; Symons, M. C. R. In Carbonium Ions; Olah, G. A., Schleyer, P. R., Eds.; Interscience: New York, 1968; Vol. 1, p 153.
56. Guisnet, M. Magnoux, P. Organic chemistry of coke formation. Appl. Catal., A 2001, 212, 83.