Hydrogenation of weakly rehybridized ethylene on Fe(100)-H: Ethyl group formation

Journal of the American Chemical Society

Volumn 118, Issue 21, 1996, Pages 5062-5067

  Merrill, Philip B ^a   Madix, Robert J ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ADSORPTION; CHEMICAL BONDS; ELECTRON ENERGY LOSS SPECTROSCOPY; HYDROGENATION; IRON;

BONDING; REACTIVITY; REHYBRIDIZATION INTERMEDIATES; REHYBRIDIZED ETHYLENE; TEMPERATURE PROGRAMMED REACTION SPECTROSCOPY;

ETHYLENE;

ETHYLENE; HYDROGEN; IRON;

ADSORPTION; ARTICLE; ELECTRON ENERGY LOSS SPECTROSCOPY; GAS; HYBRIDIZATION; HYDROGENATION; SPECTROSCOPY;

EID: 15844401781     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953484l     Document Type: Article

References (56)

1. Burke, M. L.; Madix, R. J. J. Am. Chem. Soc. 1991, 113, 3675.
2. Benziger, J. B.; Madix, R. J. J. Catal. 1980, 65, 49.
3. Hung, W.-H.; Bernasek, S. Surf. Sci. 1995, 339, 272.
4. (a) Merrill, P. B.; Madix, R. J. Surf. Sci. in press.
5. (b) Merrill, P. B. Ph.D. Thesis, Stanford University, 1995; Chapter 2.
6. Steininger, H.; Ibach, H.; Lehwald, S. Surf. Sci. 1982, 117, 685.
7. Koel, B. E.; Bent, B. E.; Somorjai, G. A. Surf. Sci. 1984, 146, 211.
8. Gates, J. B.; Kesmodel, L. L. Surf. Sci. 1983, 124, 68.
9. Marinova, T. S.; Kostov, K. L. Surf. Sci. 1987, 181, 573.
10. Hills, M. M.; Parmeter, J. E.; Mullins, C. B.; Weinberg, W. H. J. Am. Chem. Soc. 1986, 108, 3554.
11. Burke, M. L.; Madix, R. J. J. Am. Chem. Soc. 1991, 113 1475.
12. Merrill, P. B.; Madix, R. J. Surf. Sci. 1992, 271, 81.
13. 11 However, these studies cannot distinguish between (1) direct conversion of CO from atop to 4-fold sites and (2) conversion from bridge to 4-fold sites along with simultaneous conversion from atop to bridge sites.
14. Dewar, J. S. Bull. Soc. Chim. France 1951, 18, C71.
15. Chatt, J.; Duncanson, L. A. J. Chem. Soc. 1953, 2939.
16. Wong, Y.-T.; Hoffmann, R. J. Chem. Soc., Faraday Trans. 1990, 86, 4083.
17. Powell, D. B.; Scott, J. G. V.; Sheppard, N. Spectrochim. Acta 1972, 28A, 327.
18. Stuve, E. M.; Madix, R. J. J. Phys. Chem. 1985, 89, 3183.
19. Bent, B. E.; Mate, C. M.; Kao, C.-T.; Slavin, A. J.; Somorjai, G. A. J. Phys. Chem. 1988, 92, 4720.
20. Bent, B. E. Ph.D. Thesis, University of California, Berkeley, 1982.
21. Sheppard, N. Ann. Rev. Phys. Chem. 1988, 39, 589.
22. Herzberg, G. Molecular Spectra and Molecular Structure II. Infrared and Raman Spectra of Polyatomic Molecules: Van Nostrand Reinhold Company: New York, 1945.
23. Bandy, B. J.; Chesters, M. A.; James, D. I.; McDougall, G. S.; Pemble, M. E.; Sheppard, N. Philos. Trans. R. Soc. London Ser. A 1986, 318, 141.
24. Lehwald, S.; Ibach, H. Surf. Sci. 1979, 89, 425.
25. Lehwald, S.; Ibach, H.; Steininger, H. Surf. Sci. 1982, 117, 342.
26. Anson, C. E.; Bandy, B. J.; Chesters, M. A.; Keiller, B.; Oxton, I. A.; Sheppard, N. J. Electron. Spectrosc. Rel. Phenom. 1983, 29, 315.
27. Barteau, M. A.; Broughton, J. Q.; Menzel, D. Appl. Surf. Sci. 1984, 19, 92.
28. Hatzikos, G. H.; Masel, R. I. Surf. Sci. 1987, 185, 479.
29. Erley, W.; Baro, A. M.; Ibach, H. Surf. Sci. 1982, 120, 273.
30. Nyberg, C.; Tengstal, C. G.; Andersson, S. Chem. Phys. Lett. 1982, 87, 87.
31. Stuve, E. M.; Madix, R. J. J. Phys. Chem. 1985, 89, 105.
32. Chesters, M. A.; McDougall, G. S.; Pemble, M. E.; Sheppard, N. Appl. Surf. Sci. 1985, 22/23, 369.
33. Backx, C.; de Groot, C. P. M.; Biloen, P. Appl. Surf. Sci. 1980, 6, 256.
34. Kostov, K. L.; Marinova, T. S. Surf. Sci. 1987, 184, 359.
35. Seip, U.; Tsai, M.-C.; Kuppers, J.; Ertl, G. Surf. Sci. 1984, 147, 65.
36. Zaera, F.; Fischer, D. A.; Carr, R. G.; Gland, J. L. J. Chem. Phys. 1988, 89, 5335.
37. Burke, M. L; Madix, R. J. Surf. Sci. 1990, 237, 20.
38. Ho, W.; Willis, R. F.; Plummer, E. W. Phys. Rev. Lett. 1978, 40, 1463.
39. Cameron, S. D.; Dwyer, D. J. Langmuir 1988, 4, 282.
40. Lu, J.-P.; Albert, M. R.; Bernasek, S. L. Surf. Sci. 1989, 215, 348.
41. Lowry, T. H.; Richardson, K. S. Mechanism and theory in organic chemistry, 2nd ed.; Harper & Row: New York, 1981.
42. 15 Thus, as a model of π bonding, Zeise's salt represents the organometallic analog with weak back-back bonding; however, it is not an example of pure π bonding.
43. Lloyd, K. G.; Roop, B.; Campion, A.; White, J. M. Surf. Sci. 1989, 214, 227.
44. 42
45. Shimanouchi, T. Tables of Molecular Vibrational Frequencies Consolidated Volume I; U.S. Dept. of Commerce, NSRDS-NBS, 1972.
46. Hoffmann, F. M.; Felter, T. E.; Thiel, P. A.; Weinberg, W. H. Surf. Sci. 1983, 130, 173.
47. Demuth, J. E.; Ibach, H.; Lehwald, S. Phys. Rev. Lett. 1978, 40, 1044.
48. Yang, Q. Y.; Maynard, K. J.; Johnson, A. D.; Ceyer, S. T. J. Chem. Phys. 1995, 102, 7734.
49. Lin, J.-L.; Bent, B. E. Chem. Phys. Lett. 1992, 194, 208.
50. Brookhart, M.; Green, M. L. H. J. Org. Chem. 1983, 250, 395.
51. Yang, H.; Whitten, J. L. J. Am. Chem. Soc. 1991, 113, 6442.
52. Zheng, C.; Apeliog, Y.; Hoffmann, R. J. Am. Chem. Soc. 1988, 110, 749.
53. Hoffmann, F. M.; Upton, T. H. J. Phys. Chem. 1984, 88, 6209.
54. Schüle, J.; Siegbahn, P.; Wahlgren, U. J. Chem. Phys. 1988, 89, 6982.
55. Raval, R.; Chesters, M. A. Surf. Sci. 1988, 219, L505.
56. Huberty, J.; Madix, R. J. Surf. Sci., in press.