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(a) Curran, D. P.; Qi, H.; Geib, S. J.; DeMello, N. C. J. Am. Chem. Soc. 1994, 116, 3131.
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Qi, H.2
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(b) Tetrahedron Symposium-in-print on Axially Chiral Amides; Clayden, J., Ed.; Tetrahedron 2004, 60, 4325-4558.
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Representative papers: (a) Kitagawa, O.; Izawa, H.; Sato, K.; Dobashi, A.; Taguchi, T.; Shiro, M. J. Org. Chem. 1998, 63, 2634.
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Kitagawa, O.1
Izawa, H.2
Sato, K.3
Dobashi, A.4
Taguchi, T.5
Shiro, M.6
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4
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(b) Hughes, A. D.; Price, D. A.; Simpkins, N. S. J. Chem. Soc., Perkin Trans. 1 1999, 1295.
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J. Chem. Soc., Perkin Trans. 1
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Hughes, A.D.1
Price, D.A.2
Simpkins, N.S.3
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5
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(c) Kondo, K.; Fujita, H.; Suzuki, T.; Murakami, Y. Tetrahedron Lett. 1999, 40, 5577.
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Tetrahedron Lett.
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Kondo, K.1
Fujita, H.2
Suzuki, T.3
Murakami, Y.4
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7
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0001163250
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Asymmetric syntheses of atropisomeric anilides through enantiotopic selective deprotonation with a stoichiometric chiral base have been reported by two groups. However, Uemura's method (ref 3a) cannot be applied to the synthesis of ortho-mono-tert-butylanilide, which can effectively work as a chiral molecule. On the other hand, in Simpkins' method (ref 3b), improvement of the chemical yield (40-56%) and application to other substrates except for N-ortho-tert-butylphenyl maleimide are problems for future study, (a) Hata, T.; Koide, H.; Taniguchi, N.; Uemura, M. Org. Lett. 2000, 2, 1907.
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Org. Lett.
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Hata, T.1
Koide, H.2
Taniguchi, N.3
Uemura, M.4
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9
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(a) Kitagawa, O.; Kohriyama, M.; Taguchi, T. J. Org. Chem. 2002, 67, 8682.
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J. Org. Chem.
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Kitagawa, O.1
Kohriyama, M.2
Taguchi, T.3
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11
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0001054296
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Kinetic resolution of racemic dibromoparacyclophane through PHANEPHOS-Pd-calalyzed amination has been reported (only one example), while to the best of our knowledge, there has been no paper in relalion to catalytic asymmetric aromatic amination with achiral substrates. Rossen, K.; Pye, P. J.; Maliakal, A.; Volante, R. P. J. Org. Chem. 1997, 62, 6462.
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J. Org. Chem.
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Rossen, K.1
Pye, P.J.2
Maliakal, A.3
Volante, R.P.4
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(b) Guram, A. S.; Rennels, R. A.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1995, 34, 1348.
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Guram, A.S.1
Rennels, R.A.2
Buchwald, S.L.3
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(e) Prim, D.; Campagne, J.-M.; Joseph, D.; Andrioletli, B. Tetrahedron 2002, 58, 2041.
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Prim, D.1
Campagne, J.-M.2
Joseph, D.3
Andrioletli, B.4
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17
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15744389072
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note
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Resulis with other chiral phosphine ligands (see Supporting Information): Trost ligand (0%), CHIRAPHOS (0%), PHANEPHOS (0%), BPPFOAc (0%), DIOP (20%, 9% ee), Me-DuPhos (16%, 15% ee), Et-FerroTANE (12%, 33% ee), MOP (18%, 52% ee), tol-BINAP (48%, 53% ee), xyl-BINAP (56%, 78% ee).
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18
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0000155207
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Saito, T.; Yokozawa, T.; Ishizaki, T.; Moroi, T.; Sayo, N.; Miura, T.: Kumobayashi, H. Adv. Synth. Catal. 2001, 343, 264.
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Adv. Synth. Catal.
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Saito, T.1
Yokozawa, T.2
Ishizaki, T.3
Moroi, T.4
Sayo, N.5
Miura, T.6
Kumobayashi, H.7
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