[4+2] Cycloaddition of 2-substituted 1,2-dihydropyridines with nitrosobenzene: Asymmetric synthesis of trans-2-substituted 3-amino-1,2,3,6- tetrahydropyridines

Journal of Organic Chemistry

Volumn 70, Issue 6, 2005, Pages 2368-2371

  Lemire, Alexandre ^a   Beaudoin, Daniel ^a   Grenon, Michel ^a   Charette, André B ^a  

^a UNIVERSITÉ DE MONTRÉAL   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; AROMATIC COMPOUNDS; HYDROGENATION; METHANOL; REDUCTION; STEREOCHEMISTRY; SUBSTITUTION REACTIONS;

CHEMOSELECTIVE REDUCTION; CYCLOADDUCTS; HYDROGEN CHLORIDE; NITROSOBENZENE;

NITROGEN COMPOUNDS;

AMIDE; DIHYDROPYRIDINE DERIVATIVE; HYDROCHLORIC ACID; IMIDAZOLE DERIVATIVE; METHANOL; NITROSOBENZENE; PALLADIUM; PIPERIDINE DERIVATIVE; PYRIDINE DERIVATIVE;

ARTICLE; ASYMMETRIC SYNTHESIS; CHIRALITY; CYCLOADDITION; ENANTIOMER; HYDROGENATION; METHODOLOGY; REDUCTION; STEREOCHEMISTRY; SUBSTITUTION REACTION;

CYCLIZATION; DIHYDROPYRIDINES; MOLECULAR CONFORMATION; NITROSO COMPOUNDS; PYRIDINES; STEREOISOMERISM;

EID: 15444361998     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo048216x     Document Type: Article

References (29)

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26. This equilibrium has been observed on a similar system, see ref 9c.
27. 3 in the reduction of amidines.
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