Cleavage of Formamidinate Ligands on a Ta=Ta Double Bond: Formation of HxCNAryl (x = 0 and 1) and Arylimido-Bridged Complexes

Inorganic Chemistry

Volumn 36, Issue 5, 1997, Pages 896-901

  Albert Cotton, F ^a   Daniels, Lee M ^a   Murillo, Carlos A ^a,b   Wang, Xiaoping ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b UNIVERSIDAD DE COSTA RICA   (Costa Rica)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 1542637557     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9611507     Document Type: Article

References (19)

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2. (a) Cotton, F. A.; Daniels, L. M.; Maloney, D. J.; Matonic, J. H.; Murillo, C. A. Polyhedron 1994, 13, 815.
3. (b) Arnold, D. I.; Cotton, F. A.; Maloney, D. J.; Matonic J. H.; Murillo, C. A. Polyhedron 1997, 16, 133.
4. Cotton, F. A.; Daniels, L. M.; Maloney, D. J.; Murillo, C. A. Inorg. Chim. Acta 1996, 242, 31.
5. Cotton, F. A.; Walton, R. A. Multiple Bonds between Metal Atoms, 2nd ed.; Oxford University Press, Oxford, U.K., 1993.
6. Cotton, F. A.; Matonic, J. H.; Murillo, C. A.; Wang, X. Bull. Soc. Chim. Fr. 1996, 133, 711.
7. Cotton, F. A.; Daniels, L. M.; Matonic, J. H.; Murillo, C. A.; Wang, X. Polyhedron, in press.
8. Arnold, D. I.; Cotton, F. A.; Matonic, J. H.; Murillo, C. A. Chem. Soc., Chem. Commun. 1996, 2113.
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10. Roberts, R. M. J. Org, Chem. 1949, 14, 277.
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12. Bryan, J. C.; Cotton, F. A.; Daniels, L. M.; Haefner, S. C.; Sattelberger, A. P. Inorg. Chem. 1995, 34, 1875.
13. Blessing, R. H. Acta Crystallogr. 1995, A51, 33.
14. Bino, A.; Cotton, F. A.; Fanwick, P. Inorg. Chem. 1979, 18, 3558.
15. SHELXTL V.5, Siemens Industrial Automation, Madison, WI, 1990.
16. 3, Z = 2. A model containing 811 parameters was refined against 9052 unique data to converge with R1 = 0.051, wR2 = 0.140, and GOF = 1.06.
17. Scioly, A. J.; Luetkens, M. L., Jr.; Wilson, R. B., Jr.; Huffman, J. C.; Sattelberger, A. P. Polyhedron 1987, 741.
18. Gray, S. D.; Smith, D. P.; Bruck, M. A.; Wigiey, D. E. J. Am. Chem. Soc. 1992, 114, 5462 and references therein.
19. Canich, J. A. M.; Cotton, F. A.; Duraj, S. A.; Roth, W. W. Polyhedron 1986, 5, 895.