The Chemistry of Chlorosilyl Enolates 3.: Variation of the Silyl Group and the Effect on Rate and Enantiomeric Excess of Acetate Aldol Additions

Synlett

Volumn 1997, Issue 9, 1997, Pages 1087-1089

  Denmark, Scott E ^a   Winter, Stephen B D ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 1542525127     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1997-1543     Document Type: Article

References (11)

1. (a) Denmark, S. E.; Winter, S. B. D.; Su, X.; Wong, K.-T. J. Am. Chem. Soc. 1996, 118, 7404.
2. (b) Denmark, S. E.; Wong, K.-T.; Stavenger, R. A. J. Am. Chem. Soc. 1997, 119, 2333.
3. Denmark, S. E.; Coe, D. M.; Pratt, N. E.; Griedel, B. D. J. Org. Chem. 1994, 59, 6161; Kobayashi, S.; Nishio, K. J. Org. Chem. 1994, 59, 6620.
4. Denmark, S. E.; Coe, D. M.; Pratt, N. E.; Griedel, B. D. J. Org. Chem. 1994, 59, 6161; Kobayashi, S.; Nishio, K. J. Org. Chem. 1994, 59, 6620.
5. 13C NMR, IR and high resolution mass spectrometry.
6. 13C NMR, IR and high resolution mass spectrometry.
7. Corriu, R. J. P.; Royo, G.; De Saxcè, A. J. Chem. Soc., Chem. Commun. 1980, 892.
8. (a) Klebe, G.; Bats, J. W.; Hensen, K. Z. Naturforsch., B. 1983, 38, 825.
9. (b) Klebe, G.; Bats, J. W.; Hensen, K. J. Chem. Soc., Dalton Trans. 1985, 1.
10. Corriu, R. J. P.; Mazhar, M.; Poirier, M.; Royo, G.; J. Organomet. Chem. 1986, 306, C5.
11. Hexacoordinate complexes of silicon bearing only two electronegative groups are known, but all incorporate strongly chelating ligands. Corriu, R. J. P.; Young, J. C. In The Silicon-Heteroatom Bond; Patai, S. Rappoport, Z., Eds.; Wiley: New York, 1991; Chapter I.