Hydride abstraction reactivity of haloruthenoceniums and haloosmoceniums

Organometallics

Volumn 15, Issue 22, 1996, Pages 4888-4890

  Xu, Agnes N ^a   Studebaker, Daniel B ^a   Westmoreland, T David ^a  

^a WESLEYAN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 1542505117     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9606247     Document Type: Article

References (35)

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29. 3.
30. -. These side reactions did not interfere on the time scale of Figures 1 and 2.
31. +.
32. 2 and to the purity of the materials and have not been sufficiently reproducible in our hands for a stoichiometry to be reported with confidence. The initial reaction is most likely a 1:1 reaction based on the alkylmetallocene results . At any rate, it is clear that the ultimate products are those obtained by net hydride abstraction and that the metallocenium is thermodynamically competent to carry out the reaction.
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