Synthesis of (formylferrocenyl)bismuthanes. A way to control the stereochemistry at the chiral bismuth centre using hypervalent bond formation and planar chirality of ferrocene

Chemical Communications

Volumn , Issue 14, 1996, Pages 1693-1694

  Murafuji, Toshihiro ^a   Mutoh, Takanori ^a   Sugihara, Yoshikazu ^a  

^a YAMAGUCHI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 1542497509     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/cc9960001693     Document Type: Article

References (19)

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7. The bulky group in a chiral substituent has been revealed to prefer the anti orientation with respect to ferrocenyl iron. D. Marquaring, H. Klusacek, G. Gokel, P. Hoffmann and I. Ugi, J. Am. Chem. Soc., 1970, 92, 5389; F. Rebiere, O. Riant, L. Ricard and H. B. Kagan. Angew. Chem., Int. Ed. Engl., 1993, 32, 568.
8. The bulky group in a chiral substituent has been revealed to prefer the anti orientation with respect to ferrocenyl iron. D. Marquaring, H. Klusacek, G. Gokel, P. Hoffmann and I. Ugi, J. Am. Chem. Soc., 1970, 92, 5389; F. Rebiere, O. Riant, L. Ricard and H. B. Kagan. Angew. Chem., Int. Ed. Engl., 1993, 32, 568.
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17. Very recently, selective functionalization of the 1′-position in formylferrocene using lithium N-methylpiperazide has been reported independently. G. Iftime, C. Moreau-Bossuct, E. Manoury and G. G. A. Balavoine, Chem. Commun., 1996, 527.
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