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33748847518
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See also: (b) Dimroth, K.; Hoffmann, P. Chem. Ber. 1966, 99, 1325.
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Dimroth, K.1
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2
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0039243551
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Somewhat similar compounds have been reported by Gamon and Reichardt. See, e.g.: Gamon, N.; Reichardt, C. Angew. Chem., Int. Ed. Engl. 1977, 16, 404; Leibigs Ann. Chem. 1980, 2072.
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Dimroth, K. Top. Curr. Chem. 1973, 38, 1. Somewhat similar compounds have been reported by Gamon and Reichardt. See, e.g.: Gamon, N.; Reichardt, C. Angew. Chem., Int. Ed. Engl. 1977, 16, 404; Leibigs Ann. Chem. 1980, 2072.
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84985560524
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(b) Schmidpeter, A.; Lochschmidt, S.; Burget, G. Phosphorus Sulfur 1983,18, 23. (c) Schmidpeter, A.; Lochschmidt, S.; Willhalm, A. Angew. Chem., Int. Ed. Engl. 1983, 23, 903. (d) Schmidpeter, A.; Lochschmidt, S.; Sheldrick, W. S. Angew. Chem., Int. Ed. Engl. 1985, 24, 226.
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(a) Schmidpeter, A.; Lochschmidt, S.; Sheldnck, W. S. Angew. Chem., Int. Ed. Engl. 1982, 21, 63. (b) Schmidpeter, A.; Lochschmidt, S.; Burget, G. Phosphorus Sulfur 1983,18, 23. (c) Schmidpeter, A.; Lochschmidt, S.; Willhalm, A. Angew. Chem., Int. Ed. Engl. 1983, 23, 903. (d) Schmidpeter, A.; Lochschmidt, S.; Sheldrick, W. S. Angew. Chem., Int. Ed. Engl. 1985, 24, 226.
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Schmidpeter, A.1
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4
-
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0001193425
-
-
This system of nomenclature follows the organic chemistry convention suggested by 01ah4b in which the cations with lower coordination number are given the suffix "enium", while those of higher coordination number are given the suffix "onium". (b)
-
This system of nomenclature follows the organic chemistry convention suggested by 01ah4b in which the cations with lower coordination number are given the suffix "enium", while those of higher coordination number are given the suffix "onium". (b) Olah, G. A. J. Am. Chem. Soc. 1972, 94, 808.
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For brief reviews of phosphenium ion chemistry, see: (a) Fluck, E. Top. Phosphorus Chem. 1980, 10, 193. (b) Cowley, A. H.; Cushner, M. C.; Lattman, M.; McKee, M. L.; Szobota, J. S.; Wilburn, J. C. Pure Appl. Chem. 1980, 52, 789.
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Fluck, E.1
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0001057491
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For recent evidence for a sihcenium ion in solution, see:
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For recent evidence for a sihcenium ion in solution, see: Lambert, J. B.; Schulz, W. J., Jr. J. Am. Chem. Soc. 1983, 705, 1671.
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0004214539
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Halonium Ions
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For a thorough discussion of halonium ions, see: Wiley: New York
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For a thorough discussion of halonium ions, see: Olah, G. A. "Halonium Ions"; Wiley: New York, 1975.
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Olah, G.A.1
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See also the review by: Granoth, I. Top. Phosphorus Chem. 1976, 8, 41.
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See also: (b) Baxter, S. G.; Cowley, A. H.; Kemp, R. A.; Mehrotra, S. K. ACS Symp. 1981, No. 171.
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At least three models have been proposed to explain the charge derealization in ferrocenyl-substituted carbocations: (i) interaction of the central metal with a "fulvene" π system with concomitant shift of the metal toward the exocyclic carbon, (ii) conjugation between the 2p orbital of the exocyclic carbon with the tt system of the substituted ring, and (iii) distortion and bending of bonds in the substituted ring, thus bringing the exocyclic carbon closer to the metal atom. See: (a) (b) Cais, M.; Dannenburg, J. J.; Eisenstadt, A.; Levenburg, M. I.; Richards, J. H. Tetrahedron Lett. 1966, 1694. (c) Traylor, T. G.; Ware, J. C. J. Am. Chem. Soc. 1967, 89, 2304. (d) Traylor, T. G.; Hanstein, W.; Berwin, H. J.; Clinton, N. A.; Brown, R. S. J. Am. Chem. Soc. 1971, 93, 5715. (e) Fitzpatrick, J. D.; Watts, L. Pettit, R. Tetrahedron Lett. 1966,1299. (f) Davis, R. E.; Simpson, H. D.; Grice, N.; Pettit, R. J. Am. Chem. Soc. 1971, 93, 6688. (g) Corriu, M. Organomet. Chem. Rev. 1966, 7, 435.
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For a theoretical model for bent-sandwich compounds of the main-group elements see:
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U.S. Patents 2663736, 2663 737, 1953; Chem. Abstr. 1955,49, 7601. For reviews of this reaction, see: Quin, L. D. In "1,4-Cycloaddition Reactions"; Hamer, J., Ed.; Academic Press: New York, 1967; pp 47-96. Quin, L. D. In "The Heterocyclic Chemistry of Phosphorus"; Wiley-Interscience: New York, 1981; Chapter 2.
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McCormack, W. B. U.S. Patents 2663736, 2663 737, 1953; Chem. Abstr. 1955,49, 7601. For reviews of this reaction, see: Quin, L. D. In "1,4-Cycloaddition Reactions"; Hamer, J., Ed.; Academic Press: New York, 1967; pp 47-96. Quin, L. D. In "The Heterocyclic Chemistry of Phosphorus"; Wiley-Interscience: New York, 1981; Chapter 2.
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