Improved Synthesis of the V(tetracy anoethy lene)x · y (solvent) Room-Temperature Magnet: Doubling of the Magnetization at Room Temperature

ACS Symposium Series

Volumn 644, Issue , 1996, Pages 311-318

  Zhang, Jie ^a   Miller, Joel S ^a   Vazquez, Carlos ^b   Zhou, Ping ^c   Brinckerhoff, William B ^c   Epstein, Arthur J ^c  

^a UNIVERSITY OF UTAH   (United States)

^b DUPONT COMPANY   (United States)

^c OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 1542470361     PISSN: 00976156     EISSN: None     Source Type: Book Series    
DOI: 10.1021/bk-1996-0644.ch021     Document Type: Article

References (31)

1. Recent reviews: (a) Miller, J. S.; Epstein, A. J., Angew. Chem., 1994, 106, 399; Angew. Chem. internat, edit., 1994, 33, 385. (b) Buchachenko, A. L., Russ. Chem. Rev., 1990, 59, 307; Usp. Khim. 1990, 59, 529. (c) Gatteschi, D., Adv. Mat., 1994, 6, 635.
2. Recent reviews: (a) Miller, J. S.; Epstein, A. J., Angew. Chem., 1994, 106, 399; Angew. Chem. internat, edit., 1994, 33, 385. (b) Buchachenko, A. L., Russ. Chem. Rev., 1990, 59, 307; Usp. Khim. 1990, 59, 529. (c) Gatteschi, D., Adv. Mat., 1994, 6, 635.
3. Recent reviews: (a) Miller, J. S.; Epstein, A. J., Angew. Chem., 1994, 106, 399; Angew. Chem. internat, edit., 1994, 33, 385. (b) Buchachenko, A. L., Russ. Chem. Rev., 1990, 59, 307; Usp. Khim. 1990, 59, 529. (c) Gatteschi, D., Adv. Mat., 1994, 6, 635.
4. Recent reviews: (a) Miller, J. S.; Epstein, A. J., Angew. Chem., 1994, 106, 399; Angew. Chem. internat, edit., 1994, 33, 385. (b) Buchachenko, A. L., Russ. Chem. Rev., 1990, 59, 307; Usp. Khim. 1990, 59, 529. (c) Gatteschi, D., Adv. Mat., 1994, 6, 635.
5. Recent reviews: (a) Miller, J. S.; Epstein, A. J., Angew. Chem., 1994, 106, 399; Angew. Chem. internat, edit., 1994, 33, 385. (b) Buchachenko, A. L., Russ. Chem. Rev., 1990, 59, 307; Usp. Khim. 1990, 59, 529. (c) Gatteschi, D., Adv. Mat., 1994, 6, 635.
6. (d) Kahn, O., Molecular Magnetism, VCH Publishers, Inc. 1993.
7. Conference Proceedings in the conference on Ferromagnetic and High Spin Molecular Based Materials (Eds.: Miller, J. S.; Dougherty, D. A.), Mol. Cryst., Liq. Cryst. 1989, 176. Conference Proceedings in the conference on Molecular Magnetic Materials: NATO ARW Molecular Magnetic Materials (Eds.: Kahn, O.; Gatteschi, D.; Miller, J. S.; Palacio, F.), Kluwer Acad. Pub., London, 1991, E198. Conference Proceedings in the conference on Chemistry and Physics of Molecular Based Magnetic Materials (Eds.: Iwamura, H.; Miller, J. S.), Mol. Cryst., Liq. Cryst. 1993, 232/233. Conference Proceedings in the conference on Molecule-based Magnets (Eds.: Miller, J. S. and Epstein, A. J.), Mol. Cryst., Liq. Cryst. 1995, 271-274.
8. Conference Proceedings in the conference on Ferromagnetic and High Spin Molecular Based Materials (Eds.: Miller, J. S.; Dougherty, D. A.), Mol. Cryst., Liq. Cryst. 1989, 176. Conference Proceedings in the conference on Molecular Magnetic Materials: NATO ARW Molecular Magnetic Materials (Eds.: Kahn, O.; Gatteschi, D.; Miller, J. S.; Palacio, F.), Kluwer Acad. Pub., London, 1991, E198. Conference Proceedings in the conference on Chemistry and Physics of Molecular Based Magnetic Materials (Eds.: Iwamura, H.; Miller, J. S.), Mol. Cryst., Liq. Cryst. 1993, 232/233. Conference Proceedings in the conference on Molecule-based Magnets (Eds.: Miller, J. S. and Epstein, A. J.), Mol. Cryst., Liq. Cryst. 1995, 271-274.
9. Conference Proceedings in the conference on Ferromagnetic and High Spin Molecular Based Materials (Eds.: Miller, J. S.; Dougherty, D. A.), Mol. Cryst., Liq. Cryst. 1989, 176. Conference Proceedings in the conference on Molecular Magnetic Materials: NATO ARW Molecular Magnetic Materials (Eds.: Kahn, O.; Gatteschi, D.; Miller, J. S.; Palacio, F.), Kluwer Acad. Pub., London, 1991, E198. Conference Proceedings in the conference on Chemistry and Physics of Molecular Based Magnetic Materials (Eds.: Iwamura, H.; Miller, J. S.), Mol. Cryst., Liq. Cryst. 1993, 232/233. Conference Proceedings in the conference on Molecule-based Magnets (Eds.: Miller, J. S. and Epstein, A. J.), Mol. Cryst., Liq. Cryst. 1995, 271-274.
10. Conference Proceedings in the conference on Ferromagnetic and High Spin Molecular Based Materials (Eds.: Miller, J. S.; Dougherty, D. A.), Mol. Cryst., Liq. Cryst. 1989, 176. Conference Proceedings in the conference on Molecular Magnetic Materials: NATO ARW Molecular Magnetic Materials (Eds.: Kahn, O.; Gatteschi, D.; Miller, J. S.; Palacio, F.), Kluwer Acad. Pub., London, 1991, E198. Conference Proceedings in the conference on Chemistry and Physics of Molecular Based Magnetic Materials (Eds.: Iwamura, H.; Miller, J. S.), Mol. Cryst., Liq. Cryst. 1993, 232/233. Conference Proceedings in the conference on Molecule-based Magnets (Eds.: Miller, J. S. and Epstein, A. J.), Mol. Cryst., Liq. Cryst. 1995, 271-274.
11. Manriquez, J. M.; Yee, G. T.; McLean, R. S.; Epstein, A. J.; Miller, J. S., Science 1991, 252, 1415. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 461. La Chim. & La Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 475. La Chim. & La Ind. 1993, 75, 185.
12. Manriquez, J. M.; Yee, G. T.; McLean, R. S.; Epstein, A. J.; Miller, J. S., Science 1991, 252, 1415. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 461. La Chim. & La Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 475. La Chim. & La Ind. 1993, 75, 185.
13. Manriquez, J. M.; Yee, G. T.; McLean, R. S.; Epstein, A. J.; Miller, J. S., Science 1991, 252, 1415. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 461. La Chim. & La Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 475. La Chim. & La Ind. 1993, 75, 185.
14. Manriquez, J. M.; Yee, G. T.; McLean, R. S.; Epstein, A. J.; Miller, J. S., Science 1991, 252, 1415. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 461. La Chim. & La Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 475. La Chim. & La Ind. 1993, 75, 185.
15. Manriquez, J. M.; Yee, G. T.; McLean, R. S.; Epstein, A. J.; Miller, J. S., Science 1991, 252, 1415. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 461. La Chim. & La Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S., in the Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure, Oxford University Press, 1993, 475. La Chim. & La Ind. 1993, 75, 185.
16. Miller, J. S.; Dixon, D. A.; Calabrese, J. C.; Vazquez, C.; Krusic, P. J.; Ward, M. D.; Wasserman, E.; Harlow, R. L. J. Am. Chem. Soc. 1990, 112, 381.
17. (a) Ellis, J. E.; Faltynek, R. A.; Rochfort, L.; Stevens, R. E.; Zank, G. A., Inorg. Chem. 1980, 19, 1082.
18. (b) Werner, R. P. M.; Podall, H. E., Chem & Ind. (London) 1961, 144.
19. (c) King, R. B.; Stone, F. G. A., J. Am. Chem. Soc. 1959, 81, 5363.
20. (d). Palm, C.; Fischer, E. O.; Reckziegel, A., Tet. Lett. 1962, 253.
21. (e) Calderazzo, F. Inorg. Chem. 1963, 3, 810.
22. (f) King, R. B.; Stone, F. G. A., Inorg. Syn. 1963, 7, 99
23. (g) Fischer, E. O.; Vigoureux, S., Chem. Ber. 1958, 91, 2205.
24. (h) Anderson, S. J.; Wells, F. J.; Wilkinson, G.; Hussain, H.; Hursthouse, M. B., Polyhed. 1988, 7, 2615.
25. (i) W. Hieber, W.; Peterhans, J.; Winter, E., Chem. Ber. 1961, 94, 2572.
26. (j) Hieber, W.; Winter, E.; Schubert, E., Chem. Ber. 1962, 95, 3070.
27. (a) Calderazzo, F., Inorg. Chem. 1964, 3, 1207.
28. (b) Gambarotta, S.; Floriani, C.; Chiesi-Villa, A.; Guastini, C., Inorg. Chem. 1984, 23, 1739.
29. -1, consistent with incomplete loss of CO.
30. Shriver, D. F.; Drezdzon, M. A., The Manipulation of Air-Sensitive Compounds, John Wiley & Sons, New York, 1986. pp 113-115.
31. Goodenough, J. B., Magnetism and the Chemical Bond, Wiley-Interscience: New York, 1963. p98, 100, and 104.