Cyclopropanation with Diazomethane and Bis(oxazoline)palladium(II) Complexes

Journal of Organic Chemistry

Volumn 62, Issue 10, 1997, Pages 3370-3374

  Denmark, Scott E ^a   Stavenger, Robert A ^a   Faucher, Anne Marie ^a   Edwards, James P ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 1542398427     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo970044z     Document Type: Article

References (161)

1. (a) Kagan, H. B. Asymmetric Synthesis Using Organometallic Catalysts. In Comprehensive Organometallic Chemistry; Wilkinson, G., Ed.; Pergamon Press: New York, 1982; Vol. 8.
2. (b) Transition-Metal Organometallics in Organic Synthesis. In Comprehensive Organometallic Chemistry II; Hegedus, L. S., Ed.; Academic Press: New York, 1995; Vol. 12.
3. (c) Asymmetric Synthesis, Volume 5: Chiral Catalysis; Morrison, J. D., Ed.; Academic Press: New York, 1985.
4. (d) Brunner, H. Top. Stereochem. 1988, 18, 129.
5. (e) Brunner, H. Synthesis 1988, 645.
6. (f) Noyori, R. Chem. Soc. Rev. 1989, 18, 187.
7. (g) Noyori, R.; Kitmura, M. In Modern Synthetic Methods 1989; Scheffold, R., Ed.; Springer-Verlag: New York, 1989.
8. (h) Asymmetric Catalysis in Organic Synthesis; Ojima, I., Ed.; VCH: New York, 1993.
9. (i) Noyori, R. Asymmetric Catalysis in Organic Synthesis; John Wiley & Sons: Inc.: New York, 1994.
10. (j) Brunner, H.; Zettlmeier, W. Handbook of Enantioselective Catalysis with Transition Metal Compounds, Vol 1: Products and Catalysts VCH: New York, 1993.
11. (k) Brunner, H.; Zettlmeier, W. Handbook of Enantioselective Catalysis with Transition Metal Compounds, Vol 2: Ligands - References; VCH: New York, 1993.
12. (a) Fritschi, H.; Leutenegger, U.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1986, 25, 1005
13. For reviews see (b) Pfaltz, A. Chimia 1990, 44, 202. (c) Bolm, C. Angew. Chem., Int. Ed. Engl. 1991, 30, 542. (d) Pfaltz, A. Acc. Chem. Res. 1993, 26, 339.
14. For reviews see (b) Pfaltz, A. Chimia 1990, 44, 202. (c) Bolm, C. Angew. Chem., Int. Ed. Engl. 1991, 30, 542. (d) Pfaltz, A. Acc. Chem. Res. 1993, 26, 339.
15. For reviews see (b) Pfaltz, A. Chimia 1990, 44, 202. (c) Bolm, C. Angew. Chem., Int. Ed. Engl. 1991, 30, 542. (d) Pfaltz, A. Acc. Chem. Res. 1993, 26, 339.
16. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
17. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
18. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
19. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
20. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
21. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
22. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
23. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
24. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
25. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
26. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
27. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
28. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
29. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
30. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
31. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
32. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
33. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
34. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k)
35. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
36. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
37. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
38. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
39. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
40. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
41. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
42. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
43. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt, Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
44. For leading references on each class of reaction see: Allylic acetate displacement: (a) von Matt, P.; Lloyd-Jones, G. C.; Minidis, A. B. E.; Pfaltz, A.; Macko, L.; Neuburger, M.; Zehnder, M.; Rüegger, H.; Pregosin, P. S. Helv. Chim. Acta 1995, 78, 265. (b) Leutenegger, U.; Umbricht, G.; Fahrni, C.; von Matt, P.; Pfaltz, A. Tetrahedron 1992, 48, 2143. Allylic oxidation: (c) Gokhale, A. S.; Minidis, A. B. E.; Pfaltz, A. Tetrahedron Lett. 1995, 36, 1831. Hydrosilylation: (d) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K. Chem. Lett. 1993, 347. (e) Nishiyama, H.; Yamaguchi, S.; Park, S.-B.; Itoh, K. Tetrahedron Asymm. 1993, 4, 143. (f) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K. J. Org. Chem. 1992, 57, 4306. (g) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846. Organometallic additions: (h) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C. J. Am. Chem. Soc. 1994, 116, 8797. Denmark, S. E.; Nicaise, O. J.-C. Chem. Commun. 1996, 999. [4 + 2] Cycloadditions: (j) Evans, D. A.; Murry, J. A.; von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (k) Evans, D. A.; Miller, S. J.; Lectka, T. J. Am Chem. Soc. 1993, 115, 6460. Corey, E. J.; Wang, Z. Tetrahedron Lett. 1993, 34, 4001. Corey, E. J.; Ishihara, K. Tetrahedron Lett. 1992, 33, 6807. (n) Corey, E. J.; Imai, N.; Zhang, H.-Y. J. Am. Chem. Soc. 1991, 113, 728. Aziridination: (o) Hansen, K. B.; Finney, N. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1995, 34, 676. (p) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A.; Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328. Copolymerization: (q) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddau, H. A. J. Am. Chem. Soc. 1994, 116, 3641. In addition, aryl monooxazoline complexes have become popular ligands. For leading references see: Allylic acetate discplacements: (r) Rieck, H.; Helmchen, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 2687. (s) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron Asymm. 1994, 5, 573. (t) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. (u) Allen, J. V.; Coote, S. J.; Dawson, G. J.; Frost, C. G.; Martin, C. J. Williams, J. M. J. J. Chem. Soc., Perkin Trans. 1 1994, 2065. Sprinz, J.; Kiefer, M.; Helmchen, G.; Reggelin, M.; Huttner, G.; Walter, O.; Zsolnai, L. Tetrahedron Lett. 1994, 35, 1523. (w) von Matt, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 566. Hydrosilylation: Brunner, H.; Brandi, P. Tetrahedron Asymm. 1991, 2, 919. (y) Brunner, H.; Brandi, P. J. Organomet. Chem. 1990, 390, C81. Transfer hydrogenation: (z) Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Asymmetric Heck coupling: (aa) Loiseleur, O.; Meier, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. For a leading reference on the preparation of bis(oxazoline) ligands see: (bb) Denmark, S. E.; Nakajima, N.; Nicaise, O. J.-C.; Faucher, A.-M.; Edwards, J. P. J. Org. Chem. 1995, 60, 4884. For (phosphinoaryl)oxazolines see: (cc) Koch, G.; Lloyd-Jones, G. C.; Loiseleur, O.; Pfaltz, A.; Prétôt Schaffner, S.; Schnider, P.; von Matt, P. Recl. Trav. Chim. Pays-Bos 1995, 114, 206.
45. (a) Nozaki, H.; Moriuti, S.; Takaya, H.; Noyori, R. Tetrahedron Lett. 1966, 5239.
46. (b) Nozaki, H.; Takaya, H.; Moriuti, S.; Noyori, R. Tetrahedron 1968, 24, 3655.
47. (a) Aratani, T.; Yoneyoshi, Y.; Nagase, T. Tetrahedron Lett. 1975, 16, 1707.
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119. 2 requires C: 64.36; H: 4.87; Pd: 22.36. Found: C: 64.31; H: 4.83; Pd: 22.36. The use of this formula to calculate stoichiometry resulted in clean oxidative addition and recovery of dibenzylideneacetone.
120. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
121. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
122. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
123. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
124. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
125. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
126. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
127. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F.
128. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
129. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
130. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
131. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
132. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
133. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
134. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
135. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
136. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
137. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
138. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
139. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
140. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
141. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
142. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
143. For other crystal structures of bis(oxazoline)metal complexes see: Cu: (a) Reference 11a. (b) Reference 13b. (c) Hall, J.; Lehn, J.-M.; DeCian, A.; Fischer, J. Helv. Chim. Acta 1991, 74, 1. Pd: (d) Nesper, R.; Pregosin, P.; Püntener, K.; Wörle, M.; Albinati, A. J. Organomet. Chem. 1996, 507, 85. (e) Reference 3b. (f) Zehnder, M.; Neuburger, M.; von Matt, P.; Pfaltz, A. Acta. Crystallogr. 1995, C51, 1109. Zn: (g) Reference 18c. Ni: W: (h) Lloyd-Jones, G. C.; Pfaltz, A. Z. Naturforsch. 1995, 50b, 361. Rh: (i) Reference 2i Ru: (j) Bennett, S.; Brown, S. M.; Conole, G.; Kessler, M.; Rowling, S.; Sinn, E.; Woodward, S. J. Chem. Soc., Dalton Trans. 1995, 367. (k) Szczepura, L. F.; Maricich, S. M.; See, R. F.; Churchill, M. R.; Takeuchi K. J. Inorg. Chem. 1995, 34, 4198. Zr: (l) Cozzi, P. G.; Floriam C.; Chiesi-Villa A.; Rizzoli, C. Inorg. Chem. 1995, 34, 2921. For crystal structures of mono(oxazoline)metal complexes see: Cu, Ni, Zn: (m) Bolm, C.; Weickhardt, K.; Zehnder, M.; Glasmacher, D. Helv. Chim. Acta 1991, 74, 717. Pd: (n) Reference 23b. (o) Reference 23e. (p) Reference 23f. (q) Reference 3r. Pt: (r) Michelin, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. Organometallics 1991, 10, 1751. (s) Michelen, R. A.; Bertani, R.; Mozzon, M.; Bombieri, G.; Benetollo, F.; Angelici, R. J. J. Chem. Soc., Dalton Trans. 1993, 959. (t) Michelen, R. A.; Mozzon, M.; Berin, P.; Bertani, R.; Benetollo, F.; Bombieri, G.; Aneglici, R. J. Organometallics 1994, 13, 1341. Tc (u) Duatti, A.; Marchi, A.; Rossi, R.; Magon, L.; Deutsch, E.; Bertolasi, V.; Bellucci, F. Inorg. Chem. 1988, 27, 4208. (v) Wilcox B. E.; Cooper, J. N.; Elder, R. C.; Deutsch, E. Inorg. Chim. Acta 1988, 142, 55. Al, Ga, In: (w) Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1992, 31, 5408. Ti, Zr, V: Ref 271. Re, Tc: Shuter, E.; Hoveyda, H. R.; Karunaratne, V.; Rettig, S. J.; Orvig, C. Inorg. Chem. 1996, 35, 368.
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