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1H NMR spectrum, and found that the broad signals due to 3a-Mo remained intact throughout the reaction. Thus, the mechanism associated with the dissociation of the amidine ligand from 3a-Mo could not be ruled out completely at the present stage.
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33
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1542325002
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note
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The yellow crystals of complex 3a-Mo · 1/2toluene were so low crystallinity due to containing solvated toluene molecules that high quality intensity data were not obtained. Therefore, we could not discuss the bond distances and angles for 3a-Mo · 1/2toluene. However, the geometrical structure of the molecule can be discussed unequivocally.
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34
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1542355117
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note
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1H NMR of 4a-Mo in the presence of 5 equivalents of amidine 2a also showed the broad signals.
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