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Volumn 126, Issue 8, 2004, Pages 2306-2307

Formaldehyde Encapsulated in Zeolite: A Long-Lived, Highly Activated One-Carbon Electrophile to Carbonyl-Ene Reactions

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CARBONYL DERIVATIVE; FORMALDEHYDE; ZEOLITE;

EID: 1542345320     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039737p     Document Type: Article
Times cited : (79)

References (25)
  • 5
    • 0001290261 scopus 로고
    • Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford
    • (a) Snider, B. B. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, 1991; Vol. 2, pp 527-561.
    • (1991) Comprehensive Organic Synthesis , vol.2 , pp. 527-561
    • Snider, B.B.1
  • 11
    • 1542349894 scopus 로고    scopus 로고
    • note
    • NaX containing more aluminum atoms is more basic than NaY; NaX has a less acidic character than NaY.
  • 20
    • 1542379682 scopus 로고    scopus 로고
    • note
    • By using HCHO@CaA and HCHO@Na-mordenite, no carbonyl-ene adducts were obtained.
  • 25
    • 1542319843 scopus 로고    scopus 로고
    • note
    • Ionic reagents such as RMgX are not proper as a nucleophile toward HCHO@zeolite because the aluminosilicate framework of zeolites with a high A1 content such as NaX and NaY is fragile under such strongly basic conditions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.