Effect of the Synthetic Method and Support Porosity on the Structure and Performance of Silica-Supported CuBr/Pyridylmethanimine Atom Transfer Radical Polymerization Catalysts. I. Catalyst Preparation and Characterization

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 42, Issue 6, 2004, Pages 1367-1383

  Nguyen, Joseph V ^a   Jones, Christopher W ^a  

^a GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Atom transfer radical polymerization (ATRP); Catalysis; Silicas

Indexed keywords

ACRYLICS; CATALYSTS; COMPLEXATION; DIFFERENTIAL SCANNING CALORIMETRY; FREE RADICAL POLYMERIZATION; RAMAN SPECTROSCOPY; SILICA; SORPTION; THERMOGRAVIMETRIC ANALYSIS;

ATOM TRANSFER RADICAL POLYMERIZATION (ATRP); LOW TEMPERATURE NITROGEN PHYSISORPTION;

METALLORGANIC POLYMERS;

POLYMERIZATION;

EID: 1542335785     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.20001     Document Type: Article

References (54)

1. Wang, J.; Matyjaszewski, K. J Am Chem Soc 1995, 117, 5614-5615.
2. Wang, J.; Matyjaszewski, K. Macromolecules 1995, 28, 7572-7573.
3. Wang, J.; Matyjaszewski, K. Macromolecules 1995, 28, 7901-7910.
4. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721-1723.
5. Wang, J.; Matyjaszewski, K. Chem Rev 2001, 101, 2921-2990.
6. Huang, X.; Wirth, M. J. Anal Chem 1997, 69, 4577-4580.
7. Kim, J.-B.; Huang, W.; Miller, M. D.; Baker, G. L.; Bruening, M. L. J Polym Sci Part A: Polym Chem 2003, 41, 386-394.
8. Matyaszewski, K.; Qiu, J.; Tsarevsky, N. V.; Charleux, B. J Polym Sci Part A: Polym Chem 2000, 38, 4724-4734.
9. Cunningham, M. F. Prog Polym Sci 2002, 27, 1039-1067.
10. Qiu, J.; Charleux, B.; Matyjaszewski, K. Prog Polym Sci 2001, 26, 2083-2134.
11. Li, M.; Matyjaszewski, K. J Polym Sci Part A: Polym Chem 2003, 41, 3606-3614.
12. Hoogenboom, R.; Schubert, U. S. J Polym Sci Part A: Polym Chem 2003, 41, 2425-2434.
13. It has been demonstrated that good rates and control can be achieved with substantially smaller amounts of metal complexes in homogeneous systems; see Queffelec, J.; Gaynor, S. G.; Matyjaszewski, K. Macromolecules 2000, 33, 8629-8639.
14. Matyjaszewski, K.; Pintauer, T.; Gaynor, S. Macromolecules 2000, 33, 1476-1478.
15. Haddleton, D. M.; Jackson, S. G.; Bon, S. A. F. J Am Chem Soc 2000, 122, 1542-1543.
16. Angot, S.; Ayres, N.; Bon, S. A. F.; Haddleton, D. M. Macromolecules 2001, 34, 768-774.
17. Biedron, T.; Kubisa, P. Macromol Rapid Commun 2001, 22, 1237-1242.
18. Sarbu, T.; Matyjaszewski, K. Macromol Chem Phys 2001, 202, 3379-3391.
19. Carmichael, A. J.; Haddleton, D. M.; Bon, S. A. F.; Seddon, K. R. Chem Commun 2000, 1237-1238.
20. Honigfort, M. E.; Brittain, W. J.; Bosanac, T.; Wilcos, C. S. Macromolecules 2002, 35, 4849-4851.
21. Kickelbick, G.; Paik, H. J.; Matyjaszewski, K. Macromolecules 1999, 32, 2941-2947.
22. Hong, S. C.; Paik, H. J.; Matyjaszewski, K. Macromolecules 2001, 34, 5099-5102.
23. Hong, S. C.; Matyjaszewski, K. Macromolecules 2002, 35, 7592-7605.
24. Hong, S. C.; Neugebauer, D.; Inoue, Y.; Lutz, J. F.; Matyjaszewski, K. Macromolecules 2003, 36, 27-35.
25. Hong, S. C.; Lutz, J. F.; Inoue, Y.; Strissel, C.; Nuyken, O.; Matyjaszewski, K. Macromolecules 2003, 36, 1075-1082.
26. Haddleton, D. M.; Kukulj, D.; Radigue, A. P. Chem Commun 1999, 99-100.
27. Haddleton, D. M.; Duncalf, D. J.; Kukulj, D.; Radigue, A. P. Macromolecules 1999, 32, 4769-4775.
28. Liou, S.; Rademacher, J. T.; Malaba, D.; Pallack, M. E.; Brittain, W. J. Macromolecules 2000, 33, 4295-4296.
29. Hognifort, M. E.; Brittain, W. J. Macromolecules 2003, 36, 3111-3114.
30. Shen, Y.; Zhu, S.; Zeng, F.; Pelton, R. Macromol Chem Phys 2001, 201, 1387-1394.
31. Shen, Y.; Zhu, S.; Zeng, F.; Pelton, R. Macromolecules 2000, 33, 5427-5431.
32. Shen, Y.; Zhu, S.; Pelton, R. Macromolecules 2001, 34, 3182-3185.
33. Shen, Y.; Zhu, S.; Zeng, F.; Pelton, R. J Polym Sci Part A: Polym Chem 2001, 39, 1051-1059.
34. Shen, Y.; Zhu, S.; Pelton, R. Macromolecules 2001, 34, 5812-5818.
35. Shen, Y.; Zhu, S. Macromolecules 2001, 34, 8603-8609.
36. Shen, Y.; Zhu, S.; Pelton, R. Macromol Rapid Commun 2000, 21, 956-959.
37. Opstal, T.; Melis, K.; Verpoort, F. Catal Lett 2001, 74, 155-159.
38. Pintauer, T.; Qiu, J.; Kickelbick, G.; Matyjaszewski, K. Inorg Chem 2001, 40, 2818-2824.
39. Kickelbick, G.; Pintauer, T.; Matyjaszewski, K. New J Chem 2002, 26, 462-468.
40. Haddleton, D. M.; Duncalf, D. J.; Kukulj, D.; Crossman, M. C.; Jackson, S. G.; Bon, S. A. F.; Clark, A. J.; Shooter, A. J. Eur J Inorg Chem 1998, 11, 1799-1806.
41. Haddleton, D. M.; Jasieczek, C. B.; Hannon, M. J.; Shooter, A. J. Macromolecules 1997, 30, 2190-2193.
42. Dai, S.; Burleigh, M. C.; Ju, Y. H.; Gao, H. J.; Lin, J. S.; Pennycook, S. J.; Barnes, C. E.; Xue, Z. L. J Am Chem Soc 2000, 122, 992-993.
43. Dai, S.; Burleigh M. C.; Shin, Y.; Morrow, C. C.; Barnes, C. E.; Xue, Z. Angew Chem Int Ed 1999, 38, 1235-1239.
44. Zhang, Z.; Dai, S.; Hunt, R. D.; Wei, Y.; Qiu, S. Adv Mater 2001, 13, 493-496.
45. For an example of PMI ligands in solution polymerizations, see Zhang, H. Q.; Van Der Linde, R. J Polym Sci Part A: Polym Chem 2002, 40, 3549-3561.
46. Nguyen, J. V.; Jones, C. W. J Polym Sci Part A: Polym Chem, 2004, in press.
47. Pangborn, A. M.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518-1520.
48. Kruk, M.; Jaroniec, M. Chem Mater 2000, 12, 1961-1968.
49. Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Frederickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548-552.
50. Zhao, D.; Huo, Q.; Feng, J.; Chmelka, B. F.; Stucky, G. D. J Am Chem Soc 1998, 120, 6024-6036.
51. Baranska, H.; Labudzinska, A.; Terpinski, J. Laser Raman Spectrometry; Wiley: New York, 1987.
52. Nunes, C. D.; Pillinger, M.; Valente, A. A.; Goncalves, I. S.; Rocha, J. ; Ferreira, P.; Kuhn, F. E. Eur J Inorg Chem 2002, 1100-1107.
53. Product Data Sheet for Untreated Fumed Silica Cab-O-Sil EH5; Cabot Corp. ; Tuscola, IL, USA (http://www.cabot-corp.com), 2002.
54. Sindorf, D. W.; Maciel, G. E. J Am Chem Soc 1983, 105, 3767-3776.