Valent state and coordination of cobalt ions in beryl and chrysoberyl crystals

Physics and Chemistry of Minerals

Volumn 31, Issue 1, 2004, Pages 1-11

  Solntsev, V P ^a   Tsvetkov, E G ^a   Alimpiev, A I ^a   Mashkovtsev, R I ^a  

^a SOBOLEV INSTITUTE OF GEOLOGY AND MINERALOGY   (Russian Federation)

Author keywords

Beryl; Chrysoberyl; Cobalt; EPR; Optical absorption

Indexed keywords

CRYSTALS; ELECTRON ENERGY LEVELS; IMPURITIES; LIGHT ABSORPTION; LIGHT POLARIZATION; PARAMAGNETIC RESONANCE;

ABSORPTION BAND INTENSITIES; SPIN-ORBIT INTERACTIONS;

COBALT COMPOUNDS;

BERYL; COBALT; CRYSTAL STRUCTURE; ION; OPTICAL PROPERTY;

EID: 1542288056     PISSN: 03421791     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00269-003-0363-x     Document Type: Article

References (42)

1. Akridge JR, Kennedy JH (1979) Absorption and emission spectroscopy and magnetic susceptibility of sodium β-alumina doped with Mn, Co, and Ni. J Solid State Chem 29: 63-72
2. 3+ laser, in Russian, Kvantovaya Electronika, 14: 885-886
3. 3+ ions in alexandrite. Phys Status Solidi 35: 811-814
4. 3+ ions in chrysoberyl. Phys Status Solidi (b) 38: 229-234
5. 3+), in Russian, Kvantovaya Electronika 5: 1168-1169
6. Bukin GV, Matrosov VH, Orekhova VR, Remigailo YuL, Sevastyanov BK, Symonov EG, Solntsev VP, Tsvetkov EG (1981) Growth of alexandrite crystals and investigation of their properties. J Crystal Growth 52: 537-541
7. 3+ ions in emerald. J Phys (C): Solid State Phys 11: 5051-5063
8. 3+ ions in beryl. Solid State Commun 41: 195-198
9. Evdokimova OA, Belokoneva E.L, Artemenko VV, Dubovskaya VM, Urusov VS (1989) Location of impurity cations in synthetic cobalt- and copper-bearing beryls according to precise X-ray structural analysis, EPR and optical spectroscopy data, in Russian. Krstallografiya 34: 723-730
10. Farrell EF, Fang JH and Newnham RE (1963) Refinement of the chrysoberyl structure. Am Mineral 48: 804-810
11. 4). Determination of the relative site occupancy. J Chem Phys 79: 2590-2599
12. Herzberg G (1969) Electronic spectra and electronic structure of polyatomic molecules. Mir, Moscow, USSR, 772 p (translated from Herzberg G 1966. Molecular spectra and molecular structure. III. Electronic spectra and electronic structure of polyatomic molecules. Toronto)
13. 2v distorted tetrahedral copper (II) complexes. J Solid State Chem 44: 343-353
14. 3+ ions in beryl, in Russian. In: Trudy Instituta Geologii i Geofiziki, Akademiya Nauk SSSR, issue 450, Novosibirsk, pp 60-68
15. Kharchenko EI, Solntsev VP (1981b) A theoretical-group and crystallographic analysis of possible pairs of impurity ions in crystals with beryl structure, in Russian. In: Trudy Instituta Geologii i Geofiziki, Akademiya Nauk SSSR, issue 487. Novosibirsk, pp 155-163
16. Khranenko GG, Solntsev VP (1988) Isomorphous substitutions in synthetic beryls, in Russian. In: Trudy Instituta Geologii i Geofiziki, Akademiya Nauk SSSR, 487. Novosibirsk, pp 94-99
17. Lebedev AS, Klyakhin VA, Solntsev VP (1988) Crystal chemistry features of hydrothermal beryls, in Russian. In: Trudy Instituta Geologii i Geofiziki, Akademiya Nauk SSSR, 708. Novosibirsk, pp 75-94
18. Maki AH, Edelstein N, Davison A, Holm RH (1964) EPR studies of electronic structure of bis(maleonitriledithiolato) copper (II), -nickel (III), -cobalt (II), -rhodium (II) complexes. J Am Chem Soc 86: 4580-4587
19. McClure DS (1962) Optical spectra of transition-metal ions in corundum. J Chem Phys 36: 2757-2779
20. McGarvey BR (1969) Charge transfer in the metal-ligand bond as determined by electron spin resonance. In: Teh Fu-Yen (ed) Electron spin resonance of metal complexes. Adam Hilger Ltd, London, pp 1-11
21. Morosin B (1972) Structure and thermal expansion of beryl. Acta Crystallogr (B) 28: 1899-1903
22. Pappalardo R, Wood DL, Linares RC (1961) Optical absorption study of Co-doped oxide system. J Chem Phys 35: 2041-2059
23. Rae AD (1969) Relation between the experimental Hamiltonian and the point symmetry of a paramagnetic species in a crystal. J Chem Phys 50 : 2672-2685
24. Ray DK (1961) Theory of covalent bond and the analysis of a spectrum paramagnetic resonance in corundum, in Russian. Sov Phys-Solid St 3: 2223-2239
25. Rodionov AYa, Solntsev VP, Weis NS (1987) Crystallization and properties of colouring varieties of gas-transport beryl, in Russian. In: Trudy Insituta Geologii i Geofiziki, Akademiya Nauk SSSR, 679 Novosibirsk, pp 41-53
26. Shand ML, Walling JC (1982) Excited-state absorption in the lasing wavelength region of alexandrite. IEEE J Quantum Electron QE-18: 1152-1155
27. Solntsev VP, Lebedev AS, Pavlyuchenko VS, Klyakhin VA (1976) Copper centers in synthetic beryl, in Russian. Sov Phys Solid State 46: 1396-1398
28. Solntsev VP (1981) The nature of colour centers and EPR in beryl and chrysoberyl, in Russian. In: Trudy Instituta Geologii i Geofiziki, Akademiya Nauk SSSR, 499. Novosibirsk, pp 92-140
29. Solntsev VP (1982) The colour centres and EPR in chrysoberyl with Mn and Ti impurities, in Russian. Zhurnal prikladnoi spektroskopii 37: 839-843
30. Solntsev VP, Khranenko GG (1989) The EPR of radiation defects in beryl. Sov Phys Solid State 31: 292-295
31. Sviridov DT, Smirnov Yu F (1977) The theory optical spectra of transition metal ions, in Russian. Nauka, Moscow, USSR, pp 328
32. Sviridov DT, Sviridova RK, Smirnov Yu F (1976) Optical spectra of transition metal ions in crystals, in Russian. Nauka, Moscow, USSR, pp 266
33. 2+ in three synthetic silicate minerals. Am Mineral 86: 889-895
34. Townsend MG (1964) Cobaltous ion in alumina. J Phys Chem 68:1569-1572
35. Trees RE (1951) Configuration interaction in Mn (II). Phys Rev 83: 756-760
36. Trees RE (1952) The L(L + 1) correction to the Slater formulas for the energy levels. Phys Rev 85: 382
37. 3-electron in trigonal field, in Russian. Zhurnal Prikladnoi Spektroskopii 26: 131-136
38. Walling JC, Peterson OG, Jenssen HP, Morris RC, O'Dell EW (1980) Tunable alexandrite lasers. IEEE J Quantum Electron QE-16: 1302-1314
39. 2O. Phys Chem Miner 23: 489-496
40. 2O. Phys Chem Miner 20: 460-468
41. Wood DL, Nassau K (1968) The characterization of beryl and emerald by visible and infrared absorption spectroscopy. Am Mineral 53: 777-800
42. 2+ ion in corundum, in Russian. J Exp Theor Phys (USSR) 39: 57-63