Regiospecific and enantiospecific ring opening of methyl (+)-(1′R, 2R)- and (-)-(1′R, 2S)-1-(2-phenylethanol) aziridine-2-carboxylates

Molecules

Volumn 5, Issue 8, 2000, Pages 998-1003

  Gnecco, Dino ^a   Orea, F Laura ^a   Galindo, Alberto ^a   Enríquez, Raúl G ^b   Toscano, R A ^b   Reynolds, W F ^c  

^a BENEMÉRITA UNIVERSIDAD AUTÓNOMA DE PUEBLA   (Mexico)

^b UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

^c UNIVERSITY OF TORONTO   (Canada)

Author keywords

Aziridine ring opening; Enantiospecificity; Regiospecificity

Indexed keywords

AZIRIDINE DERIVATIVE; CARBOXYLIC ACID DERIVATIVE;

ACIDITY; ARTICLE; CATALYSIS; CHEMICAL REACTION; ENANTIOSELECTIVITY; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; RING OPENING METATHESIS POLYMERIZATION; STEREOCHEMISTRY;

EID: 1542263553     PISSN: 14203049     EISSN: None     Source Type: Journal    
DOI: 10.3390/50800998     Document Type: Article

References (14)

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11. D and m.p. found for these products are comparable with the corresponding enantiomers (4HCl) and (3HCl) respectively and the NMR spectral data are identical.
12. m, 128.50; C-p, 127.90; C-2, 39.21; C-3, 31.49; C-1′, 74.91; C-4, 67.52; C-6, 52.44; C-5, 171.07.
13. 2 mechanism.
14. Galindo, A.; Orea, L.; Gnecco, D.; Enríquez, R.G.; Toscano, R.A.; Reynolds, W. F. Tetrahedron: Asymmetry 1997, 8, 17, 2877-2879.