Self-oscillations on a partially wetted catalyst pellet in α-methylstyrene hydrogenation: Experiment and mathematical modeling

Theoretical Foundations of Chemical Engineering

Volumn 39, Issue 1, 2005, Pages 24-35

  Kirillov, V A ^a   Koptyug, I V ^b   Kulikov, A V ^a   Kuzin, N A ^a   Lysova, A A ^b,c   Shigarov, A B ^a   Parmon, V N ^a  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

^b INTERNATIONAL TOMOGRAPHY CENTER   (Russian Federation)

^c NOVOSIBIRSK STATE UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; COMPUTER SIMULATION; EVAPORATION; HYDROGENATION; MAGNETIC RESONANCE IMAGING; MATHEMATICAL MODELS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OSCILLATIONS; POROUS MATERIALS;

LIQUID EVAPORATION; LIQUID-PHASE DISTRIBUTION; NMR TOMOGRAPHY; SELF-OSCILLATION MODES;

STYRENE;

ALPHA METHYLSTYRENE;

ARTICLE; CATALYST; CHEMICAL ENGINEERING; EVAPORATION; HYDROGENATION; LIQUID; MATHEMATICAL MODEL; MOLECULAR MODEL; NUCLEAR MAGNETIC RESONANCE IMAGING; OSCILLATION; POROSITY; THEORETICAL MODEL;

EID: 15244363493     PISSN: 00405795     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11236-005-0024-5     Document Type: Article

References (26)

1. Watson, P.C. and Harold, M.P., Dynamic Effects of Vaporization with Exothermic Reaction in a Porous Catalytic Pellet, AIChE J., 1993, vol. 39, pp. 989-1006.
2. Watson, P.C. and Harold, M.P., Rate Enhancement and Multiplicity in a Partially Wetted and Filled Pellet: Experimental Study, AIChE J., 1994, vol. 40, p. 97.
3. Kulikov, A.V., Kuzin, N.A., Shigarov, A.B., Kirillov, V.A., Kronberg, A.E., and Westerterp, K.R., Experimental Study of Vaporization Effect on Steady State and Dynamic Behavior of Catalytic Pellets, Catal. Today, 2001, vol. 66, pp. 255-262.
4. Shigarov, A.B., Kulikov, A.V., Kuzin, N.A., and Kirillov, V.A., Modeling of Critical Phenomena for Liquid/Vapor-Gas Exothermic Reaction on a Single Catalyst Pellet, Chem. Eng. J., 2003, vol. 91, nos. 2-3, pp. 205-213.
5. Kirillov, V.A., Mikhailova, I.A., Fadeev, S.I., and Korolev, V.K., Study of Critical Phenomena in an Exothermic Reaction on a Partially Wetted Porous Catalyst Pellet, Fiz. Goreniya Vzryva, 2002, vol. 38, no. 5, pp. 22-32.
6. Kirillov, V.A., Kuzin, N.A., Gavrilin, V.N., and Kuz'min, V.A., Observed Rate of a Chemical Reaction Accompanied by Phase Transitions on the Surface of a Heterogeneous Catalyst, Kinet. Katal., 1995, vol. 36, no. 4, pp. 1-6.
7. Callaghan, P.T., Principles of Nuclear Magnetic Resonance Microscopy, Oxford: Clarendon, 1991.
8. Kuhn, W., NMR Microscopy - Fundamentals, Limits and Possible Applications, Angew. Chem., Int. Ed. Engl., 1990, vol. 29, pp. 1-19.
9. Talagala, S.L. and Lowe, I.J., Introduction to Magnetic Resonance Imaging, Concepts Magn. Reson., 1991, vol. 3, pp. 145-159.
10. Koptyug, I.V., Il'ina, L.Yu., and Matveev, A.V., Use of NMR Microtomography for Solving Topical Problems of Catalysis, Khim. Fiz., 2002, vol. 21, pp. 68-78.
11. Koptyug, I.V., Sagdeev, R.Z., Khitrina, L.Yu., and Parmon, V.N., A Nuclear Magnetic Resonance Microscopy Study of Mass Transport in Porous Materials, Appl. Magn. Reson., 2000, vol. 18, pp. 13-28.
12. Koptyug, I.V., Kulikov, A.V., Lysova, A.A., Parmon, V.N., and Sagdev, R.Z., NMR Imaging of the Distribution of the Liquid Phase in a Catalyst Pellet During α-Methylstyrene Evaporation, J. Am. Chem. Soc., 2002, vol. 124, pp. 9684-9685.
13. Gladen, L.F., Lim, M.H.M., Mantle, M.D., Sederman, A.J., and Stitt, E.H., MRI Visualization of Two-Phase Flow in Structured Support and Trickle-Bed Reactors, Catal. Today, 2003, vols. 79-80, pp. 203-210.
14. Funk, G.A., Harold, M.P., and Ng, K.M., A Novel Model for Reaction in Trickle-Bed with Flow Maldistribution, Ind. Eng. Chem. Res., 1990, vol. 29, p. 738.
15. El-Hisnavi, A.A., Dudukovic, M.P., and Mills, P.L., Trickle-Bed Reactor: Dynamic Tracer Tests, Reaction in Studies and Modeling Reactor Performance, Am. Chem. Soc. Symp. Ser., 1982, vol. 196, pp. 421-440.
16. Germain, A.H., Levebvre, A.G., and L'Homme, G.A., Experimental Study of Catalytic Trickle Bed Reactor, Adv. Chem. Ser., 1974, vol. 133, p. 164.
17. Turek, F. and Lange, R., Mass Transfer in Trickle-Bed Reactors at Low Reynolds Number, Chem. Eng. Sci., 1981, vol. 36, pp. 573-579.
18. Kadilkar, M.R., Wu, Y.X., Al-Dahhan, M.H., and Dudukovic, M.P., Comparison of Trickle-Bed and Upflow Reactor Performance at High Pressure: Model Predictions and Experimental Observations, Chem. Eng. Sci., 1996, vol. 51, no. 10, pp. 2139-2148.
19. Ahn, B.J., Smith, J.M., and McCoy, B.J., Dynamic Hydrogenation Studies in a Catalytic Slurry Reactor, AIChE J., 1986, vol. 32, no. 4, pp. 566-574.
20. Cini, P. and Harold, M.P., Experimental Study of the Tubular Multiphase Catalyst, AIChE J., 1991, vol. 37, p. 997.
21. Koptyug, I.V. and Sagdeev, R.Z., Non-Traditional Applications of NMR Tomography, Usp. Khim., 2003, vol. 72, no. 2, pp. 183-212 [Russ. Chem. Rev. (Engl. Transl.), vol. 72, no. 2, pp. 165-191].
22. Koptyug, I.V. and Sagdeev, R.Z., Non-Traditional Applications of NMR Tomography, Usp. Khim., 2003, vol. 72, no. 2, pp. 183-212 [Russ. Chem. Rev. (Engl. Transl.), vol. 72, no. 2, pp. 165-191].
23. Reid, R.C., Prausnitz, J.M., and Poling, B.E., The Properties of Gases and Liquids, New York: McGraw-Hill, 1987.
24. Hughmark, G.A., Mass and Heat Transfer from Rigid Spheres, AIChE J., 1967, vol. 3, p. 1219.
25. Andronov, A.A., Vitt, A.A., and Khaikin, S.E., Teoriya kolebanii (Theory of Oscillations), Moscow: Nauka, 1981.
26. Godunov, S.K. and Ryaben'kii, V.S., Raznostnye skhemy (Finite-Difference Schemes), Moscow: Nauka, 1977.