Synthesis and self-assembly of poly(ferrocenyldimethylsilane-b- dimethylaminoethyl methacrylate): Toward water-soluble cylinders with an organometallic core

Macromolecules

Volumn 38, Issue 5, 2005, Pages 1928-1935

  Wang, Xiaosong ^a   Winnik, Mitchell A ^a   Manners, Ian ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; ANIONIC POLYMERIZATION; ETHANOL; HYDROPHILICITY; MICELLES; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLICS; PRECIPITATION (CHEMICAL); RING OPENING POLYMERIZATION; SELF ASSEMBLY; SYNTHESIS (CHEMICAL); TRANSMISSION ELECTRON MICROSCOPY; WATER;

ANIONIC RING-OPENING POLYMERIZATION; MICELLIZATION; POLY(FERRODIMETHYLSILANE-B-DIMETHYLAMINOETHYL METHACRYLATE); POLYFERROCENYLSILANES;

BLOCK COPOLYMERS;

EID: 15244347263     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma049793q     Document Type: Article

References (48)

1. Hamley, I. W. The Physics of Block Copolymers; Oxford University Press, Inc.: New York, 1998.
2. (a) Halperin, A.; Tirrell, M.; Lodge T. P. Adv. Polym. Sci. 1992, 100, 31.
3. (b) Simon, P. F. W.; Ulrich, R.; Spiess, H. W.; Wiesner, U. Chem. Mater. 2001, 13, 3464.
4. Choucair, A.; Eisenberg, A. Eur. Phys. J. E 2003, 10, 37.
5. (a) Jenekhe, S. A.; Chen, X. L. Science 1998, 279, 1903.
6. (b) Discher, D. E., Eisenberg, A. Science 2002, 297, 967.
7. (a) Tao, J.; Stewart, S.; Liu, G.; Yang, M. Macromolecules 1997, 30, 2738.
8. (b) Stewart, S.; Liu, G. Angew. Chem. Int. Ed. 2000, 39, 340.
9. (a) Jain, S.; Bates, F. S. Science 2003, 300, 460.
10. (b) Won, Y.; Davis, H. T.; Bates, F. S. Science 1999, 283, 960.
11. (c) Discher, B. M.; Won, Y.; Ege, D. S.; Lee, J. C-M.; Bates, F. S.; Discher, D. E.; Hammer, D. A. Science 1999, 284, 1143.
12. (d) Pochan, D. J.; Chen, Z. Y.; Cui, H. G.; Hales, K.; Qi, K.; Wooley, K. L. Science 2004, 306, 94.
13. (e) Li, Z.; Kesselman, E.; Talmon, Y.; Hillmyer, M. A.; Lodge, T. P. Science 2004, 306, 98.
14. (a) Antonietti, M.; Förster, S. Adv. Mater. 2003, 15, 1323.
15. (b) Spatz, J. P.; Moessmer, S.; Möller, M. Angew. Chem., Int. Ed. Engl. 1996, 35, 1510.
16. (a) Zhang, L.; Eisenberg, A. Science 1995, 268, 1728.
17. (b) Zhang, L.; Eisenberg, A. J. Am. Chem. Soc. 1996, 118, 3168.
18. For an example as drug delivery, see: (a) Savic, R.; Luo, L.; Eisenberg, A.; Maysinger, D. Science 2003, 300, 615. For an example as impact modifiers, see: (b) Dean, J. M.; Verghese, N. E.; Pham, H. Q.; Bates, F. S. Macromolecules 2003, 36, 9267-9270. (c) Goren, M.; Lennox, R. B. Nano Lett. 2001, 1, 735. For selected reviews, see: (d) Förster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195. (e) Hamley, I. W. Angew. Chem. Int. Ed. 2003, 42, 1692. (f) Lazzari, M.; López-Quintela, M. A. Adv. Mater. 2003, 15, 1583.
19. For an example as drug delivery, see: (a) Savic, R.; Luo, L.; Eisenberg, A.; Maysinger, D. Science 2003, 300, 615. For an example as impact modifiers, see: (b) Dean, J. M.; Verghese, N. E.; Pham, H. Q.; Bates, F. S. Macromolecules 2003, 36, 9267-9270. (c) Goren, M.; Lennox, R. B. Nano Lett. 2001, 1, 735. For selected reviews, see: (d) Förster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195. (e) Hamley, I. W. Angew. Chem. Int. Ed. 2003, 42, 1692. (f) Lazzari, M.; López-Quintela, M. A. Adv. Mater. 2003, 15, 1583.
20. For an example as drug delivery, see: (a) Savic, R.; Luo, L.; Eisenberg, A.; Maysinger, D. Science 2003, 300, 615. For an example as impact modifiers, see: (b) Dean, J. M.; Verghese, N. E.; Pham, H. Q.; Bates, F. S. Macromolecules 2003, 36, 9267-9270. (c) Goren, M.; Lennox, R. B. Nano Lett. 2001, 1, 735. For selected reviews, see: (d) Förster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195. (e) Hamley, I. W. Angew. Chem. Int. Ed. 2003, 42, 1692. (f) Lazzari, M.; López-Quintela, M. A. Adv. Mater. 2003, 15, 1583.
21. For an example as drug delivery, see: (a) Savic, R.; Luo, L.; Eisenberg, A.; Maysinger, D. Science 2003, 300, 615. For an example as impact modifiers, see: (b) Dean, J. M.; Verghese, N. E.; Pham, H. Q.; Bates, F. S. Macromolecules 2003, 36, 9267-9270. (c) Goren, M.; Lennox, R. B. Nano Lett. 2001, 1, 735. For selected reviews, see: (d) Förster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195. (e) Hamley, I. W. Angew. Chem. Int. Ed. 2003, 42, 1692. (f) Lazzari, M.; López-Quintela, M. A. Adv. Mater. 2003, 15, 1583.
22. For an example as drug delivery, see: (a) Savic, R.; Luo, L.; Eisenberg, A.; Maysinger, D. Science 2003, 300, 615. For an example as impact modifiers, see: (b) Dean, J. M.; Verghese, N. E.; Pham, H. Q.; Bates, F. S. Macromolecules 2003, 36, 9267-9270. (c) Goren, M.; Lennox, R. B. Nano Lett. 2001, 1, 735. For selected reviews, see: (d) Förster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195. (e) Hamley, I. W. Angew. Chem. Int. Ed. 2003, 42, 1692. (f) Lazzari, M.; López-Quintela, M. A. Adv. Mater. 2003, 15, 1583.
23. For an example as drug delivery, see: (a) Savic, R.; Luo, L.; Eisenberg, A.; Maysinger, D. Science 2003, 300, 615. For an example as impact modifiers, see: (b) Dean, J. M.; Verghese, N. E.; Pham, H. Q.; Bates, F. S. Macromolecules 2003, 36, 9267-9270. (c) Goren, M.; Lennox, R. B. Nano Lett. 2001, 1, 735. For selected reviews, see: (d) Förster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195. (e) Hamley, I. W. Angew. Chem. Int. Ed. 2003, 42, 1692. (f) Lazzari, M.; López-Quintela, M. A. Adv. Mater. 2003, 15, 1583.
24. Manners. I. Science 2001, 294, 1664.
25. (a) Gohy, J.-F.; Lohmeijer, B. G. G.; Varshney, S. K.; Schubert, U. S. Macromolecules 2002, 35, 7427.
26. (b) Hou, S.; Man K. Y. K.; Chan, W. K. Langmuir 2003, 19, 2485.
27. (a) Rulkens, R.; Ni, Y.; Manners, I. J. Am. Chem. Soc. 1994, 116, 12121.
28. (b) Ni, Y.; Rulkens, R.; Manners, I. J. Am. Chem. Soc. 1996, 118, 4102.
29. Massey, J. A.; Power, K. N.; Manners, I.; Winnik, M. A. J. Am. Chem. Soc. 1998, 120, 9533.
30. Raez, J.; Manners, I.; Winnik, M. A. J. Am. Chem. Soc. 2002, 124, 10381.
31. Cao, L.; Manners, I; Winnik, M. A. Macromolecules 2002, 35, 8258.
32. Massey, J. A.; Temple, K.; Cao, L.; Rharbi, Y.; Raez, J.; Winnik, M. A.; Manners, I. J. Am. Chem. Soc. 2000, 122, 11577.
33. (a) Massey, J. A.; Winnik, M. A.; Manners, I.; Chan, V. Z-H.; Ostermann, J. M.; Enchelmaier, R.; Spatz, J. P.; Möller, M. J. Am. Chem. Soc. 2001, 123, 3147.
34. (b) Cao L.; Massey, J. A.; Winnik, M. A.; Manners, I.; Riethmuller, S.; Banhart F.; Spatz, J. P.; Möller, M. Adv. Funct. Mater. 2003, 13, 271.
35. Wang, X. S.; Arsenault, A.; Ozin, G. A.; Winnik, M. A.; Manners, I. J. Am. Chem. Soc. 2003, 125, 12686.
36. Wang, X. S.; Winnik, M. A.; Manners, I. Macromol. Rapid Commun. 2002, 23, 210.
37. Gohy, J. F.; Antoun, S.; Jerome, R. Macromolecules 2001, 34, 7435.
38. Wang, X. S.; Armes, S. P. Macromolecules 2000, 33, 6640.
39. (a) Quirk, R. P.; Jang, S. H.; Yang, H. M.; Lee, Y. Macromol. Symp. 1998, 132, 281.
40. (b) Zhang, P.; Moore, J. S. J. Polym. Sci., Part A 2000, 38, 207.
41. (a) Foucher, D. A.; Nelson, J. M.; Honeyman, C.; Tang, B. Z.; Manners, I. Angew. Chem. Int. Ed. 1993, 32, 1709.
42. (b) Cyr, P. W.; Tzolov, M.; Manners, I.; Sargent, E. H. Macromol. Chem. Phys. 2003, 204, 915.
43. (c) Mang, Y. Q.; Cervantes-Lee, F.; Pannell, K. H. Organometallics 2002, 21, 5859.
44. See Supporting Information.
45. Winnik, F. Ringsdorf, M.; H.; Venzmer, J. Macromolecules 1990, 23, 2415.
46. For related metallized nanocylinders, see: (a) Braun, E.; Eichen, Y.; Sivan, U.; Ben-Yoseph G.; Nature 1998, 391, 775. (b) Fullam, S.; Cottell, D.; Rensmo, H.; Fitzmaurice, D. Adv. Mater. 2000, 19, 1430. (c) Djalali, R.; Li, S. Y.; Schmidt, M. Macromolecules 2002, 35, 4282.
47. For related metallized nanocylinders, see: (a) Braun, E.; Eichen, Y.; Sivan, U.; Ben-Yoseph G.; Nature 1998, 391, 775. (b) Fullam, S.; Cottell, D.; Rensmo, H.; Fitzmaurice, D. Adv. Mater. 2000, 19, 1430. (c) Djalali, R.; Li, S. Y.; Schmidt, M. Macromolecules 2002, 35, 4282.
48. For related metallized nanocylinders, see: (a) Braun, E.; Eichen, Y.; Sivan, U.; Ben-Yoseph G.; Nature 1998, 391, 775. (b) Fullam, S.; Cottell, D.; Rensmo, H.; Fitzmaurice, D. Adv. Mater. 2000, 19, 1430. (c) Djalali, R.; Li, S. Y.; Schmidt, M. Macromolecules 2002, 35, 4282.